Synthesis, crystal structure and characterization of two new metal-organic frameworks with 1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene and cyclohexane-1,3,5-tricarboxylate ligands

2021 ◽  
pp. 1-13
Author(s):  
Jin Hu ◽  
Xin-Hua Lu
Keyword(s):  
Crystal Structure ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Methyl Benzene

Photoresponsive porous materials: the design and synthesis of photochromic diarylethene-based linkers and a metal–organic framework

2014 ◽  
Vol 50 (20) ◽  
pp. 2653-2656 ◽  
Author(s):  
Dinesh G. (Dan) Patel ◽  
Ian M. Walton ◽  
Jordan M. Cox ◽  
Cody J. Gleason ◽  
David R. Butzer ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Porous Materials ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Crystal Structure Analysis ◽  
Synthesis And Characterization ◽  
Reaction Intermediates ◽  
Design And Synthesis ◽  
Metal Organic

The synthesis and characterization of novel photochromic diarylethene-based linkers for use in metal–organic frameworks is described including crystal structure analysis of nearly all reaction intermediates.

Crystal Structure and Characterization of Manganese(II) Carboxylates:  3D Metal−Organic Frameworks

2005 ◽  
Vol 5 (5) ◽  
pp. 1945-1951 ◽  
Author(s):  
Danuta Dobrzyńska ◽  
Lucjan B. Jerzykiewicz ◽  
Julia Jezierska ◽  
Marek Duczmal
Keyword(s):  
Crystal Structure ◽  
Metal Organic Frameworks ◽  
Metal Organic

Synthesis, crystal structure, luminescence, and photocatalytic properties of a 2D Cu(II) metal-organic frameworks based on 3,5-di(1H-benzimidazol-1-yl)pyridine and 4,4′-oxybis(benzoate) ligands

2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Uv Light ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Uv Light Irradiation ◽  
Photocatalytic Activities ◽  
Metal Organic

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.

Synthesis and Characterization of Lanthanide Metal-Organic Frameworks with Perfluorinated Linkers

2016 ◽  
Vol 98 ◽  
pp. 70-74
Author(s):  
Andrius Laurikėnas ◽  
Jurgis Barkauskas ◽  
Aivaras Kareiva
Keyword(s):  
Metal Organic Frameworks ◽  
Aqueous Media ◽  
Xrd Analysis ◽  
X Ray Diffraction ◽  
Lanthanide Elements ◽  
Diffusion Controlled ◽  
Benzenedicarboxylic Acid ◽  
Metal Organic ◽  
Lanthanide Metal

In this study, lanthanide elements (Ln3+) and 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylic acid (TFBDC) based metal-organic frameworks (MOFs) were synthesized by precipitation and diffusion-controlled precipitation methods. Powders insoluble in aqueous media and polar solvents were obtained. The microstructure and properties of Ln3+ MOFs were evaluated and discussed. X-ray diffraction (XRD) analysis, infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and fluorescence spectroscopy (FLS) were carried out to characterize Ln3+ MOF's crystallinity, the microstructure, chemical composition and optical properties.

scholarly journals A Comparison of Barostats for the Mechanical Characterization of Metal–Organic Frameworks

2015 ◽  
Vol 11 (12) ◽  
pp. 5583-5597 ◽  
Author(s):  
S.M.J. Rogge ◽  
L. Vanduyfhuys ◽  
A. Ghysels ◽  
M. Waroquier ◽  
T. Verstraelen ◽  
...  
Keyword(s):  
Mechanical Characterization ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Synthesis, Crystal Structure, and Luminescent Properties of New Zinc(II) and Cadmium(II) Metal-Organic Frameworks Based on Flexible Bis(imidazol-1-yl)alkane Ligands

Crystals ◽  
2016 ◽  
Vol 6 (10) ◽  
pp. 132 ◽  
Author(s):  
Marina Barsukova ◽  
Tatiana Goncharova ◽  
Denis Samsonenko ◽  
Danil Dybtsev ◽  
Andrei Potapov
Keyword(s):  
Crystal Structure ◽  
Metal Organic Frameworks ◽  
Luminescent Properties ◽  
Metal Organic

scholarly journals STUDY OF SYNTHESIS AND CHARACTERIZATION OF METAL-ORGANIC FRAMEWORKS MOF-5 AS HYDROGEN STORAGE MATERIAL

2016 ◽  
Vol 12 (1) ◽  
pp. 14
Author(s):  
Prapti Rahayu ◽  
Witri Wahyu Lestari
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Frameworks ◽  
Synthesis Method ◽  
High Porosity ◽  
Hydrogen Storage Material ◽  
Storage Material ◽  
Good Thermal Stability ◽  
Metal Organic ◽  
Organic Linker

<p>Metal-organic frameworks (MOFs) are porous coordination polymer containing bi-or polidentate organic linker coordinated with inorganic part, such as metal oxide cluster or metal cation as node which called as secondary building unit (SBU) to form infinite structure. Due to high porosity and surface area, good thermal stability as well as the availability of unsaturated metal center or the linker influence attracts the interaction with gases, thus MOFs have potential to be applied as hydrogen storage material. One type of MOFs that have been widely studied is [Zn<sub>4</sub>O(benzene-1,4-dicarboxylate)<sub>3</sub>], namely, MOF-5.Various synthesis method have been developed to obtain optimum results. Characterization of MOF-5 from various synthesis method such as crystallinity, capacity, stability, and quantum dot behavior of MOF-5 have been summarized in this review.</p>

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