Photodissociation Dynamics of Vinyl Chloride Investigated with a Pulsed Slit-Jet and Time-Resolved Fourier-Transform Spectroscopy
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Following photodissociation of vinyl chloride seeded in a He supersonic jet at 193 nm, rotationally resolved infrared emission of HCl (v) are recorded to yield nascent rotational and vibrational distributions. Preliminary results show that the rotational distribution of HCl free from rotational quenching deviates slightly from Boltzmann-type distribution and agrees well with trajectory calculations; a portion of the low-J component observed previously in a flow system is attributed to quenching. The implications for photodissociation dynamics are discussed.
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2006 ◽
Vol 8
(37)
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pp. 4337
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1989 ◽
Vol 90
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pp. 871-879
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2001 ◽
Vol 114
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pp. 7396-7406
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1999 ◽
Vol 111
(20)
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pp. 9233-9241
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Time-resolved Fourier transform infrared emission spectroscopy of He2 produced by a pulsed discharge
2004 ◽
Vol 383
(3-4)
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pp. 256-260
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2004 ◽
Vol 121
(18)
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pp. 8792-8799
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2009 ◽
Vol 113
(15)
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pp. 3431-3437
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