Note High Yield Synthesis of Low Molecular Weight Poly(Vinyl Acetate) in Aqueous Acidic Media

1989 ◽  
Vol 26 (12) ◽  
pp. 1661-1664
Author(s):  
G. C. Joshi ◽  
A. K. Chatterjee ◽  
P. S. N. Murthy
1974 ◽  
Vol 10 (8) ◽  
pp. 615-618 ◽  
Author(s):  
G. G. Krasnyanskaya ◽  
B. V. Gryaznov ◽  
V. A. Kryunina ◽  
S. L. Lyubimova ◽  
V. N. Monastyrskii ◽  
...  

1983 ◽  
Vol 61 (2) ◽  
pp. 416-420 ◽  
Author(s):  
Norman G. Lewis ◽  
David A. I. Goring ◽  
Alfred Wong

High-yield spent bisulphite liquor (HY-SBL) from sulphonated black spruce wood (Piceamariana) was fractionated by gel permeation chromatography (GPC) and by high-performance liquid chromatography (HPLC). The GPC fractionation gave a wide bimodal distribution, whereas with HPLC, a more detailed resolution was seen with the bulk of the fraction giving several clearly defined peaks. The paucidisperse material was further concentrated by a bulk fractionation of the crude SBL which included complexing the lignosulphonates with dicyclohexylamine. The isolated paucidisperse material was found to be dialyzable and to constitute 90% of the lignosulphonate in the sample of SBL. If the bisulphite pulp obtained was recooked in fresh acid sulphite liquor to a lower yield, most of the lignosulphonate dissolved was widely polydisperse with no indication of the discrete components resolvable by HPLC. However, 25% of the lignin made soluble was in the form of the paucidisperse fractions. In all, we were able to obtain about 50% of the lignin in spruce wood as a relatively low molecular weight lignosulphonate resolvable into discrete fractions by HPLC.


Langmuir ◽  
2010 ◽  
Vol 26 (5) ◽  
pp. 3067-3076 ◽  
Author(s):  
E-Jen Teh ◽  
Yee-Kwong Leong ◽  
Yinong Liu ◽  
Vincent S. J. Craig ◽  
Rick B. Walsh ◽  
...  

1992 ◽  
Vol 29 (8) ◽  
pp. 689-698 ◽  
Author(s):  
M. Tiera ◽  
M. G. Neumann ◽  
S. G. Bertolotti ◽  
C. M. Previtali

2006 ◽  
Vol 309-311 ◽  
pp. 497-502 ◽  
Author(s):  
Yu Hong Feng ◽  
Xi Bin Wang ◽  
Qiang Lin ◽  
Zhou Xin Wu ◽  
Su Juan Pang ◽  
...  

The biosynthesis of low molecular weight bacterial cellulose (LMBC) by Static culture of Acetobacter xylinum HN001 has been investigated. The medium was prepared with coconut-water by adding sugar and N-compounds. Several conditions effected LMBC yields, such as start pH value of culture medium, culture temperature and culture time were investigated. In view of high yield of LMBC, the optimal culture time and culture temperature was about 70 hours and 32°C with yield of LMBC 1.2g/L. Molecular weight (MW) and molecular weight distribution (MWD) of LMBC were tested by GFC. Results showed that, though the start pH value of culture medium varied from 3.5 to 5.5, the MW of the product cellulose varied not notable and MWD of LMBC were all almost 1.3.


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