scholarly journals A TbPc2 sub-monolayer deposit on Titanium Dioxide ultrathin film: a magnetic, morphological, and chemical insight

2021 ◽  
Author(s):  
Andrea Luigi Sorrentino ◽  
Irene Cimatti ◽  
Giulia Serrano ◽  
Lorenzo Poggini ◽  
Brunetto Cortigiani ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Metal Oxides ◽  
Single Molecule ◽  
Ultrathin Film ◽  
Metallic Surfaces ◽  
Single Molecule Magnets ◽  
Inorganic Films ◽  
Magnetic Layers

Thin inorganic films (i.e. metal oxides) are often used as decoupling layers to optimize the interaction between magnetic layers of molecules and metallic surfaces. For deposits of Single-Molecule Magnets (SMMs),...

scholarly journals Molecular Magnetic Materials on Solid Surfaces

2009 ◽  
Author(s):  
Matteo Mannini
Keyword(s):  
Data Storage ◽  
Single Molecule ◽  
Scanning Probe Microscopy ◽  
Organic Radicals ◽  
Solid Surfaces ◽  
Scanning Probe ◽  
Metallic Surfaces ◽  
Single Molecule Magnets ◽  
Tailored Approach ◽  
Phd Thesis

This PhD thesis summarises a study of the nanostructuration of single molecule magnets and organic radicals on metallic surfaces, carried out by the author in collaboration with a number of research groups in Italy, France, Germany and Israel. A tailored approach was followed to graft individual molecules to the surface, to characterise the morphology of the functionalised surfaces with standard scanning probe microscopy and to investigate their magnetic properties using X-Ray circular dichroism. The aim of this project was to develop the initial basis for the organisation and addressing of magnetic molecules with a view to the development of single molecule devices for data storage and molecular-spintronic applications.

Seeking Magneto-Structural Correlations in Easily Tailored Pentagonal Bipyramid Dy(III) Single-Ion Magnets

2019 ◽  
Author(s):  
Guo-Zhang Huang ◽  
Ze-Yu Ruan ◽  
Jie-Yu Zheng ◽  
Yan-Cong Chen ◽  
Si-Guo Wu ◽  
...  
Keyword(s):  
Single Molecule ◽  
Structural Engineering ◽  
Magnetic Hysteresis ◽  
Sweep Rate ◽  
Coordination Bond ◽  
Pentagonal Bipyramid ◽  
Single Molecule Magnets ◽  
Crystal Field Theory ◽  
Bond Angles ◽  
Axial Coordination

<p><a></a>Controlling molecular magnetic anisotropy via structural engineering is delicate and fascinating, especially for single-molecule magnets (SMMs). Herein a family of dysprosium single-ion magnets (SIMs) sitting in pentagonal bipyramid geometry have been synthesized with the variable-size terminal ligands and counter anions, through which the subtle coordination geometry of Dy(III) can be finely tuned based on the size effect. The effective energy barrier (Ueff) successfully increases from 439 K to 632 K and the magnetic hysteresis temperature (under a 200 Oe/s sweep rate) raises from 11 K to 24 K. Based on the crystal-field theory, a semi-quantitative magneto-structural correlation deducing experimentally for the first time is revealed that the Ueff is linearly proportional to the structural-related value S2<sup>0</sup> corresponding to the axial coordination bond lengths and the bond angles. Through the evaluation of the remanent magnetization from hysteresis, quantum tunneling of magnetization (QTM) is found to exhibit negative correlation with the structural-related value S<sub>tun</sub> corresponding to the axial coordination bond angles.<br></p>

Correlating Blocking Temperatures in Single Molecule Magnets with Raman Relaxation

2018 ◽  
Author(s):  
Marcus J. Giansiracusa ◽  
Andreas Kostopoulos ◽  
George F. S. Whitehead ◽  
David Collison ◽  
Floriana Tuna ◽  
...  
Keyword(s):  
Relaxation Time ◽  
Single Molecule ◽  
Energy Barrier ◽  
Thermal Relaxation ◽  
Relaxation Mechanism ◽  
Blocking Temperature ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Key Parameter

We report a six coordinate DyIII single-molecule magnet<br>(SMM) with an energy barrier of 1110 K for thermal relaxation of<br>magnetization. The sample shows no retention of magnetization<br>even at 2 K and this led us to find a good correlation between the<br>blocking temperature and the Raman relaxation regime for SMMs.<br>The key parameter is the relaxation time (𝜏<sub>switch</sub>) at the point where<br>the Raman relaxation mechanism becomes more important than<br>Orbach.

