Degeneracy of diffusion paths in ternary, two‐phase diffusion couples

1996 ◽  
Vol 79 (10) ◽  
pp. 7592-7595 ◽  
Author(s):  
P. Maugis ◽  
W. D. Hopfe ◽  
J. E. Morral ◽  
J. S. Kirkaldy
2000 ◽  
Vol 72 ◽  
pp. 105-110
Author(s):  
John Morral ◽  
Hui Min Chen ◽  
F. Meisenkothen

2007 ◽  
Vol 266 ◽  
pp. 83-99 ◽  
Author(s):  
Kevin M. Day ◽  
Mysore A. Dayananda

Selected diffusion couples investigated in the Cu-based and Fe-based multicomponent systems are examined for diffusion path development, zero-flux planes, uphill diffusion, and internal constraints for diffusion paths. The couples are analyzed for interdiffusion fluxes and interdiffusion coefficients with the aid of the “MultiDiFlux” program. Eigenvalues and eigenvectors are also determined from the interdiffusion coefficients determined over various ranges of composition in the diffusion zone. Slopes of diffusion paths at selected sections, including the path ends, are related to interdiffusion coefficients, interdiffusion fluxes and/or eigenvectors. These relations are explored with selected single phase diffusion couples in the Cu-Ni-Zn and Fe-Ni-Al systems and the calculated path slopes are compared with those directly determined from the concentration profiles. Relations between the gradient of interdiffusion flux and the concentration gradient are examined for each component in a two-phase Cu-Ni-Zn diffusion couple. The research is supported by the National Science Foundation.


2001 ◽  
Vol 44 (3) ◽  
pp. 415-421 ◽  
Author(s):  
Martin Schwind ◽  
Thomas Helander ◽  
John Ågren

2019 ◽  
Vol 38 (2019) ◽  
pp. 151-157 ◽  
Author(s):  
Bartek Wierzba ◽  
Wojciech J. Nowak ◽  
Daria Serafin

AbstractThe interdiffusion in Ti-based alloys was studied. It was shown that during diffusion at 1,123 K formation of four intermetallic phases occurs. The diffusion paths for six different diffusion couples were determined. Moreover, the entropy production was calculated – the approximation used for determination of the sequence of intermetallic phase formation. In theoretical analysis, the intrinsic diffusion coefficients were determined from the modified Wagner method.


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