IrO2/LiLa2IrO6 as a Robust Electrocatalyst for Oxygen Evolution Reaction in Acidic Media

Author(s):  
Huihui Liu ◽  
Haeseong Jang ◽  
Yu Wang ◽  
Min Gyu Kim ◽  
Haisen Li ◽  
...  

Recently reported non-noble metal-iridium mixed oxides not only exhibit excellent activity for the oxygen evolution reaction in acid media, but also reduce the cost. However, most of them fail to...

2021 ◽  
Vol 4 (2) ◽  
pp. 1173-1181
Author(s):  
Kévin Lemoine ◽  
Zahra Gohari-Bajestani ◽  
Romain Moury ◽  
Alexandre Terry ◽  
Amandine Guiet ◽  
...  

Author(s):  
Taehyun Kwon ◽  
Heesu Yang ◽  
Minki Jun ◽  
Taekyung Kim ◽  
Jinwhan Joo ◽  
...  

The oxygen evolution reaction (OER) requires a large overpotential which undermines the stability of electrocatalysts, typically IrOx or RuOx. RuOx is particularly vulnerable to high overpotential in acidic media, due...


2021 ◽  
Author(s):  
Xiaoping Ma ◽  
Lili Deng ◽  
Manting Lu ◽  
Yi He ◽  
Shuai Zou ◽  
...  

Abstract Although researches on non-noble metal electrocatalysts have been made some progress recently, their performance in proton exchange membrane water electrolyzer (PEMWE) is still incomparable to that of noble-metal-based catalysts. Therefore, it is a more practical way to improve the utilization of precious metals in electrocatalysts for oxygen evolution reaction (OER) in the acidic medium. Herein, nanostructured IrCo@IrCoOx core-shell electrocatalysts composed of IrCo alloy core and IrCoOx shell were synthesized through a simple colloidally synthesis and calcination method. As expected, the hybrid IrCo-200 NPs with petal-like morphology show the best OER activities in acidic electrolytes. They deliver lower overpotential and better electrocatalytic kinetics than pristine IrCo alloy and commercial Ir/C, reaching a low overpotential (j = 10 mA/cm2) of 259 mV (vs. RHE) and a Tafel slope of 59 mV dec−1. The IrCo-200 NPs displayed robust durability with life time of about 55 h in acidic solution under a large current density of 50 mA/cm2. The enhanced electrocatalytic activity may be associated with the unique metal/amorphous metal oxide core-shell heterostructure, allowing the improved charge transferability. Moreover, the *OH-rich amorphous shell functions as the active site for OER and prevents the further dissolution of the metallic core and thus ensures high stability.


Author(s):  
Marisol Maril ◽  
Pablo Tobosque ◽  
Nataly Cisternas ◽  
Marie-Paule Delplancke ◽  
Jean Luc Delplancke ◽  
...  

2015 ◽  
Vol 2 (8) ◽  
pp. 1128-1137 ◽  
Author(s):  
Thomas Audichon ◽  
Sophie Morisset ◽  
Teko W. Napporn ◽  
K. Boniface Kokoh ◽  
Clément Comminges ◽  
...  

2019 ◽  
Vol 48 (12) ◽  
pp. 3181-3192 ◽  
Author(s):  
Qiurong Shi ◽  
Chengzhou Zhu ◽  
Dan Du ◽  
Yuehe Lin

The oxygen evolution reaction (OER) is a kinetically sluggish anodic reaction that requires rationalized compositions and structures for achieving highly efficient and reliable noble metal-based electrocatalysts in acidic electrolyte.


2020 ◽  
Vol 30 (15) ◽  
pp. 1910274 ◽  
Author(s):  
Zhi‐Peng Wu ◽  
Xue Feng Lu ◽  
Shuang‐Quan Zang ◽  
Xiong Wen (David) Lou

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