In situ thermally induced reduction of silver nitrate by polyvinyl alcohol to prepare a three-dimensional porous Ag substrate with excellent adsorption and surface-enhanced Raman scattering properties

2020 ◽  
Vol 8 (19) ◽  
pp. 6478-6487 ◽  
Author(s):  
Bin Yuan ◽  
Jia Guo ◽  
Shibing Bai

A 3D porous silver substrate prepared using a PVA/AgNO3 composite film has excellent SERS properties.

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Evgeny Melekhov ◽  
Tatjana Penn ◽  
Tobias Weidauer ◽  
Valerius Abb ◽  
Martin Kammler ◽  
...  

Abstract In this work, a simple two-step method to create tunable self-assembled three-dimensional nanostructure array-like nanoantennas directly on the tip of an optical quartz glass fiber is described. The structures are prepared by using dry etching of the fiber tip. For the etching process, gold nanoparticles fabricated by thermal dewetting technique were used as template. The structures are applied as sensors for label-free analysis of organic substances in ppb range, such as drug residues in liquid solutions. The measurements are carried out by a portable Raman device with an exchangeable sensor head utilizing the SERS-effect. This method allows in situ applications. In order to characterize the SERS cells, para-thiocresol and diclofenac sodium are used as model substances. For optimization of the substrate performance, different thicknesses of the dewetting-layer (6, 9, 12 nm), different etching times for formation of the pillars (6, 8, 10 and 12 min), and different thicknesses of SERS-metallization (25, 50, 75 nm) of gold and silver are compared. In order to show the applicability of the structure on the tip of a fiber, measurements from the upper side and from the underside of the substrate on quartz plates are compared. Reproducible SERS enhancement factors up to 10 7 {10^{7}} were achieved.


2019 ◽  
Vol 7 (48) ◽  
pp. 15259-15268 ◽  
Author(s):  
Lingling Zhang ◽  
Xiaodie Li ◽  
Weihua Liu ◽  
Rui Hao ◽  
Hongrui Jia ◽  
...  

In this study, we demonstrated a flexible transparent three-dimensional (3D) ordered micro-hemisphere (MHS) array PDMS film with self-assembled Au nanoparticles (NPs) (an Au NP-MHS array film) as a surface-enhanced Raman scattering (SERS) platform for the in situ detection of pesticides in food.


2022 ◽  
Author(s):  
Sha Li ◽  
Zezhou Wang ◽  
Yunpeng Shao ◽  
Kai Zhang ◽  
Linyu Mei ◽  
...  

In this paper, a highly active surface enhanced Raman scattering (SERS) substrate based on three-dimensional (3D) dendritic silver nanostructure was constructed in microfluidic channel by one-step electrodisplacement reaction for in-situ...


2017 ◽  
Vol 5 (2) ◽  
pp. 463-469 ◽  
Author(s):  
Magdalena Wrona ◽  
Jesús Salafranca ◽  
Cristina Nerín

A silver substrate for SERS generatedin situon an oxo-biodegradable polyethylene film for assessment of its oxidation upon exposure to different agents.


Nanoscale ◽  
2015 ◽  
Vol 7 (40) ◽  
pp. 17079-17087 ◽  
Author(s):  
Xiang Zhang ◽  
Chunsheng Shi ◽  
Enzuo Liu ◽  
Jiajun Li ◽  
Naiqin Zhao ◽  
...  

Nitrogen-doped graphene network supported graphene shell encapsulated Cu nanoparticles for surface-enhanced Raman scattering were constructed by in situ chemical vapor deposition.


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