Trichloroacetonitrile as an efficient activating agent for the ipso-hydroxylation of arylboronic acids to phenolic compounds

2019 ◽  
Vol 17 (32) ◽  
pp. 7558-7563 ◽  
Author(s):  
Yuanding Fang ◽  
Rong Zhao ◽  
Yuan Yao ◽  
Yang Liu ◽  
Denghu Chang ◽  
...  

An efficient and practical method for the ipso-hydroxylation of arylboronic acids was developed using TBHP and Cl3CCN under base-free conditions with blue-LED irradiation.

2021 ◽  
Vol 23 (2) ◽  
pp. 774-779
Author(s):  
Pengfei Niu ◽  
Jingya Yang ◽  
Yong Yuan ◽  
Yongxin Zhang ◽  
Chenxing Zhou ◽  
...  

A redox-neutral decarboxylative radical–radical coupling reaction of heteroaryl methylamines with NHPI esters has been developed by employing a copper complex as a photocatalyst with blue LED irradiation.


2020 ◽  
Author(s):  
Mingyu He ◽  
Guanghui Li ◽  
Xiaoqi He ◽  
Yang Wang ◽  
Hong Lei ◽  
...  

Abstract Phototherapies, including sunlight, infrared, ultraviolet, visible and laser, parts of which present high curative effect, small invasion, and negligible adverse reactions in cancer treatment. Here we aimed to explore the potential therapeutical effects of blue LED in hepatoma cell and decipher the underlying cellular/molecular mechanisms. We demonstrated that the irradiation of blue LED light in hepatoma cell could lead to cell proliferation reduction along with the cell apoptosis increase. Simultaneously, blue LED irradiation also markedly suppressed the migration and invasion ability of hepatoma cells. Sphere formation analysis further revealed the decreased stemness of hepatoma cell under the treatment of blue LED irradiation. In addition, blue LED irradiation significantly promoted the expression of γ-H2AX, a sensitive molecular marker of DNA damage. Collectively, we demonstrated that blue LED irradiation exhibited anti-tumor effects on liver cancer by inducing DNA damage, representing a potential approach for human hepatoma treatment.


2019 ◽  
Vol 58 (47) ◽  
pp. 16700-16700
Author(s):  
Tristan Chidley ◽  
Islam Jameel ◽  
Shafa Rizwan ◽  
Philippe A. Peixoto ◽  
Laurent Pouységu ◽  
...  

Data in Brief ◽  
2016 ◽  
Vol 6 ◽  
pp. 630-633 ◽  
Author(s):  
Phil-Sun Oh ◽  
Hyosook Hwang ◽  
Hwan-Seok Jeong ◽  
Jeongil Kwon ◽  
Hyun-Soo Kim ◽  
...  

2016 ◽  
Vol 40 (11) ◽  
pp. 9257-9262 ◽  
Author(s):  
Moosa Ramdar ◽  
Foad Kazemi ◽  
Babak Kaboudin ◽  
Zahra Taran ◽  
Adel Partovi

A new CdS nanorod was synthesized and it was used in the one-pot synthesis of aldonitrones under blue LED irradiation.


2015 ◽  
Author(s):  
Anja Becker ◽  
Carsten Sticht ◽  
Harsh Dweep ◽  
Frank A. van Abeelen ◽  
Norbert Gretz ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (67) ◽  
pp. 39124-39132
Author(s):  
Jianjian Zhuang ◽  
Juxin Yin ◽  
Chaojian Xu ◽  
Mengmeng Jiang ◽  
Shaowu Lv

Blue LED and 20(S)-GRh2 induced apoptosis and autophagy in cells.


2019 ◽  
Vol 131 (47) ◽  
pp. 17115-17121 ◽  
Author(s):  
Tristan Chidley ◽  
Islam Jameel ◽  
Shafa Rizwan ◽  
Philippe A. Peixoto ◽  
Laurent Pouységu ◽  
...  

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