scholarly journals Research of pH influence on sorption properties of sorbents on a basis of residual biomass of microalgae Chlorella sorokiniana and duckweed Lemna minor

2019 ◽  
Vol 124 ◽  
pp. 01050
Author(s):  
N.A. Politayeva ◽  
Yu.A. Smyatskaya ◽  
I.V. Dolbnya ◽  
L.S. Kasobov ◽  
D.B. Rakhimov ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Water Purification ◽  
Heavy Metal Ions ◽  
Lemna Minor ◽  
Sorption Process ◽  
Chlorella Sorokiniana ◽  
Sorption Properties ◽  
Special Equipment ◽  
Residual Biomass

This scientific research is determined to a study of sorption process of heavy metal ions removal from aqueous solution at water purification with a help of sorption materials on a basis of residual biomass of microalgae and duckweed. It is known that Chlorella sorokiniana and duckweed Lemna minor have in their composition different valuable substances such as lipids, proteins, pigments, pectic substances. After their extraction residual biomass is formed. And in present study it is proposed for using as biosorbent for water purification. At different pH values the removal of ions of heavy metals (Zn(II), Cd(II), Pb(II), Cu(II)) occurs with varied efficiency; it is an important and informative parameter. Equilibrium and initial concentration of the solution with heavy metal ions were measured by voltammetric method of analysis with a use of special equipment. Chitosan was used as a component for making composite sorption materials with residual biomass of microalgae and duckweed. It is biopolymer which widely used in water purification. Due to this, prepared granules have good sorption properties. Nowadays in the era of technology and wide industrial production it is important and actual to develop new ecological technology and useful materials for water treatment and other fields for environment protection in general.

scholarly journals Use of Chlorella sorokiniana biomass as an oral sorbent

2020 ◽  
Vol 61 (1) ◽  
pp. 126-132
Author(s):  
Amira Toumi ◽  
◽  
Yulia A. Smyatskaya ◽  
Natalia A. Politaeva ◽  
◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Sorption Capacity ◽  
Human Body ◽  
Heavy Metal Ions ◽  
Chlorella Sorokiniana ◽  
Sorption Properties ◽  
Hydroxyl Groups ◽  
Microalgal Biomass ◽  
Ph Values

This article presents an assessment of the biosorption capacity of Chlorella sorokiniana microalgae in relation to heavy metal ions (Zn2+, Cd2+, Pb2+, Cu2+) at various pH values. With the development of industry, several environmental threats have emerged, including heavy metal pollution. This form of pollution has negative effects in the short and long term on the health of animals and humans. To prevent the accumulation of harmful substances in the human body, it is advised to use oral sorbents in prophylactic and therapeutic purposes. Oral sorbents have the ability to adsorb and neutralize certain toxins in the stomach and the intestines and remove them from the human body. The present article investigated the possibility of using microalgae Chlorella sorokiniana as an oral sorbent. The sorption capacity of Chlorella sorokiniana microalgal biomass was determined by voltammetry of standard solutions with an initial concentration of heavy metal ions of 10 mg/L. The removal efficiency ranged from 88 to 99%. The studies were carried out at pH values from 2 to 6. The sorption capacity was high at all considered acidity values. Sorption properties were confirmed by the study of the IR spectrum and microscopy of the freeze-dried biomass samples. The surface of the sorption material was studied by electron microscopy depicting the presence of multiple pores and depressions. It could be assumed that the sorption properties of microalgae are partly due to physical processes. Freeze drying can significantly increase the active surface area of the sample. The presence of hydroxyl groups in the biomass was confirmed by IR-spectroscopy indicating the chemical nature of the sorption process.

scholarly journals REMOVAL OF Cu(II), Cd(II), Co(II), Zn(II), Cr(VI) FROM WASTEWATER BY STABILIZED NANOSCALE ZERO-VALENT IRON

