Cationic shield mediated electrodeposition stability in metal electrodes

Mechanistic understanding of coupled reaction kinetics, diffusive transport and electrostatic shield mediated electrodeposition stability is elucidated.

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Mechanistic understanding of electrochemical plating and stripping of metal electrodes

Journal of Materials Chemistry A ◽

10.1039/c8ta11326b ◽

2019 ◽

Vol 7 (9) ◽

pp. 4668-4688 ◽

Cited By ~ 10

Author(s):

Deepti Tewari ◽

Partha P. Mukherjee

Keyword(s):

Metal Electrode ◽

Metal Electrodes ◽

Electrode Interface ◽

Mechanistic Understanding ◽

Electrochemical Plating

Mechanisms driving the evolution of the metal electrode interface during plating, stripping and formation of dead metal.

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Coupled reaction kinetics of duplex steelmaking process for high phosphorus hot metal

Ironmaking & Steelmaking ◽

10.1179/1743281212y.0000000036 ◽

2013 ◽

Vol 40 (4) ◽

pp. 282-289 ◽

Cited By ~ 7

Author(s):

X Zhang ◽

B Xie ◽

H Y Li ◽

J Diao ◽

C Q Ji

Keyword(s):

Reaction Kinetics ◽

Steelmaking Process ◽

Hot Metal ◽

High Phosphorus ◽

Kinetics Of ◽

Coupled Reaction

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Mechanism, kinetics and selectivity of a Williamson ether synthesis: elucidation under different reaction conditions

Reaction Chemistry & Engineering ◽

10.1039/d0re00437e ◽

2021 ◽

Author(s):

Aikaterini Diamanti ◽

Zara Ganase ◽

Eliana Grant ◽

Alan Armstrong ◽

Patrick M. Piccione ◽

...

Keyword(s):

Reaction Kinetics ◽

Large Impact ◽

Reaction Conditions ◽

Mechanistic Understanding ◽

Ether Synthesis ◽

Shed Light ◽

Williamson Ether Synthesis

New mechanistic understanding and the quantification of reaction kinetics shed light on the large impact of the solvent on selectivity.

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Experimental analysis and modelling of temperature- and humidity-controlled curing

Journal of Rubber Research ◽

10.1007/s42464-021-00085-9 ◽

2021 ◽

Author(s):

Rebecca Jennrich ◽

Ahmet Burak Aydogdu ◽

Alexander Lion ◽

Michael Johlitz ◽

Sarah Glaser ◽

...

Keyword(s):

Mechanical Properties ◽

Finite Element ◽

Reaction Kinetics ◽

Experimental Analysis ◽

Hardening Process ◽

Complex Hardening ◽

Degree Of Curing ◽

Kinetics Of ◽

And Diffusion ◽

Coupled Reaction

AbstractThere has been much discussion about modelling the reaction kinetics of a curing polymer. Typically, curing is described by the development of a variable called degree of curing as a function of temperature and time. The material considered in this paper exhibits two different curing mechanisms, namely temperature-activated and diffusion-based. To be able to describe the complex hardening process, the material is extensively analysed experimentally, and a thermodynamically consistent coupled reaction kinetics model is formulated based on experimental observations. This model enables the implementation of the thermal, caloric, and mechanical properties of the material into a finite element (FE) framework.

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Reaction Kinetics and Modelling of a Coupled Reaction System for the Production of Norlaudanosoline from Dopamine

Biocatalysis ◽

10.3109/10242429309003666 ◽

1993 ◽

Vol 7 (2) ◽

pp. 117-129

Author(s):

Larry K. Hoover ◽

Murray Moo-Young ◽

Raymond L. Legge

Keyword(s):

Reaction Kinetics ◽

Reaction System ◽

Coupled Reaction

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A Reactive Flow Model with Coupled Reaction Kinetics for Detonation and Combustion in Non-Ideal Explosives

MRS Proceedings ◽

10.1557/proc-418-413 ◽

1995 ◽

Vol 418 ◽

Cited By ~ 19

Author(s):

Philip J. Miller

Keyword(s):

Reaction Kinetics ◽

Flow Model ◽

Reaction Model ◽

Reactive Flow ◽

Model Parameters ◽

Combustion Chemistry ◽

Metal Combustion ◽

Dimensional Finite Element ◽

Hydrodynamic Code ◽

Coupled Reaction

AbstractA new reactive flow model for highly non-ideal explosives and propellants is presented. These compostions, which contain large amounts of metal, upon explosion have reaction kinetics that are characteristic of both fast detonation and slow metal combustion chemistry. A reaction model for these systems was incorporated into the two-dimensional, finite element, Lagrangian hydrodynamic code, DYNA2D. A description of how to determine the model parameters is given.

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ON ISOCONCENTRATION SURFACES OF THREE-DIMENSIONAL TURING PATTERNS

International Journal of Bifurcation and Chaos ◽

10.1142/s0218127408020355 ◽

2008 ◽

Vol 18 (02) ◽

pp. 391-406 ◽

Cited By ~ 4

Author(s):

TILMANN GLIMM ◽

H. G. E. HENTSCHEL

Keyword(s):

Reaction Kinetics ◽

Minimal Surfaces ◽

Variational Principles ◽

Three Dimensional ◽

Equilibrium Concentration ◽

Turing Patterns ◽

Diffusive Transport ◽

Low Concentrations ◽

Dynamical Explanation

We consider three-dimensional Turing patterns and their isoconcentration surfaces corresponding to the equilibrium concentration of the reaction kinetics. We call these surfaces equilibrium concentration surfaces (EC surfaces). They are the interfaces between the regions of "high" and "low" concentrations in Turing patterns. We give alternate characterizations of EC surfaces by means of two variational principles, one of them being that they are optimal for diffusive transport. Several examples of EC surfaces are considered. Remarkably, they are often very well approximated by certain minimal surfaces. We give a dynamical explanation for the emergence of Scherk's surface in certain cases, a structure that has been observed numerically previously in [De Wit et al., 1997].

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