acidic wastewater
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2022 ◽  
Vol 177 ◽  
pp. 107370
Author(s):  
Pedro Hernández ◽  
Gonzalo Recio ◽  
Christian Canales ◽  
Alex Schwarz ◽  
Denys Villa-Gomez ◽  
...  

Author(s):  
Ahmed Mahjoub ◽  
Osman Eltayeb

This study aimed to find an additional analytical reference procedure to verify the accuracy of single beam Spectrophotometer results that used to determine the concentration of nitro compound pollutants such as TNT, DNT, and MNT (Tri Nitro Toluene, Di Nitro toluene, and Mono Nitro Toluene respectively) in treated acidic wastewater generated from TNT manufacturing. This procedure was tested and confirmed to be a reference for a single-beam spectrophotometer. In this study 10 samples with known concentrations were taken and prepared for colorimetric analysis, the concentrations gradient from 10mg/L up to 60mg/L to make a ruler with gradient color, this ruler was suitable for high concentration samples but to specify the low concentration samples the procedure depended on adding a known concentration to the unknown concentration sample then this added concentration transferred the samples from unspecified color to specified color on the ruler consisted by known concentration mentioned above, the concentration of unknown concentration samples were specified by taking the concentration corresponding to the ruler color a subtracting the value of added concentration and the value of the remains was sample concentration. This study proved the reliability of this procedure to confirm single-beam spectrophotometer results, determining low concentration value of unknown concentration sample of TNT acidic wastewater, and then it can be used as a substituent of spectrophotometer in the event of malfunctions.


Author(s):  
Hisham Dafa Alla ali Mahjoub

Acidic wastewater treatment for the TNT factory which located in the middle of the mountains is characterized by part of its nature with alkaline properties, which prompted the researcher to take advantage of it in the treatment of acidic water instead of caustic soda. Acidic waste water is originated from spent acid treatment building, nitration, purification building, drying and packing building in TNT factory. The objective of this study is to use treated Acidic water TNT Factory by rock granules. Acidic waste water is mixed together with rock granules lye after crushed process of these rocks. The results the pH value of water after neutralizing reaction showed a significant rise in pH from 1.20 to 7. 00. This is within the SSMO. These data included reduction in BOD from 30.00 to 7.00 mg/l which is also within the range of SSMO. The COD value of the acidic wastewater which is 65.00 mg/l to 11 mg/l which is also within the range of SSMO. The use of rock granules for treatment will save an amount 9.45kg/t of  caustic soda per ton of product TNT product.


Author(s):  
Khalid Hamid ◽  
Abdelmoneim Massad Abdalla

This study conducted to substituting of NaOH used as a neutralizing agent for acidic wastewater generated from manufacturing of TNT in factory of Sudanese Military industries by natural material such as Neem leaves powder. The requirement for pH values of astewater to be disposed over 6. Four weights (5 , 7.5, 10 and 12.5 ) g of dry Neem leaves powder prepared and added to four samples of acidic wastewater with volume of 100 ml for each samples, the pH values of wastewater measured after four periods (1 ,2,3 and 4) hr for each weight added. The results showed the pH values raised from 1.7 to 6.94 and no any residual salts observed. The Neem leaves powder is effective alternatives for sodium hydroxide to neutralizing acidic wastewater at TNT plant.


Author(s):  
Prinya Chindaprasirt ◽  
Peerapong Jitsangiam ◽  
Wichian Chalee ◽  
Ubolluk Rattanasak

2021 ◽  
pp. 105767
Author(s):  
Tianqi Liao ◽  
Hongtao Qu ◽  
Te Zhang ◽  
Yongguang Luo ◽  
Libo Zhang ◽  
...  

Author(s):  
Henghua Zhu ◽  
Jianwei Zhou ◽  
Zhizheng Liu ◽  
Lizhi Yang ◽  
Yunde Liu

The study of the hydrochemical characteristics and the water–rock interaction of karst groundwater is very important for the rational exploitation of karst groundwater and its pollution control. In this paper, the systematic clustering method was used to analyze the hydrochemical characteristics of different types of groundwater, combined with hydrochemical graphic analysis and correlation analysis to explore the impact of chemical acidic wastewater on the evolution of karst aquifer in the Dawu water source area, northern China. The results show that the chemical acid wastewater, sourcing from discharges/spillages from the local chemical industries, has different degrees of pollution impact on karst groundwater, causing the total hardness of all karst groundwater and the total dissolved solids, Cl− and SO42− in nearly half of the karst groundwater to exceed the quality indexes of class III water in China’s standard for groundwater quality (GB/T 14848-2017). Hydrochloric acid and sulfuric acid in the wastewater can be buffered by the dissolution of carbonate rocks, resulting in a nearly neutral pH (pH-buffering effect) and an increase in Ca2+, Mg2+, Sr, Cl− and SO42− concentrations in karst groundwater.


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