Facile fabrication of ultrathin graphene film with ultrahigh electrical conductivity and superb electromagnetic interference shielding effectiveness

2021 ◽  
Vol 9 (1) ◽  
pp. 214-222
Author(s):  
Xiaojing Liu ◽  
Wenyu Wu ◽  
Bin Guo ◽  
Minghao Cui ◽  
Huaxin Ma ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Self Assembly ◽  
Electromagnetic Interference ◽  
Graphene Film ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Graphene Films ◽  
Facile Fabrication ◽  
Electromagnetic Interference Shielding Effectiveness

Graphene films prepared through a self-assembly of graphene oxide and its derivatives have been recently explored for electromagnetic interference (EMI) shielding applications.

Graphene Films for Flexible EMI Shielding Materials with Cross-Linked Structure via Reaction with Diamine Monomers

NANO ◽  
2020 ◽  
Vol 15 (12) ◽  
pp. 2050157
Author(s):  
Shaofeng lin ◽  
Qing Zheng ◽  
Bowen Lei ◽  
Jianwei Zhang ◽  
Dazhi Jiang
Keyword(s):  
Electrical Conductivity ◽  
Self Assembly ◽  
Electromagnetic Interference ◽  
Nitrogen Doping ◽  
Graphene Film ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Xps Spectra ◽  
Emi Shielding Effectiveness ◽  
Graphene Films

Three kinds of diamine monomers [ethylenediamine, butylenediamine and [Formula: see text]-phenylenediamine (PPD)] are adopted to cross-link carboxylated graphene (GP-COOH) sheets through filtration with a vacuum-assisted self-assembly technique, to fabricate highly conductive and excellent electromagnetic interference (EMI) shielding films. XRD spectroscopy of cross-linked graphene films exhibits higher interlayer [Formula: see text]-spacing than the GP-COOH film. Results of FTIR and XPS spectroscopies indicate that diamine monomers are chemically grafted to the GP-COOH sheets through nucleophilic substitution reactions. Compared with that of the GP-COOH film, electrical conductivity of the PPD-cross-linked graphene film (GP-PPD) is remarkably improved from 69.7[Formula: see text]S/cm to 248.6[Formula: see text]S/cm, attributed to the decrease of junction contact resistance between adjacent graphene sheets, nitrogen doping effect and repair of defects. Higher nitrogen content and C/O ratio are observed in the XPS spectra of the GP-PPD film, leading to higher electrical conductivity than the remaining two amine-modified graphene films. The GP-PPD film also demonstrates excellent EMI shielding performance, with EMI shielding effectiveness (SE) of 26.5 dB at a thickness of 12.5[Formula: see text][Formula: see text]m, which is also better than the others. The outstanding EMI performance of the PPD-cross-linked graphene film is mainly ascribed to the enhanced electrical conductivity and modified electronic structure with nitrogen doping.

Electromagnetic interference shielding effectiveness of polypyrrole-silver nanocomposite films on silane-modified flexible sheet

2021 ◽  
pp. 095400832110645
Author(s):  
Karim Benzaoui ◽  
Achour Ales ◽  
Ahmed Mekki ◽  
Abdelhalim Zaoui ◽  
Boudjemaa Bouaouina ◽  
...  
Keyword(s):  
Surface Treatment ◽  
Electromagnetic Interference ◽  
Nanocomposite Films ◽  
Electrical Characteristics ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Silver Nanocomposite ◽  
Electromagnetic Interference Shielding Effectiveness ◽  
Emi Se

The conventional electromagnetic interference (EMI) shielding materials are being gradually replaced by a new generation of supported conducting polymer composites (CPC) films due to their many advantages. This work presents a contribution on the effects of silane surface–modified flexible polypyrrole-silver nanocomposite films on the electromagnetic interference shielding effectiveness (EMI-SE). Thus, the UV-polymerization was used to in-situ deposit the PPy-Ag on the biaxial oriented polyethylene terephthalate (BOPET) flexible substrates whose surfaces were treated by 3-aminopropyltrimethoxysilane (APTMS). X-ray Photoelectron Spectroscopy (XPS) analyzes confirmed the APTMS grafting procedure. Structural, morphological, thermal, and electrical characteristics of the prepared films were correlated to the effect of substrate surface treatment. Thereafter, EMI-SE measurements of the elaborated films were carried out as per ASTM D4935 standard for a wide frequency band extending from 50 MHz to 18 GHz. The obtained results confirmed that the APTMS-treated BOPET film exhibit higher EMI shielding performance and better electrical characteristics compared to the untreated film. In fact, a 32% enhancement of EMI-SE was noted for the treated films compared to the untreated ones. Overall, these results put forward the role played by the surface treatment in strengthening the position of flexible PPy-Ag supported films as high-performance materials in electronic devices and electromagnetic interference shielding applications.

Flexible, conductive, porous, fibrillar polymer–gold nanocomposites with enhanced electromagnetic interference shielding and mechanical properties

2017 ◽  
Vol 5 (5) ◽  
pp. 1095-1105 ◽  
Author(s):  
Jun Li ◽  
Hu Liu ◽  
Jiang Guo ◽  
Zhen Hu ◽  
Zhijiang Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Gold Nanoparticles ◽  
Self Assembly ◽  
Electromagnetic Interference ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Emi Shielding Effectiveness ◽  
Conductive Nanocomposites ◽  
Gold Nanocomposites

Flexible lightweight conductive nanocomposites prepared by self-assembly of gold nanoparticles on charged polymer nanofibers show enhanced EMI shielding effectiveness and mechanical properties.

