scholarly journals Using of alternative fillers based on the waste and its effect on the rubber properties

2019 ◽  
Vol 254 ◽  
pp. 04010
Author(s):  
Mariana Pajtášová ◽  
Darina Ondrušová ◽  
Róbert Janík ◽  
Zuzana Mičicová ◽  
Beáta Pecušová ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Physical And Mechanical Properties ◽  
Dynamic Mechanical Properties ◽  
Partial Replacement ◽  
Dynamic Mechanical ◽  
Rubber Compounds

The presented paper deals with a study of selected rubber compounds as well as their vulcanizates with partially replaced commonly used filler by adding selected alternative fillers. Alternative fillers were mixed into rubber compounds as partial replacement of commonly used filler – carbon black. As an alternative partial replacement of common filler, we have chosen fine fractions of the waste of thermoplastics. The differences of rubber compounds were based on the amount of used alternative filler. We determined vulcanization characteristics of prepared tread compounds and physical and mechanical properties and dynamic mechanical properties of their vulcanizates. From the measured results it can be concluded that studied waste can be used in the function of filler into rubber, as partial replacement of commonly used filler.

Strain Dependence of Dynamic Mechanical Properties of Carbon Black-Filled Rubber Compounds

1996 ◽  
Vol 69 (1) ◽  
pp. 15-47 ◽  
Author(s):  
J. D. Ulmer
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Strain Amplitude ◽  
Dynamic Mechanical Properties ◽  
Model Description ◽  
Strain Dependence ◽  
Dynamic Mechanical ◽  
Filled Rubber ◽  
Rubber Compounds ◽  
Viscous Modulus

Abstract The strain dependencies of dynamic mechanical properties of carbon black-filled rubber compounds have been modeled by Kraus. Evaluation of the Kraus model with carbon black loadings up to 110 phr shows that it provides a fairly good overall description of elastic modulus, G′, as a function of strain, γ. The model description of G′ strain dependence improves with decreased carbon black loading, and is very good with carbon black loadings of 50 phr and less. The model description of viscous modulus strain dependence, G″(γ), is less successful than the G′(γ) description. Several empirical modifications of the viscous modulus model are examined. The most improved model is a very good approximation to viscous modulus over a wide experimental strain-range. Its utility, and that of the Kraus G′(γ) model, are illustrated through calculation of simple shear dynamic properties from torsion property measurements on a solid cylinder, where the strain amplitude varies across the specimen radius. The models allow transformation of the apparent moduli, reported as functions of strain amplitude at the cylinder's outer edge, to their true counterparts, G′(γ) and G″(γ), as functions of uniform strain amplitude. Although the G′(γ) and modified G″(γ) models apply to a wide range of experimental strains, some uncertainties associated with each model's accuracy remain, and there are inconsistencies in the relation of one model to the other. Reservations associated with the models might be resolved through refined treatments of the test specimen geometries.

Novel modification of styrene butadiene rubber/acrylic rubber blends to improve mechanical, dynamic mechanical, and swelling behavior for oil sealing applications

2021 ◽  
pp. 096739112110313
Author(s):  
Ahmed Abdel-Hakim ◽  
Soma A el-Mogy ◽  
Ahmed I Abou-Kandil
Keyword(s):  
Mechanical Properties ◽  
Crosslink Density ◽  
Physical And Mechanical Properties ◽  
Dynamic Mechanical Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Blends ◽  
Dynamic Mechanical ◽  
Oil Resistance ◽  
Styrene Butadiene

Blending of rubber is an important route to modify properties of individual elastomeric components in order to obtain optimum chemical, physical, and mechanical properties. In this study, a novel modification of styrene butadiene rubber (SBR) is made by employing acrylic rubber (ACM) to obtain blends of outstanding mechanical, dynamic, and oil resistance properties. In order to achieve those properties, we used a unique vulcanizing system that improves the crosslink density between both polymers and enhances the dynamic mechanical properties as well as its resistance to both motor and break oils. Static mechanical measurements, tensile strength, elongation at break, and hardness are improved together with dynamic mechanical properties investigated using dynamic mechanical analyses. We also proposed a mechanism for the improvement of crosslink density and consequently oil resistance properties. This opens new opportunities for using SBR/ACM blends in oil sealing applications that requires rigorous mechanical and dynamic mechanical properties.