A Combined Spin-Flip and IP/EA Approach for Handling Spin and Spatial Degeneracies: Application to Double Exchange Systems

2018 ◽  
Author(s):  
Shannon Houck ◽  
Nicholas Mayhall
Keyword(s):  
Single Molecule ◽  
Double Exchange ◽  
Computational Effort ◽  
Strongly Correlated ◽  
Single Molecule Magnets ◽  
New Approach ◽  
Spin Flip ◽  
Model Hamiltonian ◽  
Simultaneous Existence ◽  
Exchange Parameters

<div>Many multiconfigurational systems, such as single-molecule magnets, are difficult to study using traditional computational methods due to the simultaneous existence of both spin and spatial degeneracies. In this work, a new approach termed n-spin-flip Ionization Potential/Electron Affinity (<i>n</i>SF-IP or <i>n</i>SF-EA) is introduced which combines the spin-flip method of Anna Krylov with particle-number changing IP/EA methods. We demonstrate the efficacy of the approach by applying it to the strongly-correlated N<sub>2</sub><sup>+</sup> as well as several double exchange systems. We also demonstrate that when these systems are well-described by a double exchange model Hamiltonian, only 1SF-IP/EA is required to extract the double exchange parameters and accurately predict energies for the low-spin states. This significantly reduces the computational effort for studying such systems. The effects of including additional excitations (using a RAS-<i>n</i>SF-IP/EA scheme) are also examined, with particular emphasis on hole and particle excitations.</div>

A Combined Spin-Flip and IP/EA Approach for Handling Spin and Spatial Degeneracies: Application to Double Exchange Systems

2018 ◽  
Author(s):  
Shannon Houck ◽  
Nicholas Mayhall
Keyword(s):  
Single Molecule ◽  
Double Exchange ◽  
Computational Effort ◽  
Strongly Correlated ◽  
Single Molecule Magnets ◽  
New Approach ◽  
Spin Flip ◽  
Model Hamiltonian ◽  
Simultaneous Existence ◽  
Exchange Parameters

<div>Many multiconfigurational systems, such as single-molecule magnets, are difficult to study using traditional computational methods due to the simultaneous existence of both spin and spatial degeneracies. In this work, a new approach termed n-spin-flip Ionization Potential/Electron Affinity (<i>n</i>SF-IP or <i>n</i>SF-EA) is introduced which combines the spin-flip method of Anna Krylov with particle-number changing IP/EA methods. We demonstrate the efficacy of the approach by applying it to the strongly-correlated N<sub>2</sub><sup>+</sup> as well as several double exchange systems. We also demonstrate that when these systems are well-described by a double exchange model Hamiltonian, only 1SF-IP/EA is required to extract the double exchange parameters and accurately predict energies for the low-spin states. This significantly reduces the computational effort for studying such systems. The effects of including additional excitations (using a RAS-<i>n</i>SF-IP/EA scheme) are also examined, with particular emphasis on hole and particle excitations.</div>

Hydrazone-based Dysprosium Single Molecule Magnets

2013 ◽  
Vol 3 (2) ◽  
pp. 101-111 ◽  
Author(s):  
Peng Zhang ◽  
Li Zhang ◽  
Jinkui Tang
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnets

The localized electron: magnetic properties

2018 ◽  
Author(s):  
Jean-Pierre Launay ◽  
Michel Verdaguer
Keyword(s):  
Single Molecule ◽  
Model Systems ◽  
Ferromagnetic Coupling ◽  
Single Chain ◽  
Single Molecule Magnets ◽  
Magnetic Systems ◽  
Orbital Interactions ◽  
Prussian Blue Analogues ◽  
Mononuclear Complexes

After preliminaries about electron properties, and definitions in magnetism, one treats the magnetism of mononuclear complexes, in particular spin cross-over, showing the role of cooperativity and the sensitivity to external perturbations. Orbital interactions and exchange interaction are explained in binuclear model systems, using orbital overlap and orthogonality concepts to explain antiferromagnetic or ferromagnetic coupling. The phenomenologically useful Spin Hamiltonian is defined. The concepts are then applied to extended molecular magnetic systems, leading to molecular magnetic materials of various dimensionalities exhibiting bulk ferro- or ferrimagnetism. An illustration is provided by Prussian Blue analogues. Magnetic anisotropy is introduced. It is shown that in some cases, a slow relaxation of magnetization arises and gives rise to appealing single-ion magnets, single-molecule magnets or single-chain magnets, a route to store information at the molecular level.

scholarly journals Tunneling, remanence, and frustration in dysprosium-based endohedral single-molecule magnets

2014 ◽  
Vol 89 (6) ◽  
Author(s):  
Rasmus Westerström ◽  
Jan Dreiser ◽  
Cinthia Piamonteze ◽  
Matthias Muntwiler ◽  
Stephen Weyeneth ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnets
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