The glassy and supercooled state of elemental sulfur: Vibrational modes, structure metastability, and polymer content

2013 ◽  
Vol 139 (12) ◽  
pp. 124501 ◽  
Author(s):  
K. S. Andrikopoulos ◽  
A. G. Kalampounias ◽  
O. Falagara ◽  
S. N. Yannopoulos
Author(s):  
V.K. Berry

There are two strains of bacteria viz. Thiobacillus thiooxidansand Thiobacillus ferrooxidanswidely mentioned to play an important role in the leaching process of low-grade ores. Another strain used in this study is a thermophile and is designated Caldariella .These microorganisms are acidophilic chemosynthetic aerobic autotrophs and are capable of oxidizing many metal sulfides and elemental sulfur to sulfates and Fe2+ to Fe3+. The necessity of physical contact or attachment by bacteria to mineral surfaces during oxidation reaction has not been fairly established so far. Temple and Koehler reported that during oxidation of marcasite T. thiooxidanswere found concentrated on mineral surface. Schaeffer, et al. demonstrated that physical contact or attachment is essential for oxidation of sulfur.


1992 ◽  
Vol 2 (10) ◽  
pp. 1929-1939 ◽  
Author(s):  
Mariette Barthes ◽  
Juegen Eckert ◽  
Susanna W. Johnson ◽  
Jacques Moret ◽  
Basil I. Swanson ◽  
...  

Circular ◽  
1970 ◽  
Author(s):  
Jim S. Hinds ◽  
Richard R. Cunningham
Keyword(s):  

1984 ◽  
Vol 19 (1) ◽  
pp. 111-118 ◽  
Author(s):  
B.G. Brownlee ◽  
D.S. Painter ◽  
R.J. Boone

Abstract During August, 1983 geosmin was identified in a municipal water supply drawn from western Lake Ontario. The geosmin concentrations were 0.01-0.07 μg L-1, within the range for threshold odour concentration of 0.01-0.2 μg L-1. 2-Methylisoborneol was not detected. The odour 'event' coincided with a dieoff of Cladophora in the lake, but we were not able to establish a direct link between the dieoff and geosmin production. Decomposing Cladophora in shoreline areas produced a strong odour in the air. 3-Methylindole, elemental sulfur, dimethyl tetrasulfide, and dimethyl pentasulfide were tentatively identified in water samples collected from these areas, but geosmin and 2-methylisoborneol were not detected.


1988 ◽  
Vol 53 (10) ◽  
pp. 2377-2384 ◽  
Author(s):  
Roman Řeřicha ◽  
Björg N. Cyvin ◽  
Jon Brunvoll ◽  
Sven J. Cyvin

Normal coordinate analyses including calculations of PED's were performed for C2H4.PtCl3 system modelling Zeise's anion, [(C2H4)PtCl3]-. The wedgewise distorsion of the C2H4 ligand known from the crystallographic data for Zeise's salt, was taken into account. Under these circumstances it was found that the kinematic couplings between the internal ligand and complex framework vibrational modes are rather small. The reliability of some existing assignments of the fundamental frequencies of Zeise's anion is discussed.


2019 ◽  
Vol 84 (5) ◽  
pp. 873-911 ◽  
Author(s):  
Marianna A Shubov ◽  
Laszlo P Kindrat

Abstract The distribution of natural frequencies of the Euler–Bernoulli beam subject to fully non-dissipative boundary conditions is investigated. The beam is clamped at the left end and equipped with a 4-parameter ($\alpha ,\beta ,k_1,k_2$) linear boundary feedback law at the right end. The $2 \times 2$ boundary feedback matrix relates the control input (a vector of velocity and its spatial derivative at the right end), to the output (a vector of shear and moment at the right end). The initial boundary value problem describing the dynamics of the beam has been reduced to the first order in time evolution equation in the state Hilbert space equipped with the energy norm. The dynamics generator has a purely discrete spectrum (the vibrational modes) denoted by $\{\nu _n\}_{n\in \mathbb {Z}^{\prime}}$. The role of the control parameters is examined and the following results have been proven: (i) when $\beta \neq 0$, the set of vibrational modes is asymptotically close to the vertical line on the complex $\nu$-plane given by the equation $\Re \nu = \alpha + (1-k_1k_2)/\beta$; (ii) when $\beta = 0$ and the parameter $K = (1-k_1 k_2)/(k_1+k_2)$ is such that $\left |K\right |\neq 1$ then the following relations are valid: $\Re (\nu _n/n) = O\left (1\right )$ and $\Im (\nu _n/n^2) = O\left (1\right )$ as $\left |n\right |\to \infty$; (iii) when $\beta =0$, $|K| = 1$, and $\alpha = 0$, then the following relations are valid: $\Re (\nu _n/n^2) = O\left (1\right )$ and $\Im (\nu _n/n) = O\left (1\right )$ as $\left |n\right |\to \infty$; (iv) when $\beta =0$, $|K| = 1$, and $\alpha>0$, then the following relations are valid: $\Re (\nu _n/\ln \left |n\right |) = O\left (1\right )$ and $\Im (\nu _n/n^2) = O\left (1\right )$ as $\left |n\right |\to \infty$.


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