Dynamic-Mechanical Properties of Tin-Coupled SBRs

1995 ◽  
Vol 68 (2) ◽  
pp. 259-266 ◽  
Author(s):  
C. A. Sierra ◽  
C. Galán ◽  
J. M. Gómez Fatou ◽  
V. Ruíz Santa Quiteria
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Interaction Parameter ◽  
Anionic Polymerization ◽  
Dynamic Mechanical Properties ◽  
Tin Compounds ◽  
Dynamic Mechanical ◽  
Tin Content ◽  
First Time

Abstract The interaction between rubber and carbon black in compounds for road tire treads has been analyzed by using mechanical and dynamical measurements in three cured compounds based on SBRs. The rubbers were prepared in solution by anionic polymerization, and coupled with tin compounds in which the carbon-tin bond at the end of the chain may correspond to styryl or butadienyl terminations. The interaction parameter, defined by the ratio of mechanical and dynamic terms, has been used for the first time for the evaluation of the compounds. The SBRs with tin-butadienyl bonds exhibit an improved interaction with the filler, with increasing tin content.

EFFECT OF CARBON BLACK NATURE ON DYNAMIC MECHANICAL PROPERTIES AND REINFORCEMENT OF NR VULCANIZATION BY LATEX TECHNIQUES

2017 ◽  
Vol 90 (4) ◽  
pp. 611-620
Author(s):  
An Dong ◽  
Zhang Zhiyi ◽  
Jia Haixiang ◽  
Shou Jinquan ◽  
Zhang Huan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Dynamic Mechanical Properties ◽  
Mixing Process ◽  
Scanning Electron Micrograph ◽  
Dynamic Mechanical ◽  
Unit Operations ◽  
New Process ◽  
Static Mechanical ◽  
Filler Dispersion

ABSTRACT The influence of the structure and size of carbon black on the static mechanical and dynamic mechanical properties of filled natural rubber (NR) compounds is investigated in detail. A new process for the production of carbon black master batches with enhanced mechanical properties has been developed. The unit operations in the process are the preparation of carbon black slurry in the presence of a suitable surfactant, addition of the slurry to the fresh NR latex under stirring, coagulation of the mixture by the addition of acid, dewatering of the coagulum, and drying to obtain carbon black–incorporated NR. The competence of the new technique is established by comparing the characteristics of the carbon black–incorporated NR by the mill mixing process (control). The mechanical properties, including tensile strength, modulus, tear strength, and hardness, are superior for the vulcanization prepared by the latex-suspension coagulation techniques. The improvement shown by the vulcanization prepared by the latex-suspension coagulation techniques was attributed to the better filler dispersion evidenced from the scanning electron micrograph along with the attainment of a higher level of vulcanization.

scholarly journals Use of waste materials in rubber matrix

2018 ◽  
Vol 157 ◽  
pp. 07009 ◽  
Author(s):  
Mariana Pajtášová ◽  
Zuzana Mičicová ◽  
Darina Ondrušová ◽  
Slavomíra Božeková ◽  
Róbert Janík ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Loss Modulus ◽  
Rolling Resistance ◽  
Dynamic Mechanical Properties ◽  
Waste Materials ◽  
Partial Replacement ◽  
Rubber Matrix ◽  
Loss Angle ◽  
Rubber Compounds ◽  
Tan Δ

The presented paper deals with the use of waste materials as ecological fillers into rubber matrix. Waste materials were used as partial replacement of the commercial filler – carbon black, designated as N339. These prepared rubber compounds were characterized on the basis of the rheology and vulcanization characteristics – minimum torque (ML), maximum torque (MH), optimum time of vulcanization (t(c90)), processing safety of compound (ts), rate coefficient of vulcanization (Rv). In the case of the prepared vulcanizates, physical-mechanical properties (tensile strength, tensibility and hardness) and dynamic-mechanical properties (storage modulus, loss modulus, loss angle tan δ) were investigated. Using the dependency of loss angle on temperature, the selected properties for tyre tread vulcanizates were evaluated, including traction on snow and ice, traction on the wet surface and rolling resistance.

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