Chemical Modification of Silica Gels After Preliminary Thermal Treatment

1980 ◽  
Vol 3 (2) ◽  
pp. 201-217 ◽  
Author(s):  
Ziad El Rassi ◽  
Colette Gonnet
Author(s):  
Zhetcho Doinov Kalitchin ◽  
Mara Krumova Kandeva ◽  
Yana Petrova Stoyanova

This research work studies the characteristics of wear and wear resistance of composite powder coatings, deposited by high-velocity oxygen fuel, which contain composite mixtures Ni-Cr-B-Si having different chromium concentrations – 9.9%; 13.2%; 14%; 16% and 20% , at one and the same size of the particles and the same content of the remaining elements. The coating of 20% Cr does not contain B and Si. Out of each powder, composite coatings have been prepared without any preliminary thermal treatment of the substrate and with preliminary thermal treatment of the substrate up to 650оС. The coatings have been tested under identical conditions of dry friction over a surface of solid firmly attached abrasive particles using the tribological testing device „Pin-on-disk“. Results have been obtained and the dependences of the hardness, mass wear, intensity of the wearing process, absolute and relative wear resistance on the Cr concentration under identical conditions of friction. It has been found out that for all the coatings the preliminary thermal treatment of the substrate leads to a decrease in the wear intensity. Upon increasing Cr concentration the wear intensity diminishes and it reaches minimal values at 16% Cr. In the case of coatings having 20% Cr concentration, the wear intensity is increased, which is due to the absence of the components B and Si in the composite mixture, whereupon no inter-metallic structures are formed having high hardness and wear resistance. The obtained results have no analogues in the current literature and they have not been published by the authors.


1996 ◽  
Vol 431 ◽  
Author(s):  
Brigitta M. Baugher ◽  
Douglas A. Loy

AbstractWhile the sol-gel polymerizations of tetraalkoxy- and organotrialkoxysilanes have been extensively studied, there have been few reports of similar investigations with the analogous tetraalkoxygermanium and organotrialkoxygermanium compounds. Germanium alkoxides have received less attention due, in part to their higher cost, but also their greater reactivity towards hydrolysis and condensation reactions. Germanium oxide materials are potentially interesting because the Ge-O-Ge linkage is labile (compared with the siloxane bond in silica gels and polysilsesquioxanes) opening up the possibility of further chemical modification of the polymeric architecture. This may permit hydrolytic reorganization of germanium oxide networks under relatively mild conditions. In this paper, we will present the results of our investigations of the solgel polymerizations of tetraethoxygermanium 1, tetraisopropoxygermanium 2, and methyltriethoxy-germanium 3 to afford network materials as both xerogels and aerogels.


Author(s):  
Iara Fontes Demuner ◽  
Fernando José Borges Gomes ◽  
Marcela Ribeiro Coura ◽  
Jéssica Silva Gomes ◽  
Antônio Jacinto Demuner ◽  
...  

1994 ◽  
Vol 38 (2) ◽  
pp. 146-156 ◽  
Author(s):  
R. Leboda ◽  
E. Mendyk ◽  
V.V. Sidortchuk ◽  
V.A. Tertykh

Author(s):  
S R Mukhametzyanov ◽  
R R Safin ◽  
G F Ilalova ◽  
R R Khasanshin ◽  
A R Shaikhutdinova

Sign in / Sign up

Export Citation Format

Share Document