The influence of fly ash adittion (90 % fraction [ 100 mm) on the cement mortar characteristics was studied. The XRD, XRF, SEM and FTIR determinations indicated that fly ash used has a hollow microstructure of microsphere and cenosphere whose total content in SiO2, Al2O3 and Fe2O3 is 88.63 % and that of CaO and MgO of 8.55 %. The mechanical, thermal and dielectric determinations made on mortar samples with content of fly ash in the 0-40 % range have highlighted fact that the mechanical strength of cement mortars is maximal at 20 %, the increase in fly ash content leads to a decrease in relative density and thermal conductivity as well as and to increased dielectric losses tgd.