Carbogenic π−Conjugated Domains as the Origin of Afterglow Emission in Carbon Dot−Based Organic Composite films

2021 ◽  
Author(s):  
Lu Zhai ◽  
Xiaoming Ren ◽  
Qiang Xu
Keyword(s):  
Organic Materials ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Composite Films ◽  
Ambient Conditions ◽  
Phase Synthesis ◽  
Carbon Dot ◽  
Synthesis Approach

The development of carbon dot (CD)-based pure organic materials displaying afterglow emission under ambient conditions with readily tunable emissions is highly desired. Herein, a facile solid-phase synthesis approach at ambient...

A Lanthanide(III) Triflate Mediated Macrolactonization/Solid-Phase Synthesis Approach for Depsipeptide Synthesis

2015 ◽  
Vol 17 (9) ◽  
pp. 2182-2185 ◽  
Author(s):  
Jordan D. Goodreid ◽  
Eduardo da Silveira dos Santos ◽  
Robert A. Batey
Keyword(s):  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Phase Synthesis ◽  
Synthesis Approach

Development of a practical solid-phase synthesis approach to 1,3,5-triazepan-2,6-diones

Tetrahedron ◽  
2012 ◽  
Vol 68 (36) ◽  
pp. 7472-7478 ◽  
Author(s):  
Joel Boeglin ◽  
Claire Venin ◽  
Gilles Guichard
Keyword(s):  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Phase Synthesis ◽  
Synthesis Approach

scholarly journals Mechanochemical Transformation of Planar Polyarene to Curved Fused-Ring System: Solid-Phase Synthesis of Corannulene

2021 ◽  
Author(s):  
Yong Teoh ◽  
Gabor Báti ◽  
Felipe Garcia ◽  
Mihaiela C. Stuparu
Keyword(s):  
Gas Phase ◽  
Solid Phase Synthesis ◽  
Molecular Level ◽  
Solid Phase ◽  
Reaction Times ◽  
Ambient Conditions ◽  
Phase Synthesis ◽  
Mechanochemical Transformation ◽  
Fused Ring ◽  
Fused Ring System

This work demonstrates that mechanochemical forces can successfully transform a planar<br>polyarene into a curved geometry by creating new C-C bonds along the rim of the molecular structure.<br>In doing so, mechanochemistry does not require inert conditions or organic solvents and provide<br>better yields within shorter reaction times. This is illustrated in a 15-minute synthesis of corannulene,<br>a fragment of fullerene C60, in 66% yield through ball milling of planar tetrabromomethylfluoranthene<br>precursor under ambient conditions. Traditional solution and gas-phase synthetic pathways do not<br>compete with the practicality and efficiency offered by the mechanochemical synthesis, which now<br>opens up a new reaction space for inducing curvature at a molecular level.

A Different Approach to the EGFR Inhibitor Gefitinib Involving Solid-Phase Synthesis

Synlett ◽  
2018 ◽  
Vol 29 (10) ◽  
pp. 1346-1350 ◽  
Author(s):  
Luísa Carvalho ◽  
André Sequeira ◽  
Ana Lourenço ◽  
Luísa Ferreira ◽  
Paula Branco ◽  
...  
Keyword(s):  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Solid Support ◽  
Egfr Inhibitor ◽  
Phase Synthesis ◽  
Synthetic Strategy ◽  
Colorimetric Assays ◽  
First Time ◽  
Synthesis Approach

An efficient solid-phase synthesis approach is here reported for the first time to prepare the EGFR inhibitor Gefitinib. The five-step synthetic strategy used FMP resin as the solid support, and FTIR and colorimetric assays were used to track the reaction’s progress. Gefitinib was obtained with an overall yield of 40%.

Ion-tagged synthesis of an oligoribonucleotide pentamer — The continuing versatility of TBDMS chemistry

2007 ◽  
Vol 85 (4) ◽  
pp. 274-282 ◽  
Author(s):  
Robert A Donga ◽  
Tak-Hang Chan ◽  
Masad J Damha
Keyword(s):  
Ionic Liquid ◽  
Rna Synthesis ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Solution Phase ◽  
Phase Synthesis ◽  
Resultant Increase ◽  
Synthesis Approach

An oligoribonucleotide has been synthesized in solution, using an ionic-liquid-based soluble tag at a scale several hundred times that of a standard solid-phase synthesis approach. Ogilvie's 2′-TBDMS strategy was adopted, and because of the resultant increase in lipophilicity, it allowed an easier purification of the growing oligomer compared with the previously observed for DNA, which does not require 2′ protection. The procedure is illustrated by the synthesis of the pentaribonucleotide sequence AGAUC, corresponding to a segment of the tRNAfMet from E. coli.Key words: solution-phase RNA synthesis, ionic-liquid tag.

A facile template-free approach for the solid-phase synthesis of CoS2 nanocrystals and their enhanced storage energy in supercapacitors

RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 50220-50225 ◽  
Author(s):  
Ying Ji ◽  
Xiaoyang Liu ◽  
Wei Liu ◽  
Ying Wang ◽  
Hongdan Zhang ◽  
...  
Keyword(s):  
Molten Salt ◽  
Specific Capacitance ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Molten Salt Synthesis ◽  
Phase Synthesis ◽  
Template Free ◽  
Synthesis Approach ◽  
Storage Energy

Porous CoS2 is synthesized by a modified molten-salt synthesis approach with a specific capacitance as high as 654 F g−1.

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