Metal-Organic-Framework derived Co@CN modified horizontally aligned graphene oxide array as free-standing anode for lithium-ion batteries

2021 ◽  
Author(s):  
Yong Wang ◽  
Jiawei Li ◽  
Xinyang Li ◽  
Hong Jin ◽  
Wajid Ali ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Carrier Mobility ◽  
2D Materials ◽  
Metal Organic Framework ◽  
Electronic Conductivity ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Electrochemical Energy Storage ◽  
Free Standing ◽  
Metal Organic

Graphene-based 2D materials have shown extraordinary promise in electrochemical energy storage, owing to their high electrochemical activity, fast carrier mobility, and large electronic conductivity. However, low specific capacity (<200 mAh...

Facile formation of a nanostructured NiP2@C material for advanced lithium-ion battery anode using adsorption property of metal–organic framework

2016 ◽  
Vol 4 (24) ◽  
pp. 9593-9599 ◽  
Author(s):  
Gaihua Li ◽  
Hao Yang ◽  
Fengcai Li ◽  
Jia Du ◽  
Wei Shi ◽  
...  
Keyword(s):  
Adsorption Property ◽  
Metal Organic Framework ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Rate ◽  
Rate Performance ◽  
Lithium Storage ◽  
Metal Organic ◽  
High Rate Performance ◽  
Battery Anode

Utilizing the adsorption properties of MOFs, a nanostructured NiP2@C was successfully synthesized, which exhibited enhanced capability for lithium storage in terms of both the reversible specific capacity and high-rate performance.

scholarly journals Advanced pillared designs for two-dimensional materials in electrochemical energy storage

2020 ◽  
Vol 2 (12) ◽  
pp. 5496-5503
Author(s):  
Chong Chen ◽  
Nian-Wu Li ◽  
Bao Wang ◽  
Shuai Yuan ◽  
Le Yu
Keyword(s):  
Energy Storage ◽  
Recent Progress ◽  
2D Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Electrochemical Energy Storage ◽  
Two Dimensional ◽  
Rate Performance ◽  
Two Dimensional Materials ◽  
Ion Storage

2D materials with pillared designs have shown great enhancement in specific capacity/capacitance and rate performance. In this study, we highlight the recent progress in 2D materials with pillared designs in lithium-ion storage and beyond.

Metal organic framework derived Nb2O5@C nanoparticles grown on reduced graphene oxide for high-energy lithium ion capacitors

2019 ◽  
Vol 55 (18) ◽  
pp. 2692-2695 ◽  
Author(s):  
Xinyan Jiao ◽  
Qingli Hao ◽  
Xifeng Xia ◽  
Zongdeng Wu ◽  
Wu Lei
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
High Energy ◽  
Reduced Graphene ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

For the first time, M-Nb2O5@C/rGO composites are fabricated by annealing the precursor of GO supported Nb-metal organic frameworks.

Encapsulating NiCo2O4 inside metal–organic framework sandwiched graphene oxide 2D composite nanosheets for high-performance lithium-ion batteries

Nanoscale ◽  
2019 ◽  
Vol 11 (32) ◽  
pp. 15166-15172 ◽  
Author(s):  
Yiwen Kuang ◽  
Chen Chen ◽  
Kai Li ◽  
Baicun Hao ◽  
Jun Ma ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Metal Organic Framework ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Metal Organic ◽  
Organic Framework

2D composite nanosheets comprised of NiCo2O4 encapsulated inside ZIF-67 sandwiched graphene oxide presented exceptional cycling stability and rate capability.

scholarly journals Facile Synthesis of Fe2O3 Nanomaterials from MIL-101(Fe) Template and Its Application in Lithium Ion Batteries

2019 ◽  
Vol 2019 ◽  
pp. 1-5
Author(s):  
Chunyan Zhang ◽  
Nianqiao Qin ◽  
Jing Li ◽  
Yan Tian ◽  
Hui Zhang
Keyword(s):  
Lithium Ion Batteries ◽  
Metal Organic Framework ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycle Performance ◽  
High Specific Capacity ◽  
Calcination Process ◽  
Metal Organic ◽  
Initial Cycle

Sponge-like porous Fe2O3 nanomaterials were obtained through the calcination process of the iron-based metal organic framework (MIL-101). As anode materials for lithium-ion batteries, thus, obtained products show a good electrochemical performance with a high specific capacity (1358 mA h g-1 at 100 mA g-1 in the initial cycle) and a relatively stable cycle performance (750 mA h g-1 after 80 charge/discharge cycles). The superior cycling performance may be attributed to their special structure, which facilitates charge transfer and Li+ diffusion.

Enhancing the Li+ diffusion in Li3VO4by coupling withreduced graphene oxide for lithium-ion batteries

2021 ◽  
Vol 17 ◽  
Author(s):  
Mingxuan Guo ◽  
Haibo Li
Keyword(s):  
Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
Electronic Conductivity ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Ion Diffusion ◽  
X Ray ◽  
Host Materials

Background: Owing to the excellent theoretical specific capacity and safety intercalation potential, Li3VO4¬ (LVO) has been proposed as anadvanced anode material for lithium ions batteries (LIBs). However, the LVO suffers from low electronic conductivity that limits its commercialization. Objective: The reduced graphene oxide (rGO) is recommended to couple with micro-LVO particles aiming to enhance the conductivity of compositeelectrodes. Method: The LVO@rGO compositeis synthesized by a facile hydrothermal method. The morphology, crystallinity, valance state and electrochemical behavior of LVO@rGO are characterized by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and electrochemical workstation, respectively. Further, the LIBs’ performance is explored by making a coins-type half-cell LIBs battery via battery system. Results: The Li+ diffusion rate of the optimized LVO@rGO electrode is 7.67×10-23 cm2 s-1, which improves two orders of magnitudesof pure LVO electrode. As a result, the LVO@rGO anode delivers a reversible capacity of 190.1 mAh/g at 0.1 A/g after 100 cycles, which is even twice higher than that of pure LVO anode (90.6 mAh/g). Besides,it exhibitssuperior rate capability, i.e.a reversible capability of 285.0, 220.2, 158.7, 105.2 and 71.7 mAh/g at 0.05, 0.1, 0.2, 0.5 and 1.0 A/g, respectively. Conclusion: The high conductivity and flexible texture enable rGO an idea building block to enhance the Li ion diffusion of whole electrode. On the other hand, it is instrumental in alleviating the aggregation of host materials, leading to high specific surface and specific capacity.

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