Modulating charge transport characteristics of bis-azaisoindigo-based D–A conjugated polymers through energy level regulation and side chain optimization

2019 ◽  
Vol 7 (25) ◽  
pp. 7618-7626 ◽  
Author(s):  
Kaiqiang Huang ◽  
Xue Zhao ◽  
Yuchang Du ◽  
Sanghyo Kim ◽  
Xiaohong Wang ◽  
...  

Six donor–acceptor (D–A) conjugated polymers, P1–P6, based on the novel electron acceptors bis-isoindigo (BIID) and bis-azaisoindigo (BAID), were designed and synthesized for solution-processed organic field-effect transistors.

2020 ◽  
Vol 8 (4) ◽  
pp. 1398-1404
Author(s):  
Guobing Zhang ◽  
Ruikun Chen ◽  
Yue Sun ◽  
Boseok Kang ◽  
Mingxiang Sun ◽  
...  

Two acceptor–donor–acceptor small molecules based on fused ring as donor, and hemi-isoindigo units as acceptors were synthesized and characterized for solution-processed organic field-effect transistors.


2017 ◽  
Vol 5 (39) ◽  
pp. 10332-10342 ◽  
Author(s):  
Yeong-A Kim ◽  
Minji Kang ◽  
Ye-Jin Jeon ◽  
Kyeongil Hwang ◽  
Yeon-Ju Kim ◽  
...  

Four donor–acceptor (D–A) type conjugated polymers were synthesized for organic photovoltaics and organic field effect transistors.


2018 ◽  
Vol 5 (3) ◽  
pp. 172025 ◽  
Author(s):  
Inori Ohnishi ◽  
Kazuhito Hashimoto ◽  
Keisuke Tajima

Linear polydimethylsiloxane (PDMS) was investigated as a solubilizing group for π-conjugated polymers with the aim of combining high solubility in organic solvents with the molecular packing in solid films that is advantageous for charge transport. Diketopyrrolopyrrole-based copolymers with different contents and substitution patterns of the PDMS side chains were synthesized and evaluated for application in organic field-effect transistors. The PDMS side chains greatly increased the solubility of the polymers and led to shorter d -spacings of the π-stacking in the thin films compared with polymers containing conventional branched alkyl side chains.


RSC Advances ◽  
2015 ◽  
Vol 5 (86) ◽  
pp. 70319-70322 ◽  
Author(s):  
Shaowei Shi ◽  
Keli Shi ◽  
Gui Yu ◽  
Xiaoyu Li ◽  
Haiqiao Wang

Two naphthodifuran-based donor–acceptor copolymers are presented. Via reasonable main-chain modification and side-chain engineering, remarkably dense π–π stacking spacings (2 V−1 s−1 are achieved at a moderate annealing temperature of 120 °C.


2018 ◽  
Vol 9 (1) ◽  
pp. 28-37 ◽  
Author(s):  
Fang-Ju Lin ◽  
Song-Di Lin ◽  
Chih-Hao Chin ◽  
Wei-Tsung Chuang ◽  
Chain-Shu Hsu

Novel bulky and rigid vinyl-donor–DPP acceptor (D–A) polymers, poly[dithieno[3,2-b:2′,3′-d]pyrrole vinylene dithieno[3,2-b:2′,3′-d]pyrrolediketopyrrolopyrrole] (PB(DTP)V-DPP) were synthesized.


2016 ◽  
Vol 7 (1) ◽  
pp. 235-243 ◽  
Author(s):  
Na Zhao ◽  
Na Ai ◽  
Mian Cai ◽  
Xiao Wang ◽  
Jian Pei ◽  
...  

A series of donor–acceptor type of polymers based on thiophene-fused isoindigo were synthesized, among which the fully conjugated PTII-T showed well balanced ambipolar OFET performance.


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