2021 ◽  
Author(s):  
Yurii M. Kholodko ◽  
Antonina I. Bondarieva ◽  
Viktoriia Yu. Tobilko ◽  
Iryna A. Kovalchuk ◽  
Borys Yu. Kornilovych
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Phase Composition ◽  
Metal Ions ◽  
Water Purification ◽  
Heavy Metal Ions ◽  
Complex Mixture ◽  
Zero Valent Iron ◽  
Sorption Properties

Background. Obtaining sorption materials based on natural raw materials for water purification from pollution by heavy metal ions is an urgent task of our time. Composites with zero-valent iron nanoparticles immobilized on the surface of clay minerals show rather high sorption properties concerning ions of some heavy metals. However, there are only a few proceedings devoted to the physicochemical substantiation of wastewater treatment processes containing a complex mixture of such pollutants. Objective. The purpose of the paper is to study the physicochemical regularities of wastewater treatment from a mixture of ions of heavy metals Cu(II), Cd(II), Co(II), Zn(II), Cr(VI) using stabilized nano dispersed powders of zero-valent iron. Methods. The phase composition and structural-sorption characteristics of palygorskite and composites were studied by X-ray phase analysis and low-temperature adsorption-desorption of nitrogen. The efficiency of removal of metal ions by silicate materials was investigated using the sorption method. The equilibrium concentrations of each of the metals were determined by inductively coupled plasma atomic emission spectrometry. Results. We have investigated the physicochemical features of wastewater treatment containing a complex mixture of heavy metal ions (Cu(II), Cd(II), Zn(II), Co(II), Cr(VI)). The phase composition and structural-sorption properties of stabilized nano dispersed powders of zero-valent iron have been studied. It has been experimentally confirmed that the materials obtained have significantly better sorption properties for the removal of heavy metals from aqueous solutions in comparison with natural palygorskite. Using Freundlich and Langmuir equations sorption isotherms were calculated. Conclusions. It has been established that stabilized nano dispersed powders of zero-valent iron can be successfully used for the purification of wastewater containing a mixture of toxic ions Cu(II), Cd(II), Co(II), Zn(II) and Cr(VI). It is shown that the degree of water purification by the obtained sorbents is 3–5 times higher than that for the unmodified mineral. A significant increase in the values of sorption of anionic forms of Cr(VI), which are difficult to remove from polluted waters by natural ion exchangers, has been determined.

scholarly journals Influence of the drying method on the sorption properties the biomass of Chlorella sorokiniana microalgae

2019 ◽  
Vol 124 ◽  
pp. 01051
Author(s):  
Y. Smyatskaya ◽  
A. Toumi ◽  
I. Atamaniuk ◽  
Ia. Vladimirov ◽  
F.K. Donaev ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Metal Removal ◽  
Inorganic Compounds ◽  
Heavy Metal Removal ◽  
Essential Amino Acids ◽  
Chlorella Sorokiniana ◽  
Microalgae Biomass ◽  
Zinc Cadmium

In this paper, it is proposed to use the biomass of microalgae Chlorella sorokiniana as a biosorbent for wastewater treatment, as well as an oral sorbent. Biosorbents are capable of adsorbing both organic and inorganic compounds, including heavy metals. The sorption capacity depends on the type of aquatic plant and microalgae strain. The use of microalgae and aquatic plants as biosorbents for pollutant treatments is discussed in the introduction part. The biomass of microalgae Chlorella sorokiniana was chosen as the object of this study. The cultivation conditions (temperature, light, pH and aeration) and the optimal biomass harvesting parameters are presented. Dehydration of biomass was carried out in two ways: IR-drying and freeze-drying. The obtained samples were tested for the ability of the biomass to extract heavy metal ions (zinc, cadmium, zinc, copper) from standard solutions. The initial concentration of heavy metal ions in the working solutions was 10 mg/l. Results show that the lyophilized samples demonstrated up to 99.9% of heavy metal removal efficiency. The paper also presents the composition of Chlorella sorokiniana biomass, in which up to 40.97–41.87% are proteins. The analysis of the amino-acid composition showed a ratio of essential to non-essential amino-acids higher than 0.8. All the above results confirm the possibility of using microalgae biomass as an oral sorbent and as an additive in the production of functional foods.

