A beam scattering study of the dynamics of CH+4(CH4,CH3)CH+5reaction in the eV collision energy range: Three competing mechanisms of CH+5formation

1990 ◽  
Vol 93 (7) ◽  
pp. 4916-4921 ◽  
Author(s):  
Zdenek Herman ◽  
Michael Henchman ◽  
Bretislav Friedrich
1998 ◽  
Vol 63 (8) ◽  
pp. 1152-1160 ◽  
Author(s):  
Ján Žabka ◽  
Zdeněk Dolejšek ◽  
Inosuke Koyano ◽  
Zdeněk Herman

Dynamics of the elementary protonation reaction in collisions of the acetonitrile cation with acetonitrile was investigated in crossed-beam scattering experiments in the hyperthermal collision energy range 1.17-2.5 eV. The reaction proceeds by three parallel collision mechanisms: direct proton (deuteron) transfer, direct H-atom transfer, and decomposition of an intermediate complex. The relative contributions of the three mechanisms to the formation of the product at T = 2.5 eV are about equal. Analysis of product angular distributions suggests that the geometry of the critical configuration of the decomposing intermediate is prolate, not far from linear.


1999 ◽  
Vol 38 (Part 1, No. 2A) ◽  
pp. 868-870 ◽  
Author(s):  
Yasunobu Kino ◽  
Fumiaki Murakami ◽  
Shinjiro Yagyu ◽  
Shigehiko Yamamoto

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