Exact mathematical expressions for the time‐dependent behavior of successive first‐order reversible reactions

1980 ◽  
Vol 73 (1) ◽  
pp. 230-234 ◽  
Author(s):  
Akio Morita
2017 ◽  
Vol 23 (5) ◽  
pp. 415-425 ◽  
Author(s):  
M Dianat ◽  
M Taghizadeh ◽  
F Shahidi ◽  
SMA Razavi

In this study, the effect of barley malt extract at two brix levels (74 and 79 °Bx) and three ratios of malt extract/honey (65:35, 70:30 and 75:25) on the flow behavior properties of honey–malt spread at three temperature levels (35 ℃, 45 ℃ and 55 ℃) was investigated. Time-dependent behavior data of the spread samples were appropriately fitted to the Weltman, first-order stress decay with a zero stress value and first-order stress decay with a non-zero stress value models. Also, the Power-law, Herschel–Bulkley, Casson and Bingham models were used for curve fitting the time-independent behavior data. Regarding the R2 and root mean square error coefficients, the first-order stress decay with a non-zero stress value and Herschel–Bulkley models were selected as the suitable models to describe the flow behavior of samples. The results for time-dependent properties showed that spread samples exhibit a thixotropic behaviour, as the viscosity for all samples decreased with increase in shearing time at a constant shear rate of 50 s−1.


Author(s):  
Frederick W. Thwaites ◽  
Mihir Sen

The purpose of this study is to analyze the behavior of a set of thermally-controlled rooms arranged in the form of a ring. Each room is heated and can exchange heat with its neighbors as well as with the environment. The heater in each room is PI controlled. A lumped capacitance approximation is used for the rooms leading to a system of first-order differential equations. Numerical methods are used to determine the time-dependent behavior of the coupled system. The linear stability of the system is analyzed for various parameters. The stability is found to be independent of the strength of the thermal coupling between rooms.


1976 ◽  
Vol 56 (2) ◽  
pp. 71-78 ◽  
Author(s):  
D. R. CAMERON ◽  
C. G. KOWALENKO

A small subsystem model was developed to simulate the major nitrogen flow pathways in an unsaturated soil treated with ammonium sulphate. A nonlinear Freundlich equilibrium model and a Langmuir kinetic model were used to describe mathematically the adsorption–desorption of soluble NH4+ to the exchangeable and clay-fixed phases, respectively. Time dependent, microbial mediated first-order kinetic models were used to quantify the ammonification and nitrification processes. The subsystem model was then used as a research tool to derive ammonification and nitrification rate coefficients for a preceding incubation experiment conducted using different soil moisture contents and temperatures. The model yields reasonably good fits to the observed data. A subsequent regression analysis relating the coefficients to temperature and moisture pointed out the importance of the temperature–water content interaction term in quantifying microbial mediated processes.


2021 ◽  
Vol 28 (2) ◽  
pp. 024503
Author(s):  
Mohammed amin Ferdi ◽  
Abdelaaziz Bouziane ◽  
Mourad Djebli

2021 ◽  
Vol 137 ◽  
pp. 104300
Author(s):  
Yi Chong Cheng ◽  
Ri Hong Zhang ◽  
Kui Hua Wang ◽  
Zhi Yong Ai

1988 ◽  
Vol 187 ◽  
pp. 487-506 ◽  
Author(s):  
I. P. Castro ◽  
W. H. Snyder

In this paper experimental measurements of the time-dependent velocity and density perturbations upstream of obstacles towed through linearly stratified fluid are presented. Attention is concentrated on two-dimensional obstacles which generate turbulent separated wakes at Froude numbers, based on velocity and body height, of less than 0.5. The form of the upstream columnar modes is shown to be largely that of first-order unattenuating disturbances, which have little resemblance to the perturbations described by small-obstacle-height theories. For two-dimensional obstacles the disturbances are similar to those found by Wei, Kao & Pao (1975) and it is shown that provided a suitable obstacle drag coefficient is specified, the lowest-order modes (at least) are quantitatively consistent with the results of the Oseen inviscid model.Discussion of some results of similar measurements upstream of three-dimensional obstacles, the importance of towing tank endwalls and the relevance of the Foster & Saffman (1970) theory for the limit of zero Froude number is also included.


2014 ◽  
Vol 900 ◽  
pp. 753-756 ◽  
Author(s):  
You Guo Li

In this paper the nonlinear transversal vibration of axially moving yarn with time-dependent tension is investigated. Yarn material is modeled as Kelvin element. A partial differential equation governing the transversal vibration is derived from Newtons second law. Galerkin method is used to truncate the governing nonlinear differential equation, and thus first-order ordinary differential equation is obtained. The periodic vibration equation and the natural frequency of moving yarn are received by applying homotopy perturbation method. As a result, the condition which should be avoided in the weaving process for resonance is obtained.


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