Breakdown of Evaporating Falling Films as a Function of Surface Tension Gradient

1996 ◽  
Vol 17 (4) ◽  
pp. 72-81 ◽  
Author(s):  
ALI G. BUDIMAN ◽  
C. FLORIJANTO ◽  
J. W. PALEN
2018 ◽  
Vol 3 (3) ◽  
Author(s):  
Dong Song ◽  
Baowei Song ◽  
Haibao Hu ◽  
Xiaosong Du ◽  
Peng Du ◽  
...  

1996 ◽  
Vol 118 (2) ◽  
pp. 201-209 ◽  
Author(s):  
Xiaoyi He ◽  
Micah Dembo

We present numerical computations of the deformation of an oil-droplet under the influence of a surface tension gradient generated by the surfactant released at the poles (the Greenspan experiment). We find this deformation to be very small under the pure surface tension gradient. To explain the large deformation of oil droplets observed in Greenspan’s experiments, we propose the existence of a phoretic force generated by the concentration gradient of the surfactant. We show that this hypothesis successfully explains the available experimental data and we propose some further tests.


CCS Chemistry ◽  
2019 ◽  
Vol 1 (2) ◽  
pp. 148-155 ◽  
Author(s):  
Mengjiao Cheng ◽  
Dequn Zhang ◽  
Shu Zhang ◽  
Zuankai Wang ◽  
Feng Shi

Inspired by the intriguing capability of beetles to quickly slide on water, scientists have long translated this surface-tension-gradient–dominated Marangoni motion into various applications, for example, self-propulsion. However, this classical spontaneous motion is limited by a short lifetime due to the loss of the surface tension gradient. Indeed, the propellant of amphiphilic surfactants can rapidly reach an adsorption equilibrium and an excessive aggregation state at the air/liquid interface. Here, we demonstrate a supramolecular host–guest chemistry strategy that allows the breaking of the physical limit of the adsorption equilibrium and the simultaneous removal of surfactant molecules from the interface. By balancing the competitive kinetics between the two processes, we have prolonged the lifetime of the motion 40-fold. Our work presents an important advance in the query of long-lived self-propulsion transport through flexible interference at the molecular level and holds promise in electricity generation applications .


1998 ◽  
Vol 359 ◽  
pp. 313-328 ◽  
Author(s):  
YULII D. SHIKHMURZAEV

An asymptotic analysis of two-dimensional free-surface cusps associated with flows at low Reynolds numbers is presented on the basis of a model which, in agreement with direct experimental observations, considers this phenomenon as a particular case of an interface formation–disappearance process. The model was derived from first principles and earlier applied to another similar process: the moving contact-line problem. As is shown, the capillary force acting on a cusp from the free surface, which in the classical approach can be balanced by viscous stresses only if the associated rate of dissipation of energy is infinite, in the present theory is always balanced by the force from the surface-tension-relaxation ‘tail’, which stretches from the cusp towards the interior of the fluid. The flow field near the cusp is shown to be regular, and the surface-tension gradient in the vicinity of the cusp, caused and maintained by the external flow, induces and is balanced by the shear stress. Existing approaches to the free-surface cusp description and some relevant experimental aspects of the problem are discussed.


2003 ◽  
Vol 475 ◽  
pp. 1-19 ◽  
Author(s):  
JAN M. SKOTHEIM ◽  
UWE THIELE ◽  
BENOIT SCHEID

We analyse the stability of a thin film falling under the influence of gravity down a locally heated plate. Marangoni flow, due to local temperature changes influencing the surface tension, opposes the gravitationally driven Poiseuille flow and forms a horizontal band at the upper edge of the heater. The thickness of the band increases with the surface tension gradient, until an instability forms a rivulet structure periodic in the transverse direction. We study the dependence of the critical Marangoni number, a non-dimensional measure of the surface tension gradient at the onset of instability, on the associated Bond and Biot numbers, non-dimensional measures of the curvature pressure and heat-conductive properties of the film respectively. We develop a model based on long-wave theory to calculate base-state solutions and their linear stability. We obtain dispersion relations, which give us the wavelength and growth rate of the fastest growing mode. The calculated film profile and wavelength of the most unstable mode at the instability threshold are in quantitative agreement with the experimental results. We show via an energy analysis of the most unstable linear eigenmode that the instability is driven by gravity and an interaction between base-state curvature and the perturbation thickness. In the case of non-zero Biot number transverse variations of the temperature profile also contribute to destabilization.


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