A highly luminescent and stable copper halide ionic hybrid structure with anionic CuBr2(tpp)2 module

Author(s):  
Hua Tong ◽  
Chanchan Xu ◽  
Wei Liu

Here, we report a novel copper bromide ionic cluster (bz-ted)CuBr2(tpp)2·H2O (1, tpp = triphenylphosphine, bz-ted = 1-benzyl-1,4-diazabicyclo[2.2.2]octan-1-ium) by a facile wet chemistry method. The inorganic module of the compound is...

2015 ◽  
Vol 1112 ◽  
pp. 57-61 ◽  
Author(s):  
Amalia Sholehah ◽  
Akhmad Herman Yuwono

In the present work, ZnO nanostructures were synthesized via wet chemistry method. The seeding solution was prepared from zinc nitrate tetrahydrate and hexamethylenetetramine. Prior to the heating process, the seeding solution was immersed in cold bath (0°C). XRD analysis had shown sharp peaks in diffractogram, indicating the high crystallinity of ZnO nanostructures. The crystallite size was determined using Scherrer equation and Williamson-Hall method. Other relevant parameters including stress, strain, and energy density were calculated using Williamson-Hall assuming UDM, UDSM, and UDEDM. The results had revealed that crystallite size calculated with Williamson-Hall method is more accurate than Scherrer equation.


2011 ◽  
Vol 11 (12) ◽  
pp. 11028-11031 ◽  
Author(s):  
Dan Zhou ◽  
Markus Boese ◽  
Rongming Wang ◽  
Hongzhou Zhang

2019 ◽  
Vol 6 (7) ◽  
pp. 1900015 ◽  
Author(s):  
Miaomiao Liu ◽  
Zihao Zhang ◽  
Francis Okejiri ◽  
Shize Yang ◽  
Shenghu Zhou ◽  
...  

2019 ◽  
Vol 1 (7) ◽  
pp. 2690-2698
Author(s):  
Sharmistha Chatterjee ◽  
Loredana Ricciardi ◽  
Julia I. Deitz ◽  
Robert E. A. Williams ◽  
David W. McComb ◽  
...  

In this contribution experimental evidence of plasmonic edge modes and acoustic breathing modes in gold nanostars (AuNSs) is reported. AuNSs are synthesized by a surfactant-free, one-step wet-chemistry method.


2020 ◽  
Vol 34 (07n09) ◽  
pp. 2040022
Author(s):  
Yi-Heng Lin ◽  
Po-Chia Huang ◽  
Sheng-Chang Wang ◽  
Jow-Lay Huang

Hydrogen is a promising alternative energy without greenhouse gas emissions. The transition metal carbides (TMCs) are considered a sustainable alternatives to noble metals in catalysis. Among the TMCs, Co[Formula: see text]C ([Formula: see text] = 2, 3) nanoparticles (NPs) act as an excellent electrocatalyst for hydrogen evolution reaction (HER) by water splitting. In our report, Co[Formula: see text]C nanocomposites were synthesized by wet chemistry method using cobalt (II) acetate, sodium hydroxide as precursors and triethylene glycol as solvent. In addition, Co2C NPs were synthesized by similar wet chemistry method using cobalt (II) acetate as precursors and triethylene glycol, oleylamine as solvent. The cobalt carbide NPs exhibited high electrocatalytic activity. Co[Formula: see text]C nanocomposites performed a −0.33 V onset potential and 91 mV/dec Tafel slope, while the Co2C NPs exhibited a better performance of −0.27 V and 60 mV/dec, respectively.


2010 ◽  
Vol 152-153 ◽  
pp. 643-647
Author(s):  
Xiao Chun Dai ◽  
Zhu Fa Zhou ◽  
Shu Mei Wang ◽  
Ran Ran Tian ◽  
Chun Rong Wang ◽  
...  

Mullite was synthesized by firing precursors prepared from kaolinite via a wet chemistry method at various temperatures. The acicular mullite grains were formed in samples with addition of AlF3 by this process. The phase evolution and morphology of the fired samples were investigated. For the samples without AlF3, the mullitization began to occur at 1300 and almost completed at 1550 , the grains formed were normal-shaped. For the samples with AlF3, acicular mullite was formed, and mullitization began to occur at 1100 and completed at 1250 . The growth of the acicular mullite was associated with a liquid phase. The formed acicular mullite was alumina-rich and had a composition of about 73.4 wt% Al2O3 and 26.6 wt% SiO2 (Al2O3/SiO2=1.65, molar ratio).


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