Lowest-Order Thermal Correction to the Hydrogen Recombination Cross-Section in Presence of Blackbody Radiation

In the present paper, the correction of the recombination and ionization processes of the hydrogen atom due to the thermal interaction of two charges was considered. The evaluation was based on a rigorous quantum electrodynamic (QED) approach within the framework of perturbation theory. The lowest-order radiative correction to the recombination/ionization cross-section was examined for a wide range of temperatures corresponding to laboratory and astrophysical conditions. The found thermal contribution was discussed both for specific states and for the total recombination and ionization coefficients.

Fundamental Parameters Related to Selenium Kα and Kβ Emission X-ray Spectra

We present relativistic ab initio calculations of fundamental parameters for atomic selenium, based on the Multiconfiguration Dirac-Fock method. In detail, fluorescence yields and subshell linewidths, both of K shell, as well as Kβ to Kα intensity ratio are provided, showing overall agreement with previous theoretical calculations and experimental values. Relative intensities were evaluated assuming the same ionization cross-section for the K-shell hole states, leading to a statistical distribution of these initial states. A method for estimating theoretical linewidths of X-ray lines, where the lines are composed by a multiplet of fine-structure levels that are spread in energy, is proposed. This method provides results that are closer to Kα1,2 experimental width values than the usual method, although slightly higher discrepancies occur for the Kβ1,3 lines. This indicates some inaccuracies in the calculation of Auger rates that have a higher contribution for partial linewidths of the subshells involved in the Kβ1,3 profile. Apart from this, the calculated value of Kβ to Kα intensity ratio, which is less sensitive to Auger rates issues, is in excellent agreement with recommended values.