Dynamic kinetics of CO oxidation over magnesium oxide

Author(s):  
Masayoshi Kobayashi ◽  
Tohru Kanno ◽  
Yasuyuki Konishi
2006 ◽  
Vol 258-260 ◽  
pp. 63-67
Author(s):  
V.M. Chumarev ◽  
V.P. Maryevich ◽  
V.A. Shashmurin

Diffusion processes play a dominant part in the macro kinetics of Fe, Ni and Co oxidation by calcium and sodium sulfates. Here, the reaction product forms a compact covering which spatially divides the reagents on the surface in the same way as in the oxidation and sulfidization of metals by oxygen and sulfur. Therefore, it is possible to assume in advance that interaction of metals with calcium and sodium sulfates will be determined not by the actual chemical reaction properly but by the diffusion transport processes.


2019 ◽  
Vol 59 (7) ◽  
pp. 63-68
Author(s):  
Nikolay F. Ushmarin ◽  
◽  
Evgeny N. Egorov ◽  
Nikolay I. Kol'tsov ◽  
◽  
...  

The article examines the oil-and-petrol resistant rubber mixture of type 7NO-68-1SK based on the combination of BNKS-18AMN grade butadiene-caoutchouc with polychloroprene caoutchouc of brand neoprene W. The effect of replacing imported burnt magnesia brand Remag AC on domestic burnt magnesia technical grade B on the properties of the rubber compound and vulcanizate was studied. The rubber mixture was prepared on a laboratory roll mill LB 320 160/160, and then its standard samples were vulcanized at 150 °C for 30 minutes in a two-story electrically heated press of the VP 400-2E brand. To establish the plasto-elastic properties of rubber mixture on the Mooney viscometer, MV 3000 was determined: the start time of the vulcanization, the time to reach the vulcanization mode, the initial maximum viscosity. To assess the kinetics of vulcanization of the rubber mixture on the rheometer MDR 3000 was determined: the start time of vulcanization, the time to reach the optimum vulcanization, the maximum torque. To assess the physicomechanical properties of rubber, the following were determined: conditional tensile strength; elongation at break; hardness; tear resistance and relative residual deformation under compression in accordance with the standards in force in the rubber industry. To assess the performance properties of rubber, changes in its mass were determined after aging in a mixture of isooctane + toluene, as well as standard liquid SJR–1. It has been shown that the introduction of burnt magnesia technical grade B into the rubber mixture does not lead to technological complications, magnesia is well distributed in the rubber matrix, and the magnesia agglomerates were not found on the rubber mixture sections. Replacement magnesium oxide m. Remag AC on burnt magnesia technical grade B has an impact on the plasto-elastic and rheometric properties of the rubber mixture. However of physicomechanical and operational properties vulcanizates of rubber mixture containing magnesium oxide m. Remag AC and burnt magnesiatechnical grade B, have almost the same values.


1979 ◽  
Vol 20 (4) ◽  
pp. 1687-1699 ◽  
Author(s):  
R. T. Williams ◽  
J. W. Williams ◽  
Thomas J. Turner ◽  
K. H. Lee

RSC Advances ◽  
2020 ◽  
Vol 10 (60) ◽  
pp. 36667-36677
Author(s):  
Khunnawat Ountaksinkul ◽  
Sippakorn Wannakao ◽  
Piyasan Praserthdam ◽  
Suttichai Assabumrungrat

The intrinsic kinetics of 1-butene isomerization over a commercial MgO catalyst was studied by using a Berty-type reactor (gradient-less recycle reactor) without limitations of heat-, external mass-, and internal mass-transfers.


1979 ◽  
Vol 15 (1) ◽  
pp. 59-61 ◽  
Author(s):  
S. N. Orlik ◽  
G. L. Koval' ◽  
A. V. Fesenko ◽  
G. P. Korneichuk ◽  
G. S. Yablonskii
Keyword(s):  

2020 ◽  
Vol 124 (5) ◽  
pp. 924-931 ◽  
Author(s):  
Zhiling Liu ◽  
Lina Hou ◽  
Ya Li ◽  
Gang Li ◽  
Zhengbo Qin ◽  
...  

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