pH-Switchable IFT variations and emulsions based on the dynamic noncovalent surfactant/salt assembly at the water/oil interface

Soft Matter ◽  
2019 ◽  
Vol 15 (27) ◽  
pp. 5529-5536 ◽  
Author(s):  
Han Jia ◽  
Xu Leng ◽  
Peng Lian ◽  
Yugui Han ◽  
Qiuxia Wang ◽  
...  

Additional HCl can facilely control the dynamic noncovalent interaction between anionic surfactant sodium dodecyl benzene sulfonate (SDBS) and additional organic matter, 4,4′-oxydianiline (ODA), at the water/oil interface.

2014 ◽  
Vol 787 ◽  
pp. 58-64
Author(s):  
Shu Yao Wen ◽  
Xiao Chun Sun ◽  
Su Yun Chen

Previous studies predominantly degraded organic matter in simulated water samples containing one or two organic components, while a few literatures reported organic matter degradation in natural and actual sewage water samples. This is likely due to the ingredient of surface water or actual sewage coexisted with many kinds of organic pollutants being complex. The relationship among coexisting organic materials is complex during photocatalytic degradation. Moreover, the coexistence of many kinds of inorganic pollutants in natural or actual sewage water samples is also common. Thus, the influence of coexisting inorganic pollutants on degradation is also worthy of study. This work explored these influences of TiO2-bentonite composite catalysts. 8.6%~11.5% sodium dodecyl benzene sulfonate (SDBS) in surface water or clothes laundering drain water was degraded by 3‰ TiO2-bentonite within 6h under 6W ultraviolet light. Under the same conditions, 86.5% of the SDBS in aqueous solution was degraded. The difference was obvious, but the causes were complicated. For example, the influence of , , and on the degradation was discussed. The results show that the influence of on the above degradation was obvious, while and was not obvious. In addition, and were captured by resulting a decrease of degradation speed. Competition of , and SDBS for surface active sites decreased the efficiency of the degradation. Based on these results, pretreatment such as filtering, deposition and impurity removal before actual sewage is degraded could improve the degradation efficiency. Further study, such as on the reasons for efficiency reduction, on new pretreatment methods and on the application of multi-treatment measures, is needed to conduct.


Langmuir ◽  
2011 ◽  
Vol 27 (14) ◽  
pp. 8867-8877 ◽  
Author(s):  
Jeff Penfold ◽  
Minglei Chen ◽  
Robert K. Thomas ◽  
Chuchuan Dong ◽  
Thomas J. P. Smyth ◽  
...  

2018 ◽  
Vol 225 ◽  
pp. 06019
Author(s):  
Sarmad K. Fakhruddin ◽  
Hayder A. Abdulbari ◽  
Ahmad Z. Sulaiman ◽  
Hind A. Rafeeq

Polyethylene Oxide (PEO) is one of the most common drag reduction agents. However, its ability to reduce drag in turbulent flow decreases with the time due to the degradation of its molecules. Thus, the enhancement of its degradation resistance by the addition of Anionic surfactant is presented. The Polyethylene oxide (PEO) was used in different concentration ranges from 10 to 60 ppm and with addition of sodium dodecyl benzene sulfonate (SDBS) as the anionic surfactant with five concentrations between 100 to 500 ppm. The degradation measurements were done using rotating disk apparatus (RDA). The RDA results have shown a considerable improvement in the degradation resistance of PEO with the addition of surfactant to the polymer solution. The interaction between the polymer and the surfactant results in transferring the polymer chain from coil to straight-like body. Thus, enhance the polymer degradation resistant ability.


Langmuir ◽  
2010 ◽  
Vol 26 (23) ◽  
pp. 17958-17968 ◽  
Author(s):  
M. L. Chen ◽  
J. Penfold ◽  
R. K. Thomas ◽  
T. J. P. Smyth ◽  
A. Perfumo ◽  
...  

