scholarly journals Influence of NaNA3and CuSO4catalytic additives on coal oxidation process kinetic dependencies

2016 ◽  
Vol 91 ◽  
pp. 01007 ◽  
Author(s):  
Kirill B. Larionov ◽  
Il’ya V. Mishakov ◽  
Alexandr A. Gromov ◽  
Andrey V. Zenkov
2020 ◽  
Vol 3 (441) ◽  
pp. 22-29
Author(s):  
P.N. Naguman ◽  
◽  
A.A. Zhorabek ◽  
A.T. Takibayeva ◽  
I.V. Kulakov ◽  
...  

2018 ◽  
Vol 194 ◽  
pp. 01034
Author(s):  
Darya Bolgova ◽  
Kirill Larionov ◽  
Andrey Zenkov ◽  
Stanislav Yankovsky

The process of coal oxidation with applied Cu(СH3COO)2 additive was studied by the capillary incipient wetness impregnation method with 5% mass concentration. The experiment was conducted by thermogravimetric analysis at a heating rate of 2.5°C/min to a maximum temperature of 600°C in atmospheric air. It was established that application of the initiation additive leads to a significant reduction in the initial temperature of sublimation and active oxidation of volatile compounds (ΔTi = 78°C) and the oxidation end temperature (ΔTf = 64°C). It was established that in the presence of copper acetate the nature of coal oxidation reaction significantly changes (DTG data). The parameters of the coals oxidation process in the presence of copper acetate were determined, and an assumption was made about the presence of a composite catalytic effect.


2003 ◽  
Vol 437-438 ◽  
pp. 495-498
Author(s):  
B. Kurniawan, Supiyanto ◽  
Sugih Sugiharto ◽  
J. Jamaludin ◽  
L. Hermanto ◽  
S. Soejati ◽  
...  

2018 ◽  
Vol 4 (9) ◽  
pp. 1231-1238 ◽  
Author(s):  
Divya Kamath ◽  
Daisuke Minakata

An elementary reaction based kinetic model was developed for the fate of acetone degradation in UV/free chlorine advanced oxidation process.


2020 ◽  
Author(s):  
Kai Wang ◽  
Haohao Fan ◽  
Yunzhong He ◽  
Jun Deng ◽  
Yanni Zhang

<p>The spontaneous combustion risk of Jurassic coal in Northwest China is special and different from that of permo-carboniferous coal. TG-FTIR experiments of a typical Jurassic coal sample in north Shaanxi was carried out to identify the grading, gas graduating and oxidation kinetics characteristic, under four heating rates of 5, 10, 15, and 20 ℃·min<sup>–1</sup> in an air atmosphere. The coal oxidation process of Jurassic coal at low temperature could be divided into two stages, mass loss stage and mass gain stage. The changing rules of apparent activation energy in the coal oxidation process at low temperature were determined by FWO and Kissinger methods. The model-fitting mathematical approach was used to identify the reaction kinetics mechanism functions at two oxidation stages of Jurassic coal in northwest China.</p>


Sign in / Sign up

Export Citation Format

Share Document