Surface-Enhanced Raman Scattering of the Bariandite Oxide Layer on a Vanadium Dioxide Crystal

2011 ◽  
Vol 64 (12) ◽  
pp. 1621
Author(s):  
Ian S. Butler ◽  
James K. Beattie
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Vanadium Dioxide ◽  
Variable Temperature ◽  
Fold Increase ◽  
Surface Enhanced Raman Scattering ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Metal Phase Transition ◽  
Enhanced Raman Scattering

Variable-temperature (25–100°C) Raman spectra of a crystal of commercial VO2 have revealed surface-enhanced Raman scattering (SERS) of the V=O stretching mode of the bariandite-like vanadium oxide species, V10O24·9H2O, that is formed on the surface of the crystal. Upon passing through the semiconductor-to-metal phase transition of VO2 at 68°C, there is an approximately three to five-fold increase in Raman intensity of the V=O stretching mode. This effect is reversible with hysteresis upon decreasing the temperature. The temperature dependence of the Raman spectra at temperatures below the transition suggest that even the semiconductor phase has some SERS effect.

scholarly journals Electronic and vibrational surface-enhanced Raman scattering: from atomically defined Au(111) and (100) to roughened Au

2020 ◽  
Vol 11 (36) ◽  
pp. 9807-9817 ◽  
Author(s):  
Motoharu Inagaki ◽  
Taichi Isogai ◽  
Kenta Motobayashi ◽  
Kai-Qiang Lin ◽  
Bin Ren ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Surface Enhanced Raman Scattering ◽  
Dielectric Interface ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Both electronic and vibrational information at the metal/dielectric interface were explicitly extracted from surface-enhanced Raman spectra.

scholarly journals Surface-Enhanced Raman Scattering Based-Molecular Encoding with Gold Nanostars for Anticounterfeiting Application

2021 ◽  
Author(s):  
Yifeng Huo ◽  
Samantha Curry ◽  
Andrew Trowbridge ◽  
Xurong Xu ◽  
Chaoyang Jiang
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Surface Enhanced Raman Scattering ◽  
Optical Methods ◽  
Molecular Fingerprint ◽  
Gold Nanostars ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Surface-enhanced Raman scattering (SERS) recently joins other optical methods in making novel anticounterfeiting materials due the fact that abundant molecular fingerprint in the Raman spectra can be less susceptible to...

scholarly journals Substrates for Surface-Enhanced Raman Scattering Formed on Nanostructured Non-Metallic Materials: Preparation and Characterization

Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 75
Author(s):  
Jan Krajczewski ◽  
Robert Ambroziak ◽  
Andrzej Kudelski
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Metallic Nanoparticles ◽  
Surface Enhanced Raman Scattering ◽  
Metallic Materials ◽  
Active Materials ◽  
Sers Substrates ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

The efficiency of the generation of Raman spectra by molecules adsorbed on some substrates (or placed at a very close distance to some substrates) may be many orders of magnitude larger than the efficiency of the generation of Raman spectra by molecules that are not adsorbed. This effect is called surface-enhanced Raman scattering (SERS). In the first SERS experiments, nanostructured plasmonic metals have been used as SERS-active materials. Later, other types of SERS-active materials have also been developed. In this review article, various SERS substrates formed on nanostructured non-metallic materials, including non-metallic nanostructured thin films or non-metallic nanoparticles covered by plasmonic metals and SERS-active nanomaterials that do not contain plasmonic metals, are described. Significant advances for many important applications of SERS spectroscopy of substrates based on nanostructured non-metallic materials allow us to predict a large increase in the significance of such nanomaterials in the near future. Some future perspectives on the application of SERS substrates utilizing nanostructured non-metallic materials are also presented.

scholarly journals Bonding between Chromium Atoms in Metal-String Complexes from Raman Spectra and Surface-Enhanced Raman Scattering: Vibrational Frequency of the Chromium Quadruple Bond

2011 ◽  
Vol 115 (28) ◽  
pp. 13919-13926 ◽  
Author(s):  
Yu-Min Huang ◽  
Huei-Ru Tsai ◽  
Szu-Hsueh Lai ◽  
Sheng Jui Lee ◽  
I-Chia Chen ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Vibrational Frequency ◽  
Surface Enhanced Raman Scattering ◽  
Quadruple Bond ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Characterization of Ir(ppy)3 and [Ir(ppy)2 bpy]+ by infrared, Raman spectra and surface-enhanced Raman scattering

