scholarly journals Preliminary Study Of Local Catalyst For Low Cost Methanol Synthesis As Subsequence Process Of A Model System Of Biomass Fluidized Bed Catalytic Gasification

2018 ◽  
Vol 67 ◽  
pp. 02035
Author(s):  
Joni Prasetyo ◽  
Nurdiah Rahmawati ◽  
Galuh Wirama Murti ◽  
S.D. Sumbogo Murti ◽  
Tyas Puspitarini ◽  
...  

Biomass waste has been emerging as an alternative energy and fuel. Direct combustion of biomass leads to harmful substances such as NOx and CO which are environmentally unfriendly manner. Innovation of clean technologies like gasification would have a potential in developing technology to reduce the emissions of harmful substances into the environment. The syngas of biomass gasification is an intermediate product which can be converted further to various types of alternative fuels especially methanol. Agency for the Assessment and application of Technology (BBPT)-Indonesia in cooperation with Gunma University-Japan has been conducting assessment and application of environmentally friendly solid biomass wastes utilization technology under the SATREPS (Science and Technology Research Partnership for Sustainable Development) program. This work is a prolongation of biomass gasification process from empty fruit bunches (EFB) to produce syngas. Furthermore, the syngas has a potential as raw material to synthesize methanol. The study of methanol synthesis focused on the development of efficient and low-cost catalyst in term of low pressure and low temperature. The catalyst of methanol synthesis was prepared by co-precipitation method with copper basis. The experiments have been performed and tested in a once-through process by Low-Pressure Fixed Bed Reactor in Micromeritics unit at a mild operating condition. The result shows that catalyst CuO: ZnO: Al2O3 (47%: 37%: 15%) has a good performance at 20 bar and 270°C with methanol concentration in the gas product up to 1.15%. On the words, the local catalyst performance comparable with commercial catalysts at low pressure and low temperature.

Author(s):  
Лемешева ◽  
E. Lemesheva ◽  
Кочегаров ◽  
D. Kochegarov ◽  
Тихомиров ◽  
...  

The growing demand for alternative motor fuels is dictated by aggravating energy and environmental problems. In article the analysis about possibility of use of alternative types of fuel for vehicles is carried out. Application of suitable alternative types of fuel will allow to improve in the future an economic and ecological situation in the country. Alternative fuel has to conform to the following requirements: to have necessary raw material resources, low cost, not to worsen operation of the engine, it is as little as possible to throw out harmful substances, whenever possible to be combined with the developed system of supply with fuel, etc. It is shown that natural gas and fuels derived from vegetable oils are most economical to use


BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 4294-4313
Author(s):  
Shuang Shang ◽  
Chaoqiang Guo ◽  
Kui Lan ◽  
Zeshan Li ◽  
Weitao He ◽  
...  

The co-gasification of wheat straw and wet sewage sludge for hydrogen-rich gas production was investigated in a fixed bed reactor with corn stalk char (CSC)-supported catalysts. The Ni/CSC, Ni-Fe/CSC, and Ni-Fe-La/CSC catalysts were characterized via ultimate analysis, X-ray fluorescence, thermogravimetric, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, Brunauer-Emmett-Teller, and Fourier transform infrared spectroscopy analyses. A series of experiments were performed to explore the effects of reactor temperature, catalyst type, moisture content of wet sludge, and catalyst recycling performance on the composition and yield of gasification gases. The experiments demonstrated that the nickel-iron alloy (Fe0.64Ni0.36) was detected in the Ni-Fe-La/CSC catalyst, and the Ni-Fe-La/CSC catalyst showed much higher hydrogen production compared with the Ni/CSC and Ni-Fe/CSC catalysts. Furthermore, La2O3 effectively maintained the catalytic performance of the catalyst by relieving carbon deposition. Compared with non-catalyst biomass gasification, H2 yield increased from 3.80 mol/kg to 11.96 mol/kg using Ni-Fe-La/CSC catalyst at 600 °C. The newly developed tri-metallic Ni-Fe-La/CSC catalyst exhibited high catalytic activity for biomass gasification at low temperature.


2002 ◽  
Vol 4 (4) ◽  
pp. 385-389 ◽  
Author(s):  
Mohammad Asadullah ◽  
Tomohisa Miyazawa ◽  
Shin-ichi Ito ◽  
Kimio Kunimori ◽  
Muneyoshi Yamada ◽  
...  

2012 ◽  
Vol 512-515 ◽  
pp. 2207-2211
Author(s):  
Hua Zhang Liu ◽  
Xia Zhen Yang ◽  
Ya Qing Cen ◽  
Hao Dong Tang

The performance and stability for FTS was studied on novel Fe1-xO-based iron catalyst (FIC) in agitated slurry reactor (ASR) and fixed bed reactor (FBR), and compared with precipitation-iron catalyst (PIC). The studied results indicate that novel Fe1-xO-based iron catalyst has the high conversion and high stability, especially, the high alkene selectivity in C2 ~ C4 products that the ratios of olefines and paraffines the more than 9 and the low cost, the preparation process and the high mechanical intensity. The catalyst can be used at FBR or ASR, and FTS at high temperature or low temperature.


Author(s):  
Gert Ehrlich

The field ion microscope, devised by Erwin Muller in the 1950's, was the first instrument to depict the structure of surfaces in atomic detail. An FIM image of a (111) plane of tungsten (Fig.l) is typical of what can be done by this microscope: for this small plane, every atom, at a separation of 4.48Å from its neighbors in the plane, is revealed. The image of the plane is highly enlarged, as it is projected on a phosphor screen with a radius of curvature more than a million times that of the sample. Müller achieved the resolution necessary to reveal individual atoms by imaging with ions, accommodated to the object at a low temperature. The ions are created at the sample surface by ionization of an inert image gas (usually helium), present at a low pressure (< 1 mTorr). at fields on the order of 4V/Å.


1987 ◽  
Vol 48 (C6) ◽  
pp. C6-487-C6-492
Author(s):  
W. Liu ◽  
D. M. Ren ◽  
C. L. Bao ◽  
T. T. Tsong

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