Micellar properties of disodium 4-alkyl 3-sulfonatosuccinates, two-headed anionic surfactants

DJ Jobe; VC Reinsborough

doi:10.1071/ch9840303

Micellar properties of disodium 4-alkyl 3-sulfonatosuccinates, two-headed anionic surfactants

Australian Journal of Chemistry ◽

10.1071/ch9840303 ◽

1984 ◽

Vol 37 (2) ◽

pp. 303 ◽

Cited By ~ 4

Author(s):

DJ Jobe ◽

VC Reinsborough

Keyword(s):

Aqueous Solution ◽

Anionic Surfactants ◽

Binding Constants ◽

Aqueous Environment ◽

Volume Changes ◽

Micellar Properties ◽

Aggregation Numbers ◽

Counter Ion

Density, viscosity, conductance, dye solubility, and carbon-13 n.m.r. studies were performed in aqueous solution of three disodium 4-alkyl 3-sulfonatosuccinate surfactants at 25.0�C. The CMC values were 0.33 mol dm-3 for the hexyl homologue (dhss), 0.14 mol dm-3 for the octyl homologue(doss), and 0.041 mol dm-3 for the decyl homologue (ddss). The aggregation numbers determined viscometrically and conductimetrically were 15 for dhss, 29 for doss, and 50 for ddss. The volume changes upon micellization were 7.0 cm3 mol-1 for dhss, 8.8 cm-3 mol-1 for doss, and 9.1 cm3 mol-1for ddss. Binding constants for the dye pada to the micelle and the fractions of unbound counter-ion were also obtained. The two polar heads with their carbon linkage were likely in an aqueous environment in the doss micelles with the micelles themselves being spherical.

Micellar properties of sodium alkyl sulfoacetates and sodium dialkyl sulfosuccinates in water

Canadian Journal of Chemistry ◽

10.1139/v84-047 ◽

1984 ◽

Vol 62 (2) ◽

pp. 280-284 ◽

Cited By ~ 8

Author(s):

David J. Jobe ◽

Vincent C. Reinsborough

Keyword(s):

Fluorescence Quenching ◽

Size Determination ◽

Micellar Solutions ◽

Volume Changes ◽

Micellar Properties ◽

Aggregation Numbers ◽

Conductance Technique ◽

Spherical Micelles ◽

Surfactant Systems ◽

Aqueous Micellar Solutions

Viscosity, conductivity, density, and fluorescence quenching studies were conducted in aqueous micellar solutions at 25.0 °C of sodium alkyl sulfoacetates and sodium dialkyl sulfosuccinates in a comparison of one-tailed and two-tailed surfactant systems. The hexyl, octyl, and decyl members of the former group and the dihexyl and dioctyl members of the latter group were investigated. The results indicated that the sulfoacetates most likely form spherical micelles with aggregation numbers 20 for hexyl, 42 for octyl, and 70 for decyl with three methods for size determination giving concordant results. For the sulfosuccinates, the aggregation numbers from fluorescence quenching were 38 for the dihexyl and 56 for the dioctyl in agreement with the results from the conductance technique which means that spherical micelles are likely formed also. Volume changes on micellization were obtained for the sulfoacetates.

Ionic effects on Supramolecular Hosts: Solvation and Counter-ion Binding in Polar Media

Physical Chemistry Chemical Physics ◽

10.1039/d1cp05444a ◽

2021 ◽

Author(s):

Nicolas Moreno-Gómez ◽

Edgar Vargas ◽

Richard Buchner

Keyword(s):

Aqueous Solution ◽

Supramolecular Chemistry ◽

Ion Binding ◽

Host Molecules ◽

Counter Ion ◽

Polar Media ◽

Counter Ion Binding ◽

Ionic Effects

For the progress of synthetic supramolecular chemistry in aqueous solution the design of host molecules soluble in this medium is essential. A possible route is the introduction of ionic residues,...

