Scalable construction of heteroatom-doped and hierarchical core–shell MnO2 nanoflakes on mesoporous carbon for high performance supercapacitor devices

2020 ◽  
Vol 7 (2) ◽  
pp. 411-420
Author(s):  
Xue Bai ◽  
Dianxue Cao ◽  
Hongyu Zhang

Combining interfacial methods and mesoporous carbon channels, an asymmetric device, using N,S-codoped mesoporous carbon and a MnO2@MC-30 core shell composite, is assembled with high energy, power densities and outstanding cycling stability.

Author(s):  
Jian Zhao ◽  
He Cheng ◽  
Huanyu Li ◽  
Yan-Jie Wang ◽  
Qingyan Jiang ◽  
...  

Developing advanced negative and positive electrode materials for asymmetric supercapacitors (ASCs) as the electrochemical energy storage can enable the device to reach high energy/power densities resulting from the cooperative effect...


RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhi Dong ◽  
Zongqing Ma ◽  
Liming Yu ◽  
Yongchang Liu

AbstractWith excellent creep resistance, good high-temperature microstructural stability and good irradiation resistance, oxide dispersion strengthened (ODS) alloys are a class of important alloys that are promising for high-temperature applications. However, plagued by a nerve-wracking fact that the oxide particles tend to aggregate at grain boundary of metal matrix, their improvement effect on the mechanical properties of metal matrix tends to be limited. In this work, we employ a unique in-house synthesized oxide@W core-shell nanopowder as precursor to prepare W-based ODS alloy. After low-temperature sintering and high-energy-rate forging, high-density oxide nanoparticles are dispersed homogeneously within W grains in the prepared alloy, accompanying with the intergranular oxide particles completely disappearing. As a result, our prepared alloy achieves a great enhancement of strength and ductility at room temperature. Our strategy using core-shell powder as precursor to prepare high-performance ODS alloy has potential to be applied to other dispersion-strengthened alloy systems.


2017 ◽  
Vol 41 (1) ◽  
pp. 237-244 ◽  
Author(s):  
Hamid Heydari ◽  
Mohammad B. Gholivand

3D porous PANI hydrogel and a gel electrolyte were used to fabricate a high performance, all-solid-state, flexible asymmetric supercapacitor with an energy density of up to 6.16 mW h cm−3.


2021 ◽  
Vol 16 (7) ◽  
pp. 1134-1142
Author(s):  
Wenduo Yang ◽  
Jun Xiang ◽  
Sroeurb Loy ◽  
Nan Bu ◽  
Duo Cui ◽  
...  

NiCo2O4 as an electrode material for supercapacitors (SCs) has been studied by a host of researchers due to its unique structural characteristics and high capacitance. However, its performance has not yet reached the level of practical applications.it is an effective strategy to synthesize composite electrode materials for tackling the problem. Herein, NiCo2O4@ZnCo2O4 as a novel core–shell composite electrode material has been fabricated through a two-step simple hydrothermal method. The as-prepared sample can be directly used as cathode material of a supercapacitor, and its specific capacitance is 463.1 C/g at 1 A/g. An assembled capacitor has an energy density of 77 Wh·kg−1 at 2700 W·kg−1, and after 8000 cycles, 88% of the initial capacity remains.


2018 ◽  
Vol 6 (4) ◽  
pp. 1802-1808 ◽  
Author(s):  
Ke Li ◽  
Yanshan Huang ◽  
Jingjing Liu ◽  
Mansoor Sarfraz ◽  
Phillips O. Agboola ◽  
...  

Three-dimensional graphene frameworks enable the development of stretchable asymmetric supercapacitors with a record high energy density of 77.8 W h kg−1, and also excellent stretchability and superior cycling stability.


NANO ◽  
2019 ◽  
Vol 14 (04) ◽  
pp. 1950049 ◽  
Author(s):  
Jingjing Lin ◽  
Song Yan ◽  
Xiaojie Zhang ◽  
Yueran Liu ◽  
Jun Lian ◽  
...  

Holey Fe-Anderson-type polyoxometalate/polyaniline/graphene (PPG) hybrid materials were first prepared by anchoring Anderson-type polyoxometalates [FeMo6O[Formula: see text]H6][Formula: see text] (FeMo[Formula: see text] onto graphene modified with polyaniline via a facile hydrothermal treatment. The as-prepared materials exhibited an excellent electrochemical performance with a high specific capacitance of 1366 F g[Formula: see text] at 1 A g[Formula: see text] and outstanding cycling stability (97.6% capacitance retention after 5000 cycle times). The uptake of polyaniline/FeMo6 nanoparticles on graphene not only provided the pseudocapacitance but also weakened the aggregation between the graphene layers, resulting in a higher surface area compared with pure graphene. In addition, the AC//PPG-15 asymmetric supercapacitor device showed a high energy density of 24.65[Formula: see text]W h kg[Formula: see text] at a low power density of 326.25[Formula: see text]W kg[Formula: see text] and good cycling stability (94.82% capacitance retention after 5000 cycles). Hence, the as-prepared PPG hybrid materials in this work possess tremendous potential as electrodes for high-performance supercapacitors.


2007 ◽  
Vol 14 (01) ◽  
pp. 117-122 ◽  
Author(s):  
JIEGUANG SONG ◽  
LIANMENG ZHANG ◽  
JUNGUO LI ◽  
JIANRONG SONG

ZrB 2 has some excellent performances, but it is easily oxidized at high temperatures to impact the high-temperature strength, which restricts its applied range. To protect from the oxidization and improve the strength of ZrB 2 at high temperature, the surface of ZrB 2 particles is coated with the Al ( OH )3– Y ( OH )3 shell to synthesize ZrB 2@ Al ( OH )3– Y ( OH )3 core–shell composite particles. Through the thermodynamic and kinetic analyses of the heterogeneous nucleation and homogeneous nucleation, the concentration product of precursor ion ( Y 3+ or Al 3+) and OH - (Qi) must be greater than the solubility product (K sp ), respectively; the conditions of Y 3+ and Al 3+ are reached to produce Al ( OH )3– Y ( OH )3 shell on the ZrB 2 surface between the Y 3+ line and the AlO 2- line. Through TEM and XRD analyses, ZrB 2@ Al ( OH )3– Y ( OH )3 core–shell composite particles are successfully synthesized by the co-precipitation method, the shell layer quality is better at pH = 9, which established the foundation for preparing high-performance YAG / ZrB 2 and Al 2 O 3– YAG / ZrB 2 multiphase ceramic materials.


2017 ◽  
Vol 5 (22) ◽  
pp. 11197-11203 ◽  
Author(s):  
Tong Shen ◽  
Xin-hui Xia ◽  
Dong Xie ◽  
Zhu-jun Yao ◽  
Yu Zhong ◽  
...  

Pomegranate-structured Si/C mesoporous microspheres are fabricated by a facile one-step hydrothermal method with high cycling stability and superior rate capacity.


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