Chromous carbonates containing a square-grid layer of {Cr2(CO3)4}n4n− based on a dichromium(ii,ii) paddlewheel core

2021 ◽  
Vol 50 (7) ◽  
pp. 2387-2392
Author(s):  
Zhi-Qiang Dong ◽  
Jian-Hui Yang ◽  
Bin Liu

The structural, spectroscopic and magnetic properties of chromous carbonates with a square-grid layer structure constructed from Cr2(CO3)44− paddlewheel units.

CrystEngComm ◽  
2020 ◽  
Vol 22 (8) ◽  
pp. 1321-1329 ◽  
Author(s):  
Gui-lei Liu ◽  
Jian-Biao Song ◽  
Qi-ming Qiu ◽  
Hui Li

Three supramolecular isomeric Cu(ii) networks with different metal fragments and ligand conformations were obtained by the adjustment of solvent molecules.


2003 ◽  
Vol 2003 (20) ◽  
pp. 3820-3825 ◽  
Author(s):  
Sandip Chakrabarti ◽  
Swapan K. Pati ◽  
Mark A. Green ◽  
Srinivasan Natarajan

2014 ◽  
Vol 43 (9) ◽  
pp. 3521 ◽  
Author(s):  
Su-Yun Zhang ◽  
Zhang-Zhen He ◽  
Ming Yang ◽  
Wen-Bin Guo ◽  
Ying-Ying Tang

1985 ◽  
Vol 1 (7) ◽  
pp. 808-809
Author(s):  
M. Michijima ◽  
H. Fujii ◽  
T. Okamoto

2002 ◽  
Vol 4 (11-12) ◽  
pp. 1499-1508 ◽  
Author(s):  
Jacques Darriet ◽  
Werner Massa ◽  
Jürgen Pebler ◽  
Ronald Stief

2021 ◽  
Vol 7 (5) ◽  
pp. 73
Author(s):  
Hongdao Li ◽  
Jiao Lu ◽  
Jing Xie ◽  
Pei Jing ◽  
Licun Li

Two multi-dentate nitronyl nitroxide radicals, namely, bisNITPhPy ([5-(4-pyridyl)-1,3-bis(1′-oxyl-3′-oxido-4′,4′,5′,5′-tetramethyl-4,5-hydro-1H-imidazol-2-yl)]benzene) and NIT-3Py-5-4Py (2-{3-[5-(4-pyridyl)]pyridyl}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide), were assembled with CuII ions to obtain two-dimensional heterospin 2p–3d coordination polymers [Cu7(hfac)14(bisNITPhPy)2]n (1) and [Cu2(hfac)4(NIT-3Py-5-4Py)]n (2) (hfac: hexafluoroacetylacetonate). In both compounds, the bisNITPhPy and NIT-3Py-5-3Py radicals acted as pentadentate and tetradentate ligands, respectively, to connect with CuII ions, generating a 2D layer structure. The analysis of the magnetic behavior indicated that strong antiferromagnetic coupling and ferromagnetic interaction (J = 17.1 cm−1) coexisted in 1. For 2, there were ferromagnetic couplings between the CuII ion and NO group, as well as the CuII ion and radical via the pyridine ring with J1 = 32.8 and J2 = 2.2 cm−1, respectively.


1993 ◽  
Vol 313 ◽  
Author(s):  
S. Tsunashima ◽  
M. Jimbo ◽  
T. Kanda ◽  
S. Goto ◽  
S. Uchiyama

ABSTRACTGiant Magnetoresistance (GMR) and soft magnetic properties together with their structural characteristics were investigated for Ni66Fe16Co18/Cu Multilayers. The Multilayers were prepared by the conventional rf sputtering method on glass or Si substrates using various buffer layers including Fe, NiFeCo, NiFe and CoZr. Although Most of the multilayers exhibited (111) preferred orientation, Fe buffered multilayers showed a considerable (200) X-ray diffraction peak at Cu thicknesses around 1 nm and 2.2 nm which corresponded to the peak positions of GMR. By using fee or amorphous underlayers the (200) diffraction intensity decreased while antiferromagnetic coupling strength was much reduced. Cross-sectional transmission electron micrograph revealed that the (100) oriented multilayer was grown on the (100) oriented Fe underlayer. By controlling the crystal orientation and the layer structure, significantly large magnetoresistance ratio of more than 10 % can be achieved in a field as low as 30 Oe.


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