Visible-light-driven photocatalytic selective organic oxidation reactions

2020 ◽  
Vol 8 (40) ◽  
pp. 20897-20924 ◽  
Author(s):  
Xue Yang ◽  
Suyuan Zhang ◽  
Peixian Li ◽  
Shuiying Gao ◽  
Rong Cao
Keyword(s):  
Visible Light ◽  
Future Development ◽  
Reaction Mechanisms ◽  
Oxidation Reactions ◽  
Development Trends ◽  
Recent Advances ◽  
The Future ◽  
Visible Light Driven ◽  
Organic Oxidation ◽  
Made In

In this review, we focus on the most recent advances made in visible-light-driven selective organic oxidation transformations and highlighted their reaction mechanisms. Moreover, we discuss the future development trends, challenges, and prospective outlook in detail.

scholarly journals Recent Advances in C-F Bond Cleavage Enabled by Visible Light Photoredox Catalysis

Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 7051
Author(s):  
Lei Zhou
Keyword(s):  
Visible Light ◽  
Future Development ◽  
Bond Cleavage ◽  
Bond Formation ◽  
Environmentally Benign ◽  
Personal Perspective ◽  
Photoredox Catalysis ◽  
Recent Advances ◽  
The Future ◽  
The Creation

The creation of new bonds via C-F bond cleavage of readily available per- or oligofluorinated compounds has received growing interest. Using such a strategy, a myriad of valuable partially fluorinated products can be prepared, which otherwise are difficult to make by the conventional C-F bond formation methods. Visible light photoredox catalysis has been proven as an important and powerful tool for defluorinative reactions due to its mild, easy to handle, and environmentally benign characteristics. Compared to the classical C-F activation that proceeds via two-electron processes, radicals are the key intermediates using visible light photoredox catalysis, providing new modes for the cleavage of C-F bonds. In this review, a summary of the visible light-promoted C-F bond cleavage since 2018 was presented. The contents were classified by the fluorosubstrates, including polyfluorinated arenes, gem-difluoroalkenes, trifluoromethyl arenes, and trifluoromethyl alkenes. An emphasis is placed on the discussion of the mechanisms and limitations of these reactions. Finally, my personal perspective on the future development of this rapidly emerging field was provided.

scholarly journals 6D Pose Estimation of Objects: Recent Technologies and Challenges

2020 ◽  
Vol 11 (1) ◽  
pp. 228
Author(s):  
Zaixing He ◽  
Wuxi Feng ◽  
Xinyue Zhao ◽  
Yongfeng Lv
Keyword(s):  
Pose Estimation ◽  
Future Development ◽  
Important Task ◽  
Development Trends ◽  
Detailed Review ◽  
The Future ◽  
Bin Picking ◽  
3D Information ◽  
Made In

6D pose estimation is a common and important task in industry. Obtaining the 6D pose of objects is the basis for many other functions such as bin picking, autopilot, etc. Therefore, many corresponding studies have been made in order to improve the accuracy and enlarge the range of application of various approaches. After several years of development, the methods of 6D pose estimation have been enriched and improved. Although some predecessors have analyzed the methods and summarized them in detailed, there have been many new breakthroughs in recent years. To understand 6D pose estimation better, this paper will make a new and more detailed review of 6D pose estimation. We divided these methods into two approaches: Learning-based approaches and non-learning-based approaches, including 2D-information-based approach and 3D-information-based approach. Additionally, we introduce the challenges that exist in 6D pose estimation. Finally, we compare the performance of different methods qualitatively and discuss the future development trends of the 6D pose estimation.

Recent Advances in Catalysts Based on Molecular Cubanes for Visible Light-Driven Water Oxidation

2020 ◽  
Vol 36 (3) ◽  
pp. 1905025-0 ◽  
Author(s):  
Wanjun Sun ◽  
◽  
Junqi Lin ◽  
Xiangming Liang ◽  
Junyi Yang ◽  
...  
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Recent Advances ◽  
Visible Light Driven

Recent advances in non-metals-doped TiO2 nanostructured photocatalysts for visible-light driven hydrogen production, CO2 reduction and air purification

2019 ◽  
Vol 44 (26) ◽  
pp. 13022-13039 ◽  
Author(s):  
Shivaraj B. Patil ◽  
Patil S. Basavarajappa ◽  
Nagaraju Ganganagappa ◽  
M.S. Jyothi ◽  
A.V. Raghu ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Visible Light ◽  
Co2 Reduction ◽  
Air Purification ◽  
Doped Tio2 ◽  
Recent Advances ◽  
Visible Light Driven

Recent progress in high-performance photo-detectors enabled by the pulsed laser deposition technology

2020 ◽  
Vol 8 (15) ◽  
pp. 4988-5014 ◽  
Author(s):  
Bing Wang ◽  
Zhi Bin Zhang ◽  
Shi Peng Zhong ◽  
Zhao Qiang Zheng ◽  
Ping Xu ◽  
...  
Keyword(s):  
Pulsed Laser Deposition ◽  
Future Development ◽  
High Performance ◽  
Recent Progress ◽  
Pulsed Laser ◽  
Laser Deposition ◽  
Development Trends ◽  
Recent Advances ◽  
Photo Detectors ◽  
Deposition Technology

This review introduces recent advances in the materials, fabrication and application of pulsed-laser deposition for high performance photo-detectors from an overall perspective. Challenges and future development trends are also discussed.

scholarly journals Recent advances in visible-light-driven organic reactions

2017 ◽  
Vol 4 (3) ◽  
pp. 359-380 ◽  
Author(s):  
Qiang Liu ◽  
Li-Zhu Wu
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Environmental Benefits ◽  
Organic Reactions ◽  
Light Sources ◽  
Recent Advances ◽  
Visible Light Driven ◽  
Hydrogen Evolution Reactions ◽  
Green Chemical Synthesis ◽  
Powerful Strategy

Abstract In recent years, visible-light-driven organic reactions have been experiencing a significant renaissance in response to topical interest in environmentally friendly green chemical synthesis. The transformations using inexpensive, readily available visible-light sources have come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In this review, we focus on recent advances in the development of visible-light-driven organic reactions, including aerobic oxidation, hydrogen-evolution reactions, energy-transfer reactions and asymmetric reactions. These key research topics represent a promising strategy towards the development of practical, scalable industrial processes with great environmental benefits.

scholarly journals Recent advances in visible-light-driven conversion of CO2 by photocatalysts into fuels or value-added chemicals

2020 ◽  
Vol 3 ◽  
pp. 46-59 ◽  
Author(s):  
Yu Gao ◽  
Kun Qian ◽  
Baotong Xu ◽  
Zheng Li ◽  
Jiaxin Zheng ◽  
...  
Keyword(s):  
Visible Light ◽  
Value Added ◽  
Recent Advances ◽  
Visible Light Driven

scholarly journals Correction: A Bpp-based dinuclear ruthenium photocatalyst for visible light-driven oxidation reactions

2020 ◽  
Vol 10 (20) ◽  
pp. 7068-7068
Author(s):  
Seán Hennessey ◽  
Pau Farràs ◽  
Jordi Benet-Buchholz ◽  
Antoni Llobet
Keyword(s):  
Visible Light ◽  
Oxidation Reactions ◽  
Visible Light Driven ◽  
Dinuclear Ruthenium

Correction for ‘A Bpp-based dinuclear ruthenium photocatalyst for visible light-driven oxidation reactions’ by Seán Hennessey et al., Catal. Sci. Technol., 2019, 9, 6760–6768, DOI: 10.1039/C9CY01796H.

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