Sorption Properties of Fly Ash Microspheres of Thermal Power Plants

2019 ◽  
Vol 23 (1) ◽  
pp. 50-54 ◽  
Author(s):  
A.I. Fomenko ◽  
L.I. Sokolov
Keyword(s):  
Heavy Metal ◽  
Fly Ash ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Power Plants ◽  
Thermal Power ◽  
Sorption Properties ◽  
Thermal Power Plants ◽  
Iron Ions ◽  
Quantitative Characteristics

The sorption characteristics of aluminosilicate microspheres of fly ash from thermal power plants with respect to heavy metal ions were studied with a view to their subsequent use for integrated treatment of household and industrial wastewater. The mechanism and kinetics of the sorption of total iron ions from aqueous solutions are studied, quantitative characteristics of the sorption capacity and adsorption equilibrium constants are obtained. It has been established that aluminosilicate microspheres of fly ash possess sorption properties with respect to common iron ions. The sorption isotherm of iron ions from water by the material under study is characteristic of microporous sorbents. The quantitative characteristics of the sorption process allow us to conclude about the possibility of using aluminosilicate fly ash microspheres without any additional treatment for the purification of waste water from heavy metal ions.

scholarly journals Effect of LDHs and Other Clays on Polymer Composite in Adsorptive Removal of Contaminants: A Review

Crystals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 957 ◽  
Author(s):  
Maleshoane Mohapi ◽  
Jeremia Shale Sefadi ◽  
Mokgaotsa Jonas Mochane ◽  
Sifiso Innocent Magagula ◽  
Kgomotso Lebelo
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Water Purification ◽  
Heavy Metal Ions ◽  
Layered Silicate ◽  
Preparation Methods ◽  
Anionic Clays ◽  
2D Nanomaterials ◽  
Double Hydroxides ◽  
And Diffusion

Recently, the development of a unique class of layered silicate nanomaterials has attracted considerable interest for treatment of wastewater. Clean water is an essential commodity for healthier life, agriculture and a safe environment at large. Layered double hydroxides (LDHs) and other clay hybrids are emerging as potential nanostructured adsorbents for water purification. These LDH hybrids are referred to as hydrotalcite-based materials or anionic clays and promising multifunctional two-dimensional (2D) nanomaterials. They are used in many applications including photocatalysis, energy storage, nanocomposites, adsorption, diffusion and water purification. The adsorption and diffusion capacities of various toxic contaminants heavy metal ions and dyes on different unmodified and modified LDH-samples are discussed comparatively with other types of nanoclays acting as adsorbents. This review focuses on the preparation methods, comparison of adsorption and diffusion capacities of LDH-hybrids and other nanoclay materials for the treatment of various contaminants such as heavy metal ions and dyes.

Polyurethane Foam Filled with Chitosan — Sorbent for Elimination of Oil Pollution

2019 ◽  
Vol 23 (5) ◽  
pp. 37-41
Author(s):  
Quyen Thi Quynh Anh ◽  
D.I. Fazilova ◽  
A.A. Nazirova ◽  
L.A. Zenitova ◽  
V.V. Yanov
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Polyurethane Foam ◽  
Water Purification ◽  
Heavy Metal Ions ◽  
Oil Pollution ◽  
Raw Material ◽  
Foam Filled ◽  
Short Time

It is proposed to use a sorbent based on polyurethane foam and natural raw material chitosan for water purification from oil pollution. Traditionally, chitosan and materials with its use are mainly used as purifiers of water and other media from heavy metal ions. This paper provides information on the use of chitosan, which is preliminary isolated from the waste from processing f various beetles, dead bees, etc. Sorbent synthesis occurs by mixing the components of polyurethane foam and chitosan in a very short time, which allows you to produce and use it directly on site.

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