The optical absorption spectrum, Photoluminesces, and non-linear optical properties for Copper Phthalocyanine (CuPc) thin films (150,300 and 450 nm) respectively have been investigated via pulsed laser deposition technique. The absorption spectrum indicted that there are two bands one in UV around 330 nm which called B-band and the second in Visible around 650nm which called Q-band. Photoluminescence spectrum related to deposit samples has been determined with different thicknesses. From closed and open aperture Z-scan data non-linear absorption coefficient and non-linear refractive index have been calculated respectively using He-Ne laser which have beam waist of (24.2 μm), wave-length of (632.8 nm) and Rayleigh thickness was 2.9 mm. Through dividing closed by open apertures, non-linear refractive index was calculated accurately. Finally, the study also showed the suitability of the deposited films as an optical limiter at the wavelength 632.8 nm.