A criterion based on the computational singular perturbation (CSP) method is
proposed in order to determine the number of quasi-steady state (QSS)
species. This criterion is employed for the reduction of a detailed chemical
kinetics mechanism for the oxidation of dimethyl ether (DME), involving 55
species and 290 reactions, leading to a 20 steps reduced mechanism which
involves 26 species. A software package, named I-CSP, was developed to make
the reduction process algorithmic. Input to the I-CSP includes (i) the
detailed mechanism, (ii) the numerical solution of the problem for a specific
set of operating conditions, (iii) the number of quasi steady state (QSS)
species. The resulting reduced mechanism was validated both in homogenous
reactor, including auto-ignition and PSR, over a wide range of pressures and
equivalence ratios, and in a one-dimensional, unstretched, premixed, laminar
steady DME/Air flame. Comparison of the results calculated with the detailed
and the reduced mechanisms shows excellent agreement in the case of
homogenous reactor, but discrepancies can be observed in the case of the
premixed laminar flame.