Simultaneous removal of nitrate, hydrogen peroxide and phosphate in semiconductor acidic wastewater by zero-valent iron

2014 ◽  
Vol 49 (9) ◽  
pp. 998-1006 ◽  
Author(s):  
Hiroyuki Yoshino ◽  
Masahiro Tokumura ◽  
Yoshinori Kawase
Water ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2909 ◽  
Author(s):  
Xiaofan Lv ◽  
Yiyang Ma ◽  
Yangyang Li ◽  
Qi Yang

Fe0@Fe3O4 nanoparticles with dispersibility and stability better than single nano zero-valent iron (nZVI) were synthesized and combined with hydrogen peroxide to constitute a heterogeneous Fenton-like system, which was creatively applied in the degradation of 2,4-dichlorophenoxyacetic acid (2,4-D). The effects of different reaction conditions like pH, hydrogen peroxide concentration, temperature, and catalyst dosage on the removal of 2,4-D were evaluated. The target pollutant was completely removed in 90min; nearly 66% of them could be mineralized, and the main intermediate product was 2,4-dichlorophenol. Synergistic effects between nZVI and Fe3O4 made the 2,4-D degradation efficiency in the Fe0@Fe3O4/H2O2 system greater than in either of them alone. More than a supporter, Fe3O4 could facilitate the degradation process by releasing ferrous and ferric ions from the inner structure. The reduction of 2,4-D was mainly attributed to hydroxyl radicals including surface-bound ∙OH and free ∙OH in solution and was dominated by the former. The possible mechanism of this Fe0@Fe3O4 activated Fenton-like system was proposed.


2020 ◽  
Vol 184 ◽  
pp. 150-162
Author(s):  
Hui Xu ◽  
Shuhua Yang ◽  
Yajuan Zhang ◽  
Jing Tang ◽  
Lei Tian ◽  
...  

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