Microwave Irradiation of Graphene Aerogel and Its Use on the Electromagnetic Interference Shielding of BMI Nanocomposites

NANO ◽  
2020 ◽  
Vol 15 (11) ◽  
pp. 2050143
Author(s):  
Bowen Feng ◽  
Wei Li ◽  
Fei Xue ◽  
Xingyu Tong ◽  
Jiaying Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
Electromagnetic Interference ◽  
Chemical Reduction ◽  
Three Dimensional ◽  
Microwave Treatment ◽  
Shielding Effectiveness ◽  
Electromagnetic Interference Shielding ◽  
Graphene Aerogels ◽  
Electromagnetic Interference Shielding Effectiveness ◽  
Emi Se

In this work, graphene aerogels (GAs) with three-dimensional interconnected networks were prepared by chemical reduction and self-assembly of graphene oxide sheets. After microwave treatment, obtained microwave reduced graphene aerogels (MRGAs) were used in the preparation of bismaleimide (BMI) composites. The results show that the microwave treatment significantly enhanced the quality of GAs, and the three-dimensional networks in the GAs were well retained. Moreover, the MRGAs were highly efficient in endowing BMI with high electrical conductivity and excellent electromagnetic interference shielding effectiveness (EMI SE). The conductivity of MRGA/BMI composites was 42–68% higher than that of GA/BMI composites. When the filler content is 1.6 wt.%, the EMI SE of MRGA/BMI composite was 32.3% higher than that of GA/BMI composite in the X band.

Flexible few-layered graphene/poly vinyl alcohol composite sheets: synthesis, characterization and EMI shielding in X-band through the absorption mechanism

RSC Advances ◽  
2015 ◽  
Vol 5 (46) ◽  
pp. 36498-36506 ◽  
Author(s):  
Sandeep K. Marka ◽  
Bashaiah Sindam ◽  
K. C. James Raju ◽  
Vadali V. S. S. Srikanth
Keyword(s):  
Electromagnetic Interference ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Composite Sheet ◽  
Absorption Mechanism ◽  
X Band ◽  
Electromagnetic Interference Shielding Effectiveness

An excellent electromagnetic interference shielding effectiveness of ∼19.5 dB was measured for a 1 mm thick flexible few-layered graphene (FLG)/PVA composite sheet owing to the formation of network-like features by FLG in the PVA matrix.

Large-area potassium-doped highly conductive graphene films for electromagnetic interference shielding

Nanoscale ◽  
2017 ◽  
Vol 9 (47) ◽  
pp. 18613-18618 ◽  
Author(s):  
Erzhen Zhou ◽  
Jiabin Xi ◽  
Yingjun Liu ◽  
Zhen Xu ◽  
Yan Guo ◽  
...  
Keyword(s):  
Electromagnetic Interference ◽  
Graphene Film ◽  
Light Weight ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Large Area ◽  
Graphene Films ◽  
Doped Graphene ◽  
High Flexibility

A potassium-doped graphene film with high flexibility, light weight and superb high EMI shielding performance.

Outstanding electromagnetic interference shielding effectiveness of polyvinylbutyral–polyaniline nanocomposite film

RSC Advances ◽  
2016 ◽  
Vol 6 (82) ◽  
pp. 79058-79065 ◽  
Author(s):  
Pritom J. Bora ◽  
Gaurav Lakhani ◽  
Praveen C. Ramamurthy ◽  
Giridhar Madras
Keyword(s):  
Electromagnetic Interference ◽  
Nanocomposite Film ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Solution Processed ◽  
X Band ◽  
Electromagnetic Interference Shielding Effectiveness ◽  
Polyaniline Nanocomposite ◽  
Ku Band

In this study, we studied the electromagnetic interference (EMI) shielding property of a solution processed polyvinylbutyral–polyaniline nanocomposite (PVBPN) film in the X-band (8.2–12.4 GHz) and Ku-band (12.4–18 GHz) frequency.

scholarly journals Mesocarbon microsphere composites with Fe3O4 nanoparticles for outstanding electromagnetic interference shielding effectiveness

RSC Advances ◽  
2015 ◽  
Vol 5 (54) ◽  
pp. 43279-43289 ◽  
Author(s):  
Ridham Dhawan ◽  
Saroj Kumari ◽  
Rajeev Kumar ◽  
S. K. Dhawan ◽  
Sanjay R. Dhakate
Keyword(s):  
Fe3o4 Nanoparticles ◽  
Electromagnetic Interference ◽  
Shielding Effectiveness ◽  
Emi Shielding ◽  
Electromagnetic Interference Shielding ◽  
Emi Shielding Effectiveness ◽  
Electromagnetic Interference Shielding Effectiveness

In situ, development of mesocarbon microsphere (MCMS) composites with magnetic Fe3O4 nanoparticles for outstanding electromagnetic (EMI) shielding effectiveness.

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