Factors Affecting Chromium(VI) Removal by Modified Poly(4-Vinylpyridine) Coated Silica Gel

Author(s):  
Dianchen Gang ◽  
Shankha K. Banerji ◽  
Thomas E. Clevenger
Author(s):  
James F. Amaku ◽  
Segun A. Ogundare ◽  
Kovo G. Akpomie ◽  
Comfort M. Ngwu ◽  
Jeanet Conradie

1986 ◽  
Vol 64 (7) ◽  
pp. 1243-1246 ◽  
Author(s):  
Paul de Mayo ◽  
N. Ramnath

The photolysis of α-methoxy acetophenones 1a–1e adsorbed on silica gel show a significant deviation from the course of reaction in methanol. The results are discussed in terms of conformational control and restricted movement of the radical through adsorption on silica gel. Factors affecting the efficiency of modification of photochemical reactivity on silica gel surface have been examined.


ChemInform ◽  
2004 ◽  
Vol 35 (22) ◽  
Author(s):  
Majid M. Heravi ◽  
Nasrin Farhangi ◽  
Yahya Sh. Beheshtiha ◽  
Mitra Ghassemzadeh ◽  
Koroush Tabar-Hydar

2008 ◽  
Vol 27 (2) ◽  
pp. 117 ◽  
Author(s):  
Shahriare Ghammamy ◽  
Mohammad Kazem Mohammadi ◽  
Ali Hassani Joshaghani

Triethylammonium halochromates, (C2H5)3NCrO3X, TEAXC (X = Cl, F) are easily synthesized by the reaction of triethylamine with a solution of chromium(VI) oxide in 6M hydrochloric acid, or a solution of chromium(VI) oxide in 40% hydrofluoric acid. These reagents are easily supported on common silica gel and can be used as heterogeneous oxidants. Triethylammonium halochromate(VI) is a versatile reagent for the effective and selective oxidation of organic substrates. Various aliphatic (cyclic and acyclic) and aromatic thiols are converted into the corresponding disulfides by treatment with triethylammonium fluorochromate(VI), (TEACC) or triethylammonium chlorochromate(VI), (TEAFC) supported on silica gel, in excellent yields and under mild reaction conditions.


2021 ◽  
Vol 10 (4) ◽  
pp. 901-910
Author(s):  
Jehan F AlRubaiea ◽  
Farkad A Latteiff ◽  
Jasim M Mahdi ◽  
Mohammed A Atiya ◽  
Hasan Sh Majdi

There are still areas around the world suffer from severe shortage of freshwater supplies. Desalination technologies are not widely used due to their high energy usage, cost, and environmental damaging effects. In this study, a mathematical model of single-bed adsorption desalination system using silica gel-water as working pair is developed and validated via earlier experiments. A very good match between the model predictions and the experimental results is recorded. The objective is to reveal the factors affecting the productivity of fresh water and cooling effect in the solar adsorption system. The proposed model is setup for solving within the commercially-available software (Engineering Equation Solver). It is implemented to solve the mass and heat balance equations for the adsorbent bed, condenser, and evaporator components. At a typical temperature of 89 °C and flow rate of 30 m3/sec for the hot water entering the bed, the following results are reported: (a) the specific daily water production of 1.89 m3 /ton of silica gel/ day, (b) coefficient of performance of 0.32, and (c) specific cooling power of 40.82 W/kg of silica gel. The concentration of salt (X) in the product (desalinated water) has been set with value of 0.5 gm/kg to be suitable for drinking and irrigation. The salt concentration in the evaporator is estimated to be 4.611 gm/kg during the overall adsorption process. The results from this study should be of wide interest for the field of solar water desalination and air-conditioning.


2001 ◽  
Vol 9 (1) ◽  
pp. 11-15 ◽  
Author(s):  
M. QuiIntana ◽  
G. Curutchet ◽  
E. Donati

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