Improvement of hot ductility of C-Mn Steel containing arsenic by rare earth Ce

2018 ◽  
Vol 115 (4) ◽  
pp. 419 ◽  
Author(s):  
Wenbin Xin ◽  
Jing Zhang ◽  
Guoping Luo ◽  
Ruifen Wang ◽  
Qingyong Meng ◽  
...  

The effect of different Ce content on the hot ductility of C-Mn steel containing arsenic was investigated at the temperature ranging from 700 to 1100 °C conducting Gleebel-1500 thermal-mechanical simulator. The reduction of area (RA%) was used to evaluate the hot ductility. The 0.16 mass% As widened the ductility trough range and especially, decreased the RA value at 850–950 °C. Conversely, adding Ce in the steel could remedy the arsenic-induced hot ductility deterioration. Moreover, with the increase of Ce content from 0 to 0.035 mass%, the RA value at 800–950 °C significantly increased, compared to that of the arsenic steel. When the content of Ce reached 0.027–0.035 mass%, the RA value at 800–850 °C was even higher than that of steel without As. Besides, the corresponding fracture morphology was changed from intergranular feature to ductile and/or interdendritic feature. Grain refinement by Ce addition, the formation of arsenious rare earth inclusions and grain boundary segregation of Ce were considered to improve the hot ductility of the steel containing As.

2015 ◽  
Vol 47 (1) ◽  
pp. 522-530 ◽  
Author(s):  
Joseph D. Robson ◽  
Sarah J. Haigh ◽  
Bruce Davis ◽  
David Griffiths

Metals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1598
Author(s):  
Yu Guo ◽  
Yu Zhao ◽  
Shenhua Song

Advanced SA508-4N RPV steel samples, unadded, P-added, and P+Ce-added, are investigated on their hot ductility behavior. Hot tensile tests are carried out in the temperature range of 750 to 1000 °C through a Gleeble 1500D machine. It is demonstrated that the deformation temperatures of all the three steels are located in the austenite single-phase region. There is no ductility trough present for the P+Ce-added steel, but the unadded one exhibits a deep ductility trough. The reduction of area (RA) of the former is always higher than 75% and increases with rising temperature until reaching ~95% at 900 °C or above, whereas the lowest RA value of the latter is only ~50% at 850 °C. Microanalysis indicates that the grain boundary segregation of P and Ce takes place in the tested P+Ce-added steel. This may restrain the boundary sliding so as to improve the hot ductility behavior of the steel. Furthermore, the addition of P and Ce is able to facilitate the occurrence of the dynamic recrystallization (DR) of the steel, lowering the initial temperature of DR from ~900 to ~850 °C and thereby enhancing the hot ductility performance. Consequently, the combined addition of P and Ce can significantly improve the hot ductility of SA508-4N RPV steel, thereby improving its continuous casting performance and hot workability.


2015 ◽  
Vol 30 (10) ◽  
pp. 1701-1714
Author(s):  
Zongwen Zheng ◽  
Hongyao Yu ◽  
Zhenjun Liu ◽  
Tingdong Xu ◽  
R. Devesh K. Misra

Abstract


Author(s):  
C.L. Briant

Grain boundary segregation is the process by which solute elements in a material diffuse to the grain boundaries, become trapped there, and increase their local concentration at the boundary over that in the bulk. As a result of this process this local concentration of the segregant at the grain boundary can be many orders of magnitude greater than the bulk concentration of the segregant. The importance of this problem lies in the fact that grain boundary segregation can affect many material properties such as fracture, corrosion, and grain growth.One of the best ways to study grain boundary segregation is with Auger electron spectroscopy. This spectroscopy is an extremely surface sensitive technique. When it is used to study grain boundary segregation the sample must first be fractured intergranularly in the high vacuum spectrometer. This fracture surface is then the one that is analyzed. The development of scanning Auger spectrometers have allowed researchers to first image the fracture surface that is created and then to perform analyses on individual grain boundaries.


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