Amine-functionalized metal–organic framework-based Pd nanoparticles: highly efficient multifunctional catalysts for base-free aerobic oxidation of different alcohols

2020 ◽  
Vol 44 (44) ◽  
pp. 19113-19121
Author(s):  
Abu Taher ◽  
Md. Abu Bin Hasan Susan ◽  
Noorjahan Begum ◽  
Ik-Mo Lee
Keyword(s):  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Pd Nanoparticles ◽  
Highly Efficient ◽  
Amine Functionalized ◽  
Multifunctional Catalysts ◽  
Aromatic Alcohols ◽  
Metal Organic ◽  
Organic Framework

Metal–organic framework-based palladium nanoparticles are found to be highly efficient multifunctional catalysts for the base-free aerobic oxidation of different aliphatic, aromatic and hetero-aromatic alcohols.

Ferrocenyl metal–organic framework hollow microspheres for in situ loading palladium nanoparticles as a heterogeneous catalyst

2019 ◽  
Vol 48 (24) ◽  
pp. 8995-9003 ◽  
Author(s):  
Zheng Deng ◽  
Yi Guo ◽  
Zhuoyi Li ◽  
Xiaobin Wang ◽  
Xinsheng Peng ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Hollow Microspheres ◽  
Highly Efficient ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

Zn–Fc MOF hollow microspheres were prepared for the in situ reduction of Pd2+ into Pd nanoparticles as a highly efficient heterogeneous catalyst.

Metal organic framework derived magnetic porous carbon composite supported gold and palladium nanoparticles as highly efficient and recyclable catalysts for reduction of 4-nitrophenol and hydrodechlorination of 4-chlorophenol

2014 ◽  
Vol 2 (44) ◽  
pp. 18775-18785 ◽  
Author(s):  
Zhengping Dong ◽  
Xuanduong Le ◽  
Yansheng Liu ◽  
Chunxu Dong ◽  
Jiantai Ma
Keyword(s):  
Porous Carbon ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Catalyst Support ◽  
Carbon Composite ◽  
Highly Efficient ◽  
Recyclable Catalysts ◽  
Metal Organic ◽  
Supported Gold ◽  
Organic Framework

A magnetic porous carbon composite which has been synthesized from MOF is used as a catalyst support to fabricate Au and Pd NP based nanocatalysts.

Incorporation of a Ru complex into an amine-functionalized metal–organic framework for enhanced activity in photocatalytic aerobic benzyl alcohol oxidation

2019 ◽  
Vol 9 (6) ◽  
pp. 1511-1517 ◽  
Author(s):  
Yusuke Isaka ◽  
Yoshifumi Kondo ◽  
Yasutaka Kuwahara ◽  
Kohsuke Mori ◽  
Hiromi Yamashita
Keyword(s):  
Benzyl Alcohol ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Alcohol Oxidation ◽  
Benzyl Alcohol Oxidation ◽  
Ru Complex ◽  
Amine Functionalized ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic ◽  
Organic Framework

Encapsulation of [Ru(bpy)3]2+ in the cavity of a metal–organic framework was found to enhance its activity in the photocatalytic aerobic oxidation of benzyl alcohol.

Improved activity of palladium nanoparticles using a sulfur-containing metal–organic framework as an efficient catalyst for selective aerobic oxidation in water

2017 ◽  
Vol 41 (13) ◽  
pp. 5846-5852 ◽  
Author(s):  
Sedigheh Abedi ◽  
Ali Morsali
Keyword(s):  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Efficient Catalyst ◽  
Metal Organic ◽  
Selective Aerobic Oxidation ◽  
Sulfur Containing ◽  
Organic Framework

Synergism of thiophene and confinement of MOF with time of Pd entrance leads an efficient catalyst for oxidation in water.

