scholarly journals Correction: A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp3)–H activation and thiolation

2021 ◽  
Author(s):  
Tao Li ◽  
Kangjiang Liang ◽  
Jiaying Tang ◽  
Yuzhen Ding ◽  
Xiaogang Tong ◽  
...  
Keyword(s):  
Eda Complex

Correction for ‘A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp3)–H activation and thiolation’ by Tao Li et al., Chem. Sci., 2021, DOI: 10.1039/d1sc03667j.

Electron donor-acceptor (EDA)-complex enabled SF5Cl addition on alkenes and alkynes

2021 ◽  
Vol 243 ◽  
pp. 109734
Author(s):  
Audrey Gilbert ◽  
Mélodie Birepinte ◽  
Jean-François Paquin
Keyword(s):  
Electron Donor ◽  
Donor Acceptor ◽  
Eda Complex

scholarly journals N-Heterocyclic Carbene/Magnesium Co-catalyzed Radical Relay Assembly of Aliphatic Keto-nitriles

2020 ◽  
Author(s):  
Lei Chen ◽  
Shiyi Jin ◽  
Jian Gao ◽  
Tongtong Liu ◽  
Yuebo Shao ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Reaction Conditions ◽  
Eda Complex

An N-heterocyclic carbene and magnesium co-catalyzed three-component alkylacylation of alkenes with cycloketone oxime esters and aldehydes was presented. This method displayed good scope generality, providing a transition metal and photo-redox free pathway to access various multi-functionalized aliphatic keto-nitrile structures under mild reaction conditions. Moreover, this strategy is supposed to follow a radical relay mechanism via a single electron transfer (SET) event of Mg/oxime ester/Breslow intermediate ternary electron donating acceptor (EDA) complex.

Step by Step Modeling of Superbasic Catalysts of the EDA Complex Type

1997 ◽  
Vol 167 (2) ◽  
pp. 503-512 ◽  
Author(s):  
Jacek Kijeński ◽  
Ryszard Hombek
Keyword(s):  
Complex Type ◽  
Eda Complex

scholarly journals Discovery of EDA-Complex Photocatalyzed Reactions Using Multidimensional Image Processing: Iminophosphorane Synthesis as a Case Study

2021 ◽  
Author(s):  
Rodrigo Silva ◽  
Gabriel Batista ◽  
Timothy Brocksom ◽  
Kleber de Oliveira
Keyword(s):  
Image Processing ◽  
Digital Image Processing ◽  
Digital Image ◽  
Color Change ◽  
Visible Spectrum ◽  
Screening Strategy ◽  
Multidimensional Screening ◽  
Eda Complex ◽  
Tlc Analysis

Abstract Herein, we report a multidimensional screening strategy for the discovery of EDA-complex photocatalyzed reactions using only photographic devices (webcam, cellphone) and TLC analysis. An algorithm was designed to identify automatically EDA-complex reactive mixtures in solution from digital image processing in a 96-wells microplate and by TLC-analysis. The code highlights the region of absorption of the mixture in the visible spectrum, and the quantity of the color change through grayscale values. Furthermore, the code identifies automatically the blurs on the TLC plate and classifies the mixture as colorimetric reactions, non-reactive or potentially reactive EDA mixtures. This strategy allowed us to discover and then optimize a new EDA-mediated approach for obtaining iminophosphoranes in up to 90% yield.

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