Determination of dopamine based on a temperature-sensitive PMEO2MA and Au@rGO-MWCNT nanocomposite-modified electrode

The Analyst ◽  
2022 ◽  
Author(s):  
Chao Chen ◽  
chenxi Wang ◽  
pengcheng zhao ◽  
Jing Zhang ◽  
Dechong Ma ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Temperature Sensitive ◽  
Ethyl Methacrylate ◽  
Temperature Controlled ◽  
Composite Modification

First, the nanocomposite Au@rGO-MWCNT was synthesized by hydrothermal method. Next, a temperature-controlled composite sensing film was prepared by composite modification of poly(2-(2-methoxyethoxy)ethyl methacrylate) (PMEO2MA) and Au@rGO-MWCNT on a glassy carbon...

scholarly journals Electrochemical determination of ascorbic acid at p-phenylenediamine film-holes modified glassy carbon electrode

2015 ◽  
Vol 80 (9) ◽  
pp. 1161-1175 ◽  
Author(s):  
Bikila Olana ◽  
Shimeles Kitte ◽  
Tesfaye Soreta
Keyword(s):  
Ascorbic Acid ◽  
Detection Limit ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Linear Response ◽  
Modified Electrodes ◽  
Electrochemical Determination ◽  
Carbon Electrode

In this work the determination of ascorbic acid (AA) at glassy carbon electrode (GCE) modified with a perforated film produced by reduction of diazonium generated in situ from p-phenylenediamine (PD) is reported. Holes were intentionally created in the modifier film by stripping a pre-deposited gold nanoparticles. The modified electrodes were electrochemically characterized by common redox probes: hydroquinone, ferrocyanide and hexamineruthenium(III). The cyclic voltammetric and amperometric response of AA using the modified electrodes was compared with that of bare GCE. The bare GCE showed a linear response to AA in the concentration range of 5 mM to 45 mM with detection limit of 1.656 mM and the modified GCE showed a linear response to AA in the concentration range of 5 ?M to 45 ?M with detection limit of 0.123 ?M. The effect of potential intereferents on amperometric signal of AA at the modified GCE was examined and found to be minimal. The inter-electrode reproducibility, stability, and accuracy were determined. The modified electrode showed excellent inter-electrode reproducibility, accuracy and stability. The modified electrode reported is a promising candidate for use in electroanalysis of AA.

scholarly journals Electrochemical Determination of Trace Pb (II) by The Modified Glassy Carbon Electrode Compositing MultiWalled Carbon Nanotubes-Nafion-Bi Film

2020 ◽  
pp. 1-12
Keyword(s):  
Carbon Nanotubes ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Anodic Stripping Voltammetry ◽  
Electrochemical Sensing ◽  
Carbon Electrode ◽  
Bismuth Film ◽  
Modified Glassy Carbon Electrode

A modified glassy carbon electrode (GCE) compositing multi-walled carbon nanotubes (MWCNTs), Nafion and bismuth film was prepared and applied for the sensitive detection of trace Pb (II). MWCNTs were dispersed into ethanol by ultrasonication in the presence of Nafion and the nanotubes are coated onto the bare GCE. After that, an extra Nafion adhesion agent is added to the electrode. By the in situ plating, a bismuth film was fabricated on the MWCNTs-NA/GCE, making the desired electrode, MWCNTs-NA-Bi/GCE. The modified electrode was characterized by differential pulse anodic stripping voltammetry, scanning electron microscopy, and cyclic voltammetry. A deposition potential of –1.4 V (vs. Ag/AgCl) and a deposition time of 300 s were applied to the working electrode under stirred conditions after optimizing. Nanotubes and Nafion concentrations and pH were carefully optimized to determine trace lead ions by using the electrode as an electrochemical-sensing platform. Nafion effectively increased the stability and adhesivity of the composite film. The MWCNTs-NA-Bi film modified electrode can remarkably increase the anodic peak current of Pb2+. The sensitivity of MWCNTs-NA-Bi/GCE is 4.35 times higher than that of the bare GCE with bismuth film. The prepared electrode showed excellent stability and reproducibility and can be applied for determination of Pb2+ contained wastewater.

scholarly journals Electrocatalytic Study of Paracetamol at a Single-Walled Carbon Nanotube/Nickel Nanocomposite Modified Glassy Carbon Electrode

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Koh Sing Ngai ◽  
Wee Tee Tan ◽  
Zulkarnain Zainal ◽  
Ruzniza Mohd Zawawi ◽  
Joon Ching Juan
Keyword(s):  
Cyclic Voltammetry ◽  
Carbon Nanotube ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Single Walled Carbon Nanotube ◽  
Paracetamol Concentration ◽  
Single Walled Carbon

A rapid, simple, and sensitive method for the electrochemical determination of paracetamol was developed. A single-walled carbon nanotube/nickel (SWCNT/Ni) nanocomposite was prepared and immobilized on a glassy carbon electrode (GCE) surface via mechanical attachment. This paper reports the voltammetry study on the effect of paracetamol concentration, scan rate, pH, and temperature at a SWCNT/Ni-modified electrode in the determination of paracetamol. The characterization of the SWCNT/Ni/GCE was performed by cyclic voltammetry. Variable pressure scanning electron microscopy (VPSEM) and energy dispersive X-ray (EDX) spectrometer were used to examine the surface morphology and elemental profile of the modified electrode, respectively. Cyclic voltammetry showed significant enhancement in peak current for the determination of paracetamol at the SWCNT/Ni-modified electrode. A linear calibration curve was obtained for the paracetamol concentration between 0.05 and 0.50 mM. The SWCNT/Ni/GCE displayed a sensitivity of 64 mA M−1and a detection limit of 1.17 × 10−7 M in paracetamol detection. The proposed electrode can be applied for the determination of paracetamol in real pharmaceutical samples with satisfactory performance. Results indicate that electrodes modified with SWCNT and nickel nanoparticles exhibit better electrocatalytic activity towards paracetamol.

