The development of novel, noble metal-free semiconductor catalysts with high efficiency is of great importance for the degradation of organic compounds. Among them, amorphous materials have been extensively studied for their unique and commercially useful properties. Here, a completely amorphous, noble metal-free photocatalyst C3N4ZnxOy (x, y = 0.32–1.10) was successfully synthesized from urea and ZnO by a simple high-temperature polymerization method. As the Zn content increased, the short-range ordered structures of the amorphous samples were still retained, as revealed by XPS, FTIR, and ssNMR. Meanwhile, the -CN3 structures were observed to be gradually destroyed, which may make the amorphous state more favorable for photocatalytic reactions. Compared with g-C3N4, the amorphous samples showed significantly reduced intensities in the photoluminescence spectra, indicating that the recombination rate of the photo-generated charge carriers was greatly reduced. It was confirmed that the optimized sample (C3N4Zn0.61O0.61) achieved a photocatalytic efficiency of 86.1% in the degradation of tetracycline hydrochloride under visible light irradiation within 1 h. This is about 2 times higher than that of both g-C3N4 and ZnO. This study emphasizes the importance of the amorphous structure in photocatalytic reactions, and this synthetic strategy may provide an effective model for designing other novel catalysts.
Photocatalytic hydrogen production from a noble metal free system based on a water soluble porphyrin derivative and a cobaloxime catalyst
