Self-assembly of isotropic colloids into colloidal strings, Bernal spiral-like, and tubular clusters

2020 ◽  
Vol 56 (46) ◽  
pp. 6309-6312 ◽  
Author(s):  
Yong Guo ◽  
Bas G. P. van Ravensteijn ◽  
Willem K. Kegel

Colloidal strings, Bernal spiral-like, and tubular clusters comprising isotropic colloids are formed in an aqueous environment by competing interactions.

2015 ◽  
Vol 17 (7) ◽  
pp. 5413-5420 ◽  
Author(s):  
Susan James ◽  
Michelle K. Quinn ◽  
Jennifer J. McManus

Anisotropy is central to protein self-assembly. The kinetic and thermodynamic properties of proteins in which competing interactions exist due to the anisotropic or patchy nature of the protein surface have been explored using a phase diagram approach.


Author(s):  
I. Novak ◽  
L. Truskinovsky

The complexity of fracture-induced segmentation in elastically constrained cohesive (fragile) systems originates from the presence of competing interactions. The role of discreteness in such phenomena is of interest in a variety of fields, from hierarchical self-assembly to developmental morphogenesis. In this paper, we study the analytically solvable example of segmentation in a breakable mass–spring chain elastically linked to a deformable lattice structure. We explicitly construct the complete set of local minima of the energy in this prototypical problem and identify among them the states corresponding to the global energy minima. We show that, even in the continuum limit, the dependence of the segmentation topology on the stretching/pre-stress parameter in this problem takes the form of a devil's type staircase. The peculiar nature of this staircase, characterized by locking in rational microstructures, is of particular importance for biological applications, where its structure may serve as an explanation of the robustness of stress-driven segmentation. This article is part of the themed issue ‘Patterning through instabilities in complex media: theory and applications.’


2013 ◽  
Vol 117 (38) ◽  
pp. 19426-19435 ◽  
Author(s):  
Chris R. L. Chapman ◽  
Elvis C.M. Ting ◽  
Ashley Kereszti ◽  
Irina Paci

Soft Matter ◽  
2017 ◽  
Vol 13 (44) ◽  
pp. 8055-8063 ◽  
Author(s):  
Andrew P. Santos ◽  
Jakub Pȩkalski ◽  
Athanassios Z. Panagiotopoulos

Colloidal clustering driven by isotropic competing interactions can resemble surfactant micellization or exhibit novel, non-pressure-affecting clustering, depending on conditions.


2013 ◽  
Vol 12 (4) ◽  
pp. 282-291 ◽  
Author(s):  
Jun Kawai ◽  
Seema Jagota ◽  
Takeo Kaneko ◽  
Yumiko Obayashi ◽  
Yoshitaka Yoshimura ◽  
...  

AbstractTitan, the largest satellite of Saturn, has a thick atmosphere containing nitrogen and methane. A variety of organic compounds have been detected in the atmosphere, most likely produced when atmospheric gases are exposed to ultraviolet light, electrons captured by the magnetosphere of Saturn and cosmic rays. The Cassini/Huygens probe showed that the average temperature on the surface of Titan is 93.7 K, with lakes of liquid ethane and methane. Sub-surface mixtures of liquid ammonia and water may also be present. We have synthesized complex organic compounds (tholins) by exposing a mixture of nitrogen and methane to plasma discharges, and investigated their interactions with several different liquids that simulate Titan's liquidosphere. We found that coacervates formed when tholins were extracted in non-polar solvents followed by exposure to aqueous ammonia solutions. The results suggest that coacervates can self-assemble in Titan's liquidosphere which have the potential to undergo further chemical evolution. Similar processes are likely to occur in the early evolution of habitable planets when tholin-like compounds undergo phase separation into microscopic structures dispersed in a suitable aqueous environment.


2006 ◽  
Vol 947 ◽  
Author(s):  
Kai de lang Kristiansen ◽  
Eldrid Svåsand ◽  
Geir Helgesen ◽  
Arne T. Skjeltorp

ABSTRACTNonmagnetic microspheres dispersed in a ferrofluid are denoted magnetic holes. When the spheres are confined to a monolayer between two plane, parallel plates and subjected to AC magnetic fields, they show a variety of dynamical behaviors and assemblages. The magnetic interactions between the particles and their dynamical behavior are influenced by the boundaries and the degree of confinement. We have derived analytical results for the pair-wise competing interactions, and these compare favorably with experimental results.It is also possible to characterize the self-assembly and dynamics of the spheres by the theory of braids. It involves classifying different ways of tracing curves in space. The essentially two-dimensional motion of a sphere can be represented as a curve in a three-dimensional space-time diagram, and so several spheres in motion produce a set of braided curves. The dynamical modes can then be described in terms of braid-words. We also present a few other examples on how this system can be used to study dynamical processes.


Soft Matter ◽  
2021 ◽  
Author(s):  
Oksana Patsahan ◽  
Marek Litniewski ◽  
Alina Ciach

Coexistence lines between gas and ordered phases in binary microsegregating mixtures are studied theoretically and by MD simulations.


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