Simultaneous determination of TBHQ and BHA on a MWNT-Brij® 35 modified electrode in micellar media

2015 ◽  
Vol 7 (19) ◽  
pp. 8344-8351 ◽  
Author(s):  
Guzel Ziyatdinova ◽  
Karina Os'kina ◽  
Endzhe Ziganshina ◽  
Herman Budnikov
Keyword(s):  
Simultaneous Determination ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Micellar Medium ◽  
Micellar Media ◽  
Modified Glassy Carbon Electrode ◽  
Simultaneous Voltammetric Determination

Simultaneous voltammetric determination of TBHQ and BHA using a MWNT-Brij® 35 modified glassy carbon electrode in Brij® 35 micellar medium.

Electrocatalytic Response and Determination of Noradrenaline in the Presence of L-Ascorbic and Uric Acids with Poly(Eriochrome Black T)-Modified Electrode

2007 ◽  
Vol 72 (9) ◽  
pp. 1177-1188 ◽  
Author(s):  
Xinhua Lin ◽  
Wei Li ◽  
Hong Yao ◽  
Yuanyuan Sun ◽  
Liying Huang ◽  
...  
Keyword(s):  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Dynamic Range ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
Modified Glassy Carbon Electrode ◽  
Eriochrome Black T ◽  
Wide Linear Dynamic Range

A poly(Eriochrome Black T) chemically modified glassy carbon electrode modified with Eriochrome Black T was prepared by cyclic voltammetry. The modified electrode showed an excellent electrocatalytic activity in oxidation of noradrenaline (NA) and could separate its electrochemical responses from those of L-ascorbic acid (AA) and uric acid (UA). Differences of the oxidation peak potentials for NA-AA and UA-NA were about 150 mV. The responses to NA, AA and UA of the modified electrode are relatively independent. Using differential pulse voltammetry, the peak currents of NA at modified glassy carbon electrode increased linearly with the concentration of NA from 0.5 to 100 μmol l-1. The detection limit was 0.2 μmol l-1. With the modified electrode, UA could be selectively determined in the presence of AA. The method showing a wide linear dynamic range and excellent sensitivity was successfully applied to the determination of NA in pharmaceutical injections and various samples.

A novel modified electrode based on terbium oxide and carbon nanotubes for the simultaneous determination of methyldopa and paracetamol

2016 ◽  
Vol 8 (23) ◽  
pp. 4711-4719 ◽  
Author(s):  
Aysegul Kutluay Baytak ◽  
Sehriban Duzmen ◽  
Tugce Teker ◽  
Mehmet Aslanoglu
Keyword(s):  
Carbon Nanotubes ◽  
Simultaneous Determination ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Terbium Oxide ◽  
Sensing Platform ◽  
Voltammetric Sensing

A novel voltammetric sensing platform was prepared ultrasonically by modifying a glassy carbon electrode (GCE) with a composite of terbium oxide (Tb4O7NPs) nanoparticles and carbon nanotubes (CNTs) for the simultaneous determination of methyldopa (MD) and paracetamol (PR).

A voltammetric sensor based on eosin Y film modified glassy carbon electrode for simultaneous determination of hydroquinone and catechol

2014 ◽  
Vol 6 (16) ◽  
pp. 6494-6503 ◽  
Author(s):  
Jiahong He ◽  
Ri Qiu ◽  
Wenpo Li ◽  
Shaohua Xing ◽  
Zhongrong Song ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Simultaneous Determination ◽  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Eosin Y ◽  
Carbon Electrode ◽  
Voltammetric Sensor ◽  
Modified Glassy Carbon Electrode

By using cyclic voltammetry, eosin Y film was electrodeposited on the surface of glassy carbon electrode (GCE) to obtain the modified electrode (denoted as eosin Y/GCE).

scholarly journals Preparation and Application of Keggin Silicomolybdic acid Modified Electrode

2020 ◽  
Author(s):  
Miao Liu ◽  
Mingxuan Jia ◽  
Dong Hui Li
Keyword(s):  
Glassy Carbon Electrode ◽  
Modified Electrode ◽  
Glassy Carbon ◽  
Photoelectron Spectroscopy ◽  
Limit Of Detection ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
X Ray ◽  
Linear Relationships

Abstract An innovative method for the determination of isoniazid tablets is studied through electrochemical method for the modification of glassy carbon electrode (GCE). Polyoxomolybdate, with stable structures, has not been widely used for the determination of substance. In this study, the mentioned polyoxomolybdate was characterized by Fourier transform infrared spectroscopy (FT-IR), UV-vis, X-ray diffraction (XRD), Atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS), and used to modify the glassy carbon electrode. The electrochemical performance of the polyoxomolybdate@GCE was investigated with cyclic voltammetry (CV) and differential pulse voltammetry (DPV), compared with the unmodified electrode, the proposed polyoxomolybdate modified electrode exhibited strong electro-catalytic activities towards isoniazid (INH). Under the optimized conditions, there was linear relationships between the DPV peak currents and the concentrations in the range of 1 × 10 -7 g/L to 3 × 10 -7 g/L for INH (R 2 = 0.9979), with the limit of detection (LOD) of 0.024 μg/L (based on S/N = 3). The modified electrode has proper reproducibility (RSD < 5%), stability, response time (< 3 min) and lifetime (up to 6 days).

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