A Highly Stable Zn9-Pyrazolate Metal-Organic Framework with Metallosalen Ligands as Carbon Dioxide Cycloaddition Catalyst

2022 ◽  
Author(s):  
Rong Cao ◽  
Fa-Xue Ma ◽  
Fu-Qi Mi ◽  
Meng-Jiao Sun ◽  
Tao Huang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Catalytic Activity ◽  
Cycloaddition Reactions ◽  
Metal Organic ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework constructed from unprecedented Zn9O2(OH)2(pyz)12 (pyz = pyrazolate) clusters and Ni(salen)-derived linkers was reported. The MOF exhibits high catalytic activity for CO2 cycloaddition reactions with excellent...

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Cobalt nanoparticle-embedded nitrogen-doped carbon/carbon nanotube frameworks derived from a metal–organic framework for tri-functional ORR, OER and HER electrocatalysis

2019 ◽  
Vol 7 (8) ◽  
pp. 3664-3672 ◽  
Author(s):  
Hele Guo ◽  
Qichun Feng ◽  
Jixin Zhu ◽  
Jingsan Xu ◽  
Qianqian Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbon Nanotube ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Nitrogen Doped Carbon ◽  
Cobalt Nanoparticle ◽  
Organic Framework

A Co@N-CNTF electrocatalyst derived from a metal–organic framework exhibits high catalytic activity in the ORR, OER and HER.

A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

2019 ◽  
Vol 55 (98) ◽  
pp. 14781-14784 ◽  
Author(s):  
Ning-Yu Huang ◽  
Xue-Wen Zhang ◽  
Yu-Zhi Xu ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Metal Center ◽  
High Catalytic Activity ◽  
Methylene Groups ◽  
Metal Organic ◽  
Repulsive Forces ◽  
Organic Framework

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

Interfacial assembly and hydrolysis for synthesizing a TiO2/metal–organic framework composite

Soft Matter ◽  
2017 ◽  
Vol 13 (48) ◽  
pp. 9174-9178 ◽  
Author(s):  
Lifei Liu ◽  
Fanyu Zhang ◽  
Jianling Zhang ◽  
Xiuniang Tan ◽  
Bingxing Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Interfacial Assembly ◽  
Metal Organic ◽  
Organic Framework

The interfacial assembling and hydrolysis route is proposed for fabricating TiO2/UiO-67 composites, which have shown high catalytic activity for photocatalytic CO2 reduction.

scholarly journals A base-free Chan–Lam reaction catalyzed by an easily assembled Cu(II)-carboxylate metal-organic framework

2021 ◽  
pp. 174751982110265
Author(s):  
Xinhai Zhang ◽  
Jianhua Qin ◽  
Ruixuan Ma ◽  
Lei Shi
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
High Catalytic Activity ◽  
Arylboronic Acids ◽  
Metal Organic ◽  
Organic Framework

A new copper(II) metal-organic framework is constructed as a sustainable copper heterogeneous catalyst. Cu-DPTCA, with high catalytic activity, can effectively promote the Chan–Lam coupling reaction of arylboronic acids and amines without adding any base or additive.

scholarly journals Hybrid Catalysts for CO2 Conversion into Cyclic Carbonates

Catalysts ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 325 ◽  
Author(s):  
Carla Calabrese ◽  
Francesco Giacalone ◽  
Carmela Aprile
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Scientific Community ◽  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Co2 Conversion ◽  
Cyclic Carbonates ◽  
Hybrid Catalysts ◽  
Metal Organic

The conversion of carbon dioxide into valuable chemicals such as cyclic carbonates is an appealing topic for the scientific community due to the possibility of valorizing waste into an inexpensive, available, nontoxic, and renewable carbon feedstock. In this regard, last-generation heterogeneous catalysts are of great interest owing to their high catalytic activity, robustness, and easy recovery and recycling. In the present review, recent advances on CO2 cycloaddition to epoxide mediated by hybrid catalysts through organometallic or organo-catalytic species supported onto silica-, nanocarbon-, and metal–organic framework (MOF)-based heterogeneous materials, are highlighted and discussed.

Metal–organic framework-derived hybrid of Fe3C nanorod-encapsulated, N-doped CNTs on porous carbon sheets for highly efficient oxygen reduction and water oxidation

2016 ◽  
Vol 6 (16) ◽  
pp. 6365-6371 ◽  
Author(s):  
Pingping Zhao ◽  
Xing Hua ◽  
Wei Xu ◽  
Wei Luo ◽  
Shengli Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction ◽  
Porous Carbon ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

A hybrid of Fe3C@CNTs grown on N-doped porous carbon sheets derived from MOF exhibited exceedingly high catalytic activity toward ORR and OER.

Palladium nanoparticles encapsulated inside the pores of a metal–organic framework as a highly active catalyst for carbon–carbon cross-coupling

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54487-54493 ◽  
Author(s):  
Ningzhao Shang ◽  
Shutao Gao ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles were successfully encapsulated in the cages of MIL-101, which exhibited high catalytic activity toward the C–C coupling reactions.

scholarly journals Cyclometalation of lanthanum(iii) based MOF for catalytic hydrogenation of carbon dioxide to formate

RSC Advances ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 3593-3605 ◽  
Author(s):  
Piwai Tshuma ◽  
Banothile C. E. Makhubela ◽  
Lars Öhrström ◽  
Susan A. Bourne ◽  
Nabanita Chatterjee ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Catalytic Hydrogenation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Hydrogenation Of Carbon Dioxide ◽  
Organic Framework

A novel metal–organic framework JMS-1 with rare topology zaz shows catalytic activity towards conversion of carbon dioxide to formate.

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