A multi-functional composite nitrogen carrier for ammonia production via a chemical looping route

2021 ◽  
Author(s):  
Sheng Feng ◽  
Wenbo Gao ◽  
Qianru Wang ◽  
Yeqin Guan ◽  
Hanxue Yan ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Synthesis Process ◽  
Chemical Looping ◽  
Ammonia Production ◽  
Functional Composite

A chemical looping ammonia synthesis process mediated by a multi-functional nitride–imide composite nitrogen carrier was demonstrated.

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

An intelligent quantitative risk assessment method for ammonia synthesis process

2021 ◽  
Vol 420 ◽  
pp. 129893
Author(s):  
Zijian Liu ◽  
Wende Tian ◽  
Zhe Cui ◽  
Honglong Wei ◽  
Chuankun Li
Keyword(s):  
Risk Assessment ◽  
Ammonia Synthesis ◽  
Assessment Method ◽  
Quantitative Risk Assessment ◽  
Synthesis Process ◽  
Risk Assessment Method

scholarly journals Chemical Looping Method for Production the Feed Gases of Ammonia Synthesis: Thermodynamics

2019 ◽  
Vol 612 ◽  
pp. 022109
Author(s):  
Qi Wang ◽  
Kun Wang ◽  
Jialiang Hua ◽  
Ruijie Peng
Keyword(s):  
Ammonia Synthesis ◽  
Chemical Looping

scholarly journals Chromium-modified cobalt molybdenum nitrides as catalysts for ammonia synthesis

2019 ◽  
Vol 17 (1) ◽  
pp. 127-131
Author(s):  
Paweł Adamski ◽  
Marlena Nadziejko ◽  
Agata Komorowska ◽  
Adam Sarnecki ◽  
Aleksander Albrecht ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Specific Surface ◽  
Surface Area ◽  
Chromium Content ◽  
Ammonia Synthesis ◽  
Chromium Concentration ◽  
Synthesis Process ◽  
Pure Cobalt ◽  
Molybdenum Nitrides ◽  
Chromium Compounds

AbstractThe influence of chromium compounds on the properties of cobalt molybdenum nitrides was studied. CoMoO4 obtained by precipitation from cobalt and molybdenum salts was modified by the addition of chromium(III) nitrate. A mixture of cobalt-molybdenum nitrides, Co2Mo3N and Co3Mo3N, was formed by ammonolysis of modified CoMoO4. The concentration of Co2Mo3N decreases with increasing chromium content. The specific surface area of cobalt molybdenum nitrides consisting of 2 wt% of Cr atoms increased by 50% in comparison to pure cobalt molybdenum nitrides. The catalytic activity of obtained catalysts in ammonia synthesis process decreases with rising of chromium concentration.

scholarly journals Control structure design for the ammonia synthesis process

2008 ◽  
Vol 32 (12) ◽  
pp. 2920-2932 ◽  
Author(s):  
Antonio Araújo ◽  
Sigurd Skogestad
Keyword(s):  
Control Structure ◽  
Ammonia Synthesis ◽  
Structure Design ◽  
Synthesis Process
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