The acid-catalysed hydrolysis of α-methylallyl acetate in aqueous solution

The kinetics of the acid-catalysed hydrolysis of a-methylallyl acetate in aqueous solution have been studied over the range 30-100�. Oxygen-18 tracer experiments reveal the mechanism to be solely Aac2 and the Arrhenius parameters are consistent with this conclusion. Crotyl alcohol is observed in the reaction products. The formation of rearranged alcohol is explained by allylic isomerization of the α-methylallyl alcohol produced by the hydrolysis.

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Kinetics of base hydrolysis of cis-aminebromobis(ethylenediamine)-cobalt(III) Complexes in aqueous solution at 25 °C

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9780000556 ◽

1978 ◽

pp. 556-560 ◽

Cited By ~ 5

Author(s):

Robert W. Hay ◽

Dharam P. Piplani

Keyword(s):

Aqueous Solution ◽

Base Hydrolysis ◽

Kinetics Of ◽

Hydrolysis Of

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Arrhenius parameters for the alkaline hydrolysis of glycine ethyl ester, in aqueous solution, and thermodynamic functions for its ionisation as an acid

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29670001265 ◽

1967 ◽

pp. 1265 ◽

Cited By ~ 5

Author(s):

Margaret Robson Wright

Keyword(s):

Aqueous Solution ◽

Ethyl Ester ◽

Thermodynamic Functions ◽

Alkaline Hydrolysis ◽

Arrhenius Parameters ◽

Glycine Ethyl Ester ◽

Hydrolysis Of

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ChemInform Abstract: The Production of the Superoxide Radical Anion by the OH Radical-Induced Oxidation of Trimethylamine in Oxygenated Aqueous Solution. The Kinetics of the Hydrolysis of (Hydroxymethyl)dimethylamine

ChemInform ◽

10.1002/chin.198725089 ◽

1987 ◽

Vol 18 (25) ◽

Author(s):

S. DAS ◽

M. N. SCHUCHMANN ◽

H.-P. SCHUCHMANN ◽

C. VON SONNTAG

Keyword(s):

Aqueous Solution ◽

Radical Anion ◽

Superoxide Radical ◽

Oh Radical ◽

Superoxide Radical Anion ◽

Kinetics Of ◽

Hydrolysis Of

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Stability of N-heterocyclic oxime derivatives. Part III. The kinetics of the hydrolysis of formyl- and acetyl-pyridine O-acetyloximes in aqueous solution in the pH range 6·0–10·8 at 25, 35, and 40°

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29680000167 ◽

1968 ◽

Vol 0 (0) ◽

pp. 167-169 ◽

Cited By ~ 1

Author(s):

J. H. Blanch

Keyword(s):

Aqueous Solution ◽

Oxime Derivatives ◽

Ph Range ◽

Kinetics Of ◽

Hydrolysis Of

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Early stages of the hydrolysis of chromium(III) in aqueous solution—VII. Kinetics of dimerization of deprotonated forms of doubly bridged dimer

Polyhedron ◽

10.1016/s0277-5387(00)86200-2 ◽

1991 ◽

Vol 10 (20-21) ◽

pp. 2389-2397 ◽

Cited By ~ 12

Author(s):

Michael R. Grace ◽

Leone Spiccia

Keyword(s):

Aqueous Solution ◽

Early Stages ◽

Kinetics Of ◽

Hydrolysis Of

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Arrhenius parameters for the alkaline hydrolysis of esters in aqueous solution. Part III. Methyl betaine methyl ester

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29680000548 ◽

1968 ◽

pp. 548 ◽

Cited By ~ 17

Author(s):

Margaret Robson Wright

Keyword(s):

Aqueous Solution ◽

Methyl Ester ◽

Alkaline Hydrolysis ◽

Arrhenius Parameters ◽

Hydrolysis Of Esters ◽

Hydrolysis Of

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Early stages of the hydrolysis of chromium(III) in aqueous solution. 3. Kinetics of dimerization of the deprotonated aqua ion

Inorganic Chemistry ◽

10.1021/ic00224a019 ◽

1986 ◽

Vol 25 (4) ◽

pp. 489-495 ◽

Cited By ~ 58

Author(s):

Francois P. Rotzinger ◽

Hans Stuenzi ◽

Werner Marty

Keyword(s):

Aqueous Solution ◽

Early Stages ◽

Kinetics Of ◽

Hydrolysis Of

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Reactivity of base catalysed hydrolysis of 2-pyridinylmethylene-8-quinolinyl-Schiff base iron(II) iodide complexes: solvent effects

Chemical Papers ◽

10.2478/s11696-012-0291-7 ◽

2013 ◽

Vol 67 (4) ◽

Cited By ~ 6

Author(s):

Ahmad Mohamad ◽

Mohamed Adam

Keyword(s):

Aqueous Solution ◽

Schiff Base ◽

Solvent Effects ◽

Base Hydrolysis ◽

Iodide Ions ◽

Ligand Structure ◽

Solvation Parameters ◽

Kinetics Of ◽

Hydrolysis Of ◽

Direct Condensation

AbstractThree ligands of 2-pyridinylmethylene-8-quinolinyl (L1), methyl-2-pyridinylmethylene-8-quinolinyl (L2), and phenyl-2-pyridinylmethylene-8-quinolinyl (L3), Schiff bases were synthesised by direct condensation of 8-aminoquinoline with 2-pyridinecarboxaldehyde, 2-acetylpyridine, or 2-benzoylpyridine. They coordinated to Fe(II) ion in a 1: 2 mole ratio followed by treatment with iodide ions affording complexes with a general formula [Fe(L)2]I2·2H2O, (L = L1, L2, or L3). Spectrophotometric evaluation of the kinetics of base catalysed hydrolysis of these complex cations was carried out with an aqueous solution of NaOH in different ratios of water/methanol binary mixtures. Kinetics of the hydrolysis followed the rate law (k 2[OH−] + k 3[OH−]2)[complex]. Reactivity trends and their rate constants were compared and discussed in terms of ligand structure and solvation parameters. The methanol ratio affects the hydrolysis as a co-solvent which was analysed into initial and transition state components. The increase in the rate constant of the base hydrolysis of Fe(II) complexes, as the ratio of methanol increases, is predominantly caused by the strong effect of the organic co-solvent on the transition states.

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