Two Zr−based heterometal−organic frameworks for efficient CO2 reduction under visible light
Two new zirconium−based heterometal−organic frameworks, Zr3CP3−Mn (1) and Zr3CP3−Ni (2) constructed from [Cp3Zr3(μ3−O)(μ2−OH)3(IN)3] secondary building units and transition metal cations, were successfully synthesized through one−pot method. Single-crystal X-ray diffraction analysis...