Surfactant-assisted Fabrication and Supercapacitor Performances of 12-phosphomolybdate-pillared Metal-Organic Framework Containing Helix and its SWNT Nanocomposites

CrystEngComm ◽  
2021 ◽  
Author(s):  
Jinlong Zhuo ◽  
Yunliang Wang ◽  
Yu-Guang Wang ◽  
Mingqi Xu ◽  
Jing-Quan Sha
Keyword(s):  
Single Crystal ◽  
Hydrothermal Method ◽  
Metal Organic Framework ◽  
Crystalline Compound ◽  
X Ray ◽  
Metal Organic ◽  
First Time ◽  
Surfactant Assisted ◽  
Organic Framework

A new polyoxometalate-pillared metal-organic framework crystalline compound with multi-fold helical chains, [Ni7(1,2,4-Tri)12(H2O)10][HPMo12O40]·10H2O (NiPMo12), was successfully synthesized by surfactant-assisted hydrothermal method for the first time and characterized by single crystal X-ray...

Single Crystal X-ray Diffraction Studies of Carbon Dioxide and Fuel-Related Gases Adsorbed on the Small Pore Scandium Terephthalate Metal Organic Framework, Sc2(O2CC6H4CO2)3

Langmuir ◽  
2009 ◽  
Vol 25 (6) ◽  
pp. 3618-3626 ◽  
Author(s):  
Stuart R. Miller ◽  
Paul A. Wright ◽  
Thomas Devic ◽  
Christian Serre ◽  
Gérard Férey ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Small Pore ◽  
Metal Organic ◽  
Organic Framework

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

2013 ◽  
Vol 275-277 ◽  
pp. 2367-2370
Author(s):  
Qing Yu Ma ◽  
Rui Fang Guan ◽  
Guo Zhong Li ◽  
Deng Xu Wang
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Diffusion Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Diffusion ◽  
Sheet Structure ◽  
Metal Organic ◽  
1D Chains ◽  
Organic Framework

A novel metal-organic framework, MnCl2(BIPS)2•2CH3OH•2H2O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-yl)2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

scholarly journals Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework

CrystEngComm ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 2097-2102 ◽  
Author(s):  
Julia G. Knapp ◽  
Xuan Zhang ◽  
Tatyana Elkin ◽  
Laura E. Wolfsberg ◽  
Sylvia L. Hanna ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Uranyl Ion ◽  
Single Crystal Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Photo Oxidation ◽  
Metal Organic ◽  
Organic Framework

The zirconium MOF NU-1000 was post-synthetically modified through solvothermal deposition to include the uranyl ion and characterized via single-crystal X-ray diffraction; photo-oxidation was also performed.

A zinc(II) metal–organic framework with a novel topology formed from 4,4′,4′′-nitrilotribenzoate and 4,4′-bipyridine ligands

2015 ◽  
Vol 71 (9) ◽  
pp. 799-803 ◽  
Author(s):  
Meng Zhao ◽  
Jian Su ◽  
Jun Zhang ◽  
Jie-Ying Wu ◽  
Yu-Peng Tian
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
Solvothermal Method ◽  
Metal Organic Framework ◽  
Topological Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Paddle Wheel ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework with a novel topology, poly[sesqui(μ2-4,4′-bipyridine)bis(dimethylformamide)bis(μ4-4,4′,4′′-nitrilotribenzoato)trizinc(II)], [Zn3(C21H12NO6)2(C10H8N2)1.5(C3H7NO)2]n, was obtained by the solvothermal method using 4,4′,4′′-nitrilotribenzoic acid and 4,4′-bipyridine (bipy). The structure, determined by single-crystal X-ray diffraction analysis, possesses three kinds of crystallographically independent ZnIIcations, as well as binuclear Zn2(COO)4(bipy)2paddle-wheel clusters, and can be reduced to a novel topology of a (3,3,6)-connected 3-nodal net, with the Schläfli symbol {5.62}4{52.6}4{58.87} according to the topological analysis.

A 2-D Metal–Organic Framework Based on Linear Trinuclear Copper Cluster Units: Syntheses, Structures and Magnetic Properties

2018 ◽  
Vol 42 (4) ◽  
pp. 198-201 ◽  
Author(s):  
Liping Wang ◽  
Erpeng Zhang ◽  
Xiaoli Zhou ◽  
Yufei Wang ◽  
Yanli Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Copper Cluster ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

The coordination polymer [Cu3(tci)2(phen)2] n (H3tci = 1,3,5-tris(2-carboxyethyl)isocyanurate; phen = 1,10-phenanthroline) has been synthesised. Single-crystal X-ray diffraction studies have shown that the polymer displays a 2-D metal–organic framework based on linear trinuclear copper cluster units, and its magnetic properties indicate antiferromagnetic interactions.

scholarly journals Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography

2017 ◽  
Vol 129 (29) ◽  
pp. 8532-8536 ◽  
Author(s):  
Alexandre Burgun ◽  
Campbell J. Coghlan ◽  
David M. Huang ◽  
Wenqian Chen ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Organic ◽  
Catalytic Processes ◽  
Organic Framework

A Novel, Interpenetrating Metal–Organic Framework: Synthesis, Structure, and Luminescence Detection of Nitrobenzene

2017 ◽  
Vol 70 (7) ◽  
pp. 792 ◽  
Author(s):  
Peng-Fei Shi ◽  
Li-Xian Wang ◽  
Zhao-Peng Yu
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Solvent Stability ◽  
Qualitative Detection ◽  
Highly Sensitive ◽  
Metal Organic ◽  
First Time ◽  
Ppm Level ◽  
Organic Framework

A 3D heterometal–organic framework {[TbZn(BPDC)2(HCOO)(H2O)3]·2H2O}n (1) was constructed from Tb3+ and Zn2+ as metal ions and 4,4′-dicarboxylate-2,2′-dipyridine (H2BPDC) as the ligand using a solvothermal method. Single-crystal X-ray diffraction analysis revealed that compound 1 is 2-fold interpenetrating. Thermogravimetric and solvent stability analyses demonstrated that compound 1 displayed good thermal and solvent stabilities. The luminescent explorations revealed that compound 1 exhibited highly sensitive and qualitative detection of nitrobenzene at the ppm level. To our knowledge, the present study reports for the first time the use of an interpenetrating heterometallic metal–organic framework as a luminescent probe for nitrobenzene.

Surfactant-assisted synthesis and electrochemical properties of an unprecedented polyoxometalate-based metal–organic nanocaged framework

2019 ◽  
Vol 55 (9) ◽  
pp. 1201-1204 ◽  
Author(s):  
Xiya Yang ◽  
Peipei Zhu ◽  
Jing Ren ◽  
Yuhao Chen ◽  
Xiao Li ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Hydrothermal Method ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Surfactant Assisted ◽  
Organic Framework

The first polyoxometalate-based nanocaged three-dimensional metal–organic framework was synthesized by a surfactant-assisted hydrothermal method.

Sign in / Sign up

Export Citation Format

Share Document