In situ growth of well-aligned Ni-MOF nanosheets on nickel foam for enhanced photocatalytic degradation of typical volatile organic compounds

Nanoscale ◽  
2020 ◽  
Vol 12 (17) ◽  
pp. 9462-9470 ◽  
Author(s):  
Xin Ding ◽  
Hongli Liu ◽  
Jiangyao Chen ◽  
Meicheng Wen ◽  
Guiying Li ◽  
...  

Well-aligned Ni-MOF nanosheet arrays vertically grown on nickel foam were synthesized via a facile in situ solvothermal strategy, which exhibited remarkably improved photocatalytic activities to typical VOCs under visible light irradiation.

2021 ◽  
Author(s):  
Jingjing Xu ◽  
Yang liu ◽  
xueping li ◽  
Mindong Chen

Direct Z-scheme Bi3TaO7/Zn0.5Cd0.5S composite photocatalysts were successfully prepared via an in-situ growth hydrothermal method. The photocatalytic activities of composites were investigated by the degradation of levofloxacin under visible light. And...


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Fei He ◽  
Seunghyun Weon ◽  
Woojung Jeon ◽  
Myoung Won Chung ◽  
Wonyong Choi

AbstractPhotocatalytic air purification is widely regarded as a promising technology, but it calls for more efficient photocatalytic materials and systems. Here we report a strategy to introduce an in-situ water (self-wetting) layer on WO3 by coating hygroscopic periodic acid (PA) to dramatically enhance the photocatalytic removal of hydrophilic volatile organic compounds (VOCs) in air. In ambient air, water vapor is condensed on WO3 to make a unique tri-phasic (air/water/WO3) system. The in-situ formed water layer selectively concentrates hydrophilic VOCs. PA plays the multiple roles as a water-layer inducer, a surface-complexing ligand enhancing visible light absorption, and a strong electron acceptor. Under visible light, the photogenerated electrons are rapidly scavenged by periodate to produce more •OH. PA/WO3 exhibits excellent photocatalytic activity for acetaldehyde degradation with an apparent quantum efficiency of 64.3% at 460 nm, which is the highest value ever reported. Other hydrophilic VOCs like formaldehyde that are readily dissolved into the in-situ water layer on WO3 are also rapidly degraded, whereas hydrophobic VOCs remain intact during photocatalysis due to the “water barrier effect”. PA/WO3 successfully demonstrated an excellent capacity for degrading hydrophilic VOCs selectively in wide-range concentrations (0.5−700 ppmv).


2003 ◽  
Author(s):  
Michael Loren Thomas ◽  
Robert Clark Hughes ◽  
Ara S Kooser ◽  
Lucas K McGrath ◽  
Clifford Kuofei Ho ◽  
...  

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