Pyrene-Labeled Gangliosides: Micellar Properties in Aqueous Solution, Lateral Diffusion and Thermotropic Behaviour in Phosphatidylcholine Bilayer

Gangliosides and Modulation of Neuronal Functions ◽

10.1007/978-3-642-71932-5_13 ◽

1987 ◽

pp. 181-182 ◽

Cited By ~ 1

Author(s):

M. Ollmann ◽

G. Schwarzmann ◽

K. Sandhoff ◽

H.-J. Galla

Keyword(s):

Aqueous Solution ◽

Lateral Diffusion ◽

Micellar Properties

Removal of cationic heavy metal from aqueous solution by activated carbon impregnated with anionic surfactants

Journal of Hazardous Materials ◽

10.1016/j.jhazmat.2008.09.036 ◽

2009 ◽

Vol 164 (2-3) ◽

pp. 1130-1136 ◽

Cited By ~ 165

Author(s):

Chi K. Ahn ◽

Donghee Park ◽

Seung H. Woo ◽

Jong M. Park

Keyword(s):

Aqueous Solution ◽

Heavy Metal ◽

Activated Carbon ◽

Anionic Surfactants

Volume changes for ionization of formic, acetic, and butyric acids and the glycinium ion in aqueous solution at 25.deg.

The Journal of Physical Chemistry ◽

10.1021/j100725a008 ◽

1969 ◽

Vol 73 (5) ◽

pp. 1220-1232 ◽

Cited By ~ 96

Author(s):

Edward Jasper King

Keyword(s):

Aqueous Solution ◽

Volume Changes

Effects of 1-alkyl-3-methylimidazolium bromide ionic liquids on the micellar properties of [butanediyl-1,4-bis(dimethyldodecylammonium bromide)] gemini surfactant in aqueous solution

Colloid & Polymer Science ◽

10.1007/s00396-017-4210-x ◽

2017 ◽

Cited By ~ 2

Author(s):

Utkarsh U. More ◽

Zuber S. Vaid ◽

Sargam M Rajput ◽

Naved I Malek ◽

Omar A. El Seoud

Keyword(s):

Aqueous Solution ◽

Ionic Liquids ◽

Gemini Surfactant ◽

Micellar Properties

Micellar properties of bolaform electrolytes in aqueous solution

The Journal of Physical Chemistry ◽

10.1021/j100588a022 ◽

1975 ◽

Vol 79 (21) ◽

pp. 2327-2328 ◽

Cited By ~ 15

Author(s):

J. R. Johnson ◽

R. Fleming

Keyword(s):

Aqueous Solution ◽

Micellar Properties ◽

Bolaform Electrolytes

Aqueous Solution of Anionic Surfactants Mixed with Soils Show a Synergistic Reduction in Surface Tension

Water Air & Soil Pollution ◽

10.1007/s11270-009-0175-9 ◽

2009 ◽

Vol 209 (1-4) ◽

pp. 3-13 ◽

Cited By ~ 5

Author(s):

Kerstin Hagenhoff ◽

Jingfeng Dong ◽

Babur Z. Chowdhry ◽

Stephen Anthony Leharne

Keyword(s):

Aqueous Solution ◽

Surface Tension ◽

Anionic Surfactants

Volume changes for thermally induced transitions of block copolymers of propylene oxide and ethylene oxide in aqueous solution as model systems for hydrophobic interaction

The Journal of Physical Chemistry ◽

10.1021/j100247a037 ◽

1985 ◽

Vol 89 (1) ◽

pp. 178-182 ◽

Cited By ~ 12

Author(s):

R. K. Williams ◽

M. A. Simard ◽

C. Jolicoeur

Keyword(s):

Aqueous Solution ◽

Block Copolymers ◽

Ethylene Oxide ◽

Propylene Oxide ◽

Hydrophobic Interaction ◽

Model Systems ◽

Volume Changes ◽

Thermally Induced

Long-chain anionic surfactants in aqueous solution. Removal by Moringa oleifera coagulant

Chemical Engineering Journal ◽

10.1016/j.cej.2011.11.024 ◽

2012 ◽

Vol 180 ◽

pp. 128-136 ◽

Cited By ~ 38

Author(s):

J. Beltrán-Heredia ◽

J. Sánchez-Martín ◽

M. Barrado-Moreno

Keyword(s):

Aqueous Solution ◽

Moringa Oleifera ◽

Anionic Surfactants ◽

Long Chain