2017 ◽  
Vol 13 (2) ◽  
pp. 145
Author(s):  
Monica Cahyaning Ratri ◽  
Adhitasari Suratman ◽  
Roto Roto

The analytical method development on an anionic surfactant of sodium dodecylbenzenesulfonate (SDBS) in a catfish using spectrophotometer UV-Vis using acridine orange (AO) has been conducted. This research aims to determine the optimum conditions of analysis and to determine validation parameters of sodium dodecylbenzenesulfonate (SDBS) analysis in a catfish. This study was divided into two steps, isolation of sodium dodecyl benzene sulfonate (SDBS) in the catfish with soxhlet extraction and the analysis of SDBS. The analysis of sodium dodecylbenzenesulfonate (SDBS) is based on the formation of ion pair between dodecylbenzenesulfonate (DBS) and acridine orange (AO). The results showed that the analysis can be performed at 499 nm, using ethanol as acridine orange (AO) solvent, the mole ratio of dodecylbenzenesulfonate (DBS) acridine orange (AO) 2:1, and pH 2.97. The parameters of validation had good acceptability as linearity (r) 0.998, limit of detection 0.0343 mg/L   and limit of quantification 0.104 mg/L, precision 0.382 - 1.78 %, sensitivity 4.64 x 10<sup>4</sup> L mol<sup>-1</sup>cm<sup>-1</sup>, and accuracy (82.11 - 100.3 %).


2014 ◽  
Vol 1073-1076 ◽  
pp. 2106-2111 ◽  
Author(s):  
Yan Cheng Zheng ◽  
Li Wen Yu ◽  
Deng Pan ◽  
Ping Mei ◽  
Lu Lai

A surface properties of a sulfobetaine–type zwitterionic gemini surfactant with the structure of 1,2-bis [N-methyl-N-(3-sulfopropyl) -dodecylammonium] ethane betaine (ZGS12), were investigated in aqueous solution . The critical micelle concentration (CMC) of the gemini surfactant at different temperatures and mixed micelle properties of ZGS12 and sodium dodecyl benzene sulfonate (SDBS) were investigated. The results show that cmc of the gemini surfactant (ZGS12) decreases with raising temperature, Gibbs free energy changes and entropy changes are negative and postive, respectively, indicating the formation of micelle is spontaneous and driven mainly by entropy. According to the theory of regular solution , interaction parameters between the zwitterionic gemini surfactant ZGS12 and the anionic surfactant SDBS indicate strong attractive interaction and great degree of synergism in micelle formation due to weakening of the electrostatic head group repulsion.


2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Xiaobin Wen ◽  
Aoqi Zhang ◽  
Xiaoyan Zhu ◽  
Lin Liang ◽  
Yan Huo ◽  
...  

Abstract Background Predatory flagellates and ciliates are two common bio-contaminants which frequently cause biomass losses in Chlorella mass culture. Efficient and targeted ways are required to control these contaminations in Chlorella mass cultivation aiming for biofuel production especially. Results Five surfactants were tested for its ability to control bio-contaminations in Chlorella culture. All five surfactants were able to eliminate the contaminants at a proper concentration. Particularly the minimal effective concentrations of sodium dodecyl benzene sulfonate (SDBS) to completely eliminate Poterioochromonas sp. and Hemiurosomoida sp. were 8 and 10 mg L−1, respectively, yet the photosynthesis and viability of Chlorella was not significantly affected. These results were further validated in Chlorella mass cultures in 5, 20, and 200 m2 raceway ponds. Conclusions A chemical method using 10 mg L−1 SDBS as pesticide to control predatory flagellate or ciliate contamination in Chlorella mass culture was proposed. The method helps for a sustained microalgae biomass production and utilization, especially for biofuel production.


2013 ◽  
Vol 734-737 ◽  
pp. 2505-2508
Author(s):  
Lin Lin Cui ◽  
Hua Nan Guan

Dodecyl trimethyl ammonium bromide/sodium dodecyl benzene sulfonate (DTAB/SDBS) complex formulation of scale effect on the spontaneous formation of vesicles and the influence of different factors on the stability of vesicles were discussed, structure and morphology of vesicles were observed.


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