Some studies in inorganic complexes. XXIV. Copper(II) complexes of 2-acetamidopyridine and 2-methylpyridine-6-carboxylic acid
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Complexes of copper(II) with 2-acetamidopyridine (acpy) and with 2- methyl-pyridine-6-carboxylic acid (mepiac-H) have been prepared. The compounds studied included [Cu(acpy)2Cl2], [Cu(acpy)2Br2], [Cu(acpy)2(NCS)2], [Cu(acpy)2(NO3)2], [Cu(acpy)2(H2O)ClO4]ClO4,H2O, [Cu(mepiac)(mepiac-H)Cl], [Cu(mepiac)(mepiac-H)-Br], [Cu(mepiac)(mepiac-H)BrH2O], and [Cu(mepiac)2H2O]. The magnetic properties, conductances, reflectance and solution spectra, as well as infrared spectra, are in agreement with the copper(II) complexes of acpy being six-coordinate and those of mepiac-H having a five- coordinate structure.
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1999 ◽
Vol 477
(1-3)
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pp. 127-141
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1998 ◽
Vol 54
(3)
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pp. 507-516
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1972 ◽
Vol 28
(2)
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pp. 269-283
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2013 ◽
Vol 36
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pp. 224-226
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1982 ◽
Vol 60
(15)
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pp. 2017-2022
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