Allylic oxidation of olefins with a manganese-based metal–organic framework

2019 ◽  
Vol 21 (13) ◽  
pp. 3629-3636 ◽  
Author(s):  
Jingwen Chen ◽  
Minda Chen ◽  
Biying Zhang ◽  
Renfeng Nie ◽  
Ao Huang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Allylic Oxidation ◽  
Efficient Catalyst ◽  
Mild Conditions ◽  
Highly Efficient ◽  
Oxidation Of Olefins ◽  
Metal Organic ◽  
Selective Aerobic Oxidation ◽  
Organic Framework

Manganese-based CPF-5 as a highly efficient catalyst for the selective aerobic oxidation of cyclohexene to cyclohexenone under mild conditions.

Regulating the size and spatial distribution of Pd nanoparticles supported by the defect engineered metal–organic framework HKUST-1 and applied in the aerobic oxidation of cinnamyl alcohol

2019 ◽  
Vol 9 (14) ◽  
pp. 3703-3710 ◽  
Author(s):  
Penghu Guo ◽  
Qi Fu ◽  
Ceylan Yildiz ◽  
Yen-Ting Chen ◽  
Kevin Ollegott ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Pd Nanoparticles ◽  
Cinnamyl Alcohol ◽  
Pd Catalysts ◽  
Size Regime ◽  
Metal Organic ◽  
Organic Framework

A series of novel Pd@DE-HKUST-1(Cu/Pd) catalysts with different pydc feeding ratios were successfully synthesized. The size regime and the spatial distribution of the Pd NPs can be controlled by the amount of framework incorporated pydc.

scholarly journals Highly efficient metal organic framework (MOF)-based copper catalysts for the base-free aerobic oxidation of various alcohols

RSC Advances ◽  
2017 ◽  
Vol 7 (29) ◽  
pp. 17806-17812 ◽  
Author(s):  
Abu Taher ◽  
Dong Wook Kim ◽  
Ik-Mo Lee
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Alcohol Oxidation ◽  
Copper Catalysts ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

Copper containing metal organic frameworks (MOFs) are found to be highly efficient heterogeneous catalysts for alcohol oxidation.

HIGHLY CATALYTICALLY ACTIVE PALLADIUM NANOPARTICLES INCORPORATED INSIDE METAL-ORGANIC FRAMEWORK PORES BY DOUBLE SOLVENTS METHOD

2012 ◽  
Vol 05 (04) ◽  
pp. 1250039 ◽  
Author(s):  
MAHENDRA YADAV ◽  
ARSHAD AIJAZ ◽  
QIANG XU
Keyword(s):  
Aqueous Solution ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Catalytically Active ◽  
Metal Organic ◽  
Hydrophilic Solvent ◽  
Hydrophobic Solvent ◽  
Catalytic Performances ◽  
Organic Framework

Highly monodispersed palladium (Pd) nanoparticles have been successfully incorporated inside the mesopores of a metal–organic framework (MOF), MIL-101, without deposition of Pd nanoparticles on the external surfaces of framework by using the "double solvents" method, in which cyclohexane is used as a hydrophobic solvent to disperse the mesoporous MOF and an aqueous solution of Pd precursor is used as a hydrophilic solvent to fill the mesopores. The resulting Pd @MIL-101 composite is highly catalytically active for the reduction of 4-nitrophenol (4-NPh) by sodium borohydride ( NaBH4 ). The observed excellent catalytic performances are attributed to the small Pd nanoparticles within the pores of MIL-101.

Synergetic catalysis of palladium nanoparticles encaged within amine-functionalized UiO-66 in the hydrodeoxygenation of vanillin in water

2016 ◽  
Vol 18 (9) ◽  
pp. 2900-2908 ◽  
Author(s):  
Fumin Zhang ◽  
Shuang Zheng ◽  
Qiang Xiao ◽  
Yijun Zhong ◽  
Weidong Zhu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Selective Conversion ◽  
Amine Functionalized ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

Ultrasmall palladium nanoparticles (1.5–2.5 nm) encapsulated within the highly porous and hydrothermally stable amine-functionalized metal–organic framework UiO-66 exhibit excellent catalytic activity for the selective conversion of vanillin to 2-methoxy-4-methylphenol.

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