2011 ◽  
Vol 42 (3) ◽  
pp. 332-338 ◽  
Author(s):  
Szu-Hsueh Lai ◽  
Jung-Wei Ling ◽  
Yu-Min Huang ◽  
Min-Jie Huang ◽  
Chien Hung Cheng ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Surface Enhanced Raman Scattering ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Degradation of Polystyrene on Silver Substrates during Surface-Enhanced Raman Scattering

1988 ◽  
Vol 42 (7) ◽  
pp. 1207-1213 ◽  
Author(s):  
R. S. Venkatachalam ◽  
F. J. Boerio ◽  
M. R. Carnevale ◽  
P. G. Roth
Keyword(s):  
Thin Films ◽  
Raman Scattering ◽  
Raman Spectra ◽  
Thick Films ◽  
Surface Enhanced Raman Scattering ◽  
Solid Polymer ◽  
Silver Surface ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Surface-enhanced Raman scattering (SERS) by films of polystyrene adsorbed onto silver island films was investigated. Films that were only a few tens of angstroms in thickness degraded rapidly during laser irradiation to form graphite-like species at the silver surface. However, no degradation was observed while Raman spectra of the solid polymer were obtained, indicating that the graphitization was probably induced by laser heating of the substrate and catalyzed by silver. For thin films of polystyrene, the rate of graphitization was high and was proportional to laser power. However, the degradation reaction was inhibited for thick films or for thin films overcoated with thick films of a second polymer. The Raman spectra were similar for all films thicker than approximately a hundred angstroms, even those overcoated with a thick film of a second polymer having a large Raman scattering cross section, indicating that most of the observed scattering originated from polymer molecules within a few tens of angstroms of the silver surface. It was concluded that SERS can be used to probe the molecular structure of polymer/metal interfaces without interference by scattering from the bulk of the polymer.

Recent progress in the applications of graphene in surface-enhanced Raman scattering and plasmon-induced catalytic reactions

2015 ◽  
Vol 3 (35) ◽  
pp. 9024-9037 ◽  
Author(s):  
Leilei Kang ◽  
Jiayu Chu ◽  
Hongtao Zhao ◽  
Ping Xu ◽  
Mengtao Sun
Keyword(s):  
Raman Scattering ◽  
Laser Irradiation ◽  
Raman Spectra ◽  
Recent Progress ◽  
Surface Enhanced Raman Scattering ◽  
Catalytic Reactions ◽  
Sers Substrates ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

In this review, the advances in informative Raman spectra of graphene are firstly reviewed. Then, the graphene related SERS substrates are summarized. We finally highlight the catalytic reactions occurring on graphene itself and molecules adsorbed onto graphene upon laser irradiation.

scholarly journals The application of surface enhanced Raman scattering to the detection of asphaltic petroleum in sediment extracts: deconvolving three component-mixtures using look-up tables of entire surface enhanced Raman spectra

2019 ◽  
Vol 11 (46) ◽  
pp. 5846-5856 ◽  
Author(s):  
Stephen A. Bowden ◽  
Colin W. Taylor
Keyword(s):  
Raman Scattering ◽  
Raman Spectra ◽  
Raman Effect ◽  
Surface Enhanced Raman Scattering ◽  
Entire Surface ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

The detection of asphaltic petroleum by surface enhanced Raman scattering (SERS) is uncomplicated, except in instances where the petroleum has been mixed with other components that also exhibit a strong Raman effect.

scholarly journals Hybrid surface-enhanced Raman scattering substrate from gold nanoparticle and photonic crystal: Maneuverability and uniformity of Raman spectra

2009 ◽  
Vol 17 (24) ◽  
pp. 21522 ◽  
Author(s):  
Cheng Yi Wu ◽  
Chia Chi Huang ◽  
Jia Sin Jhang ◽  
An Chi Liu ◽  
Chun-Chen Chiang ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Raman Scattering ◽  
Gold Nanoparticle ◽  
Raman Spectra ◽  
Surface Enhanced Raman